乙烯-乙酸乙烯酯共聚物接枝聚合物的合成、表征及应用新进展

doi:10.16085/j.issn.1000-6613.2017-0129

化工进展 ›› 2017, Vol. 36 ›› Issue (10): 3757-3764.DOI: 10.16085/j.issn.1000-6613.2017-0129

乙烯-乙酸乙烯酯共聚物接枝聚合物的合成、表征及应用新进展

金世龙^1,2, 郑斌茹^1,2, 历娜¹, 毛国梁¹, 吴韦¹, 崔崑²

1. 东北石油大学化学化工学院, 石油与天然气化工省重点实验室, 黑龙江大庆 163318;
2. 中国科学院上海有机化学研究所, 中国科学院有机功能分子合成与组装化学重点实验室, 上海 200032

收稿日期:2017-01-19 修回日期:2017-04-19 出版日期:2017-10-05 发布日期:2017-10-05
通讯作者: 崔崑,博士,高级工程师,主要从事功能高分子材料、纳米复合材料研究;毛国梁,博士,教授,主要研究方向为聚烯烃催化剂及油田化学剂.
作者简介:金世龙(1989-),男,硕士研究生.E-mail:fumupingan6@163.com.
基金资助:
国家自然科学基金（51534004，U1362110，21374130）及上海市自然科学基金（14ZR1448700）项目。

Recent advances in the synthesis,characterization and application of ethylene-vinyl acetate graft polymer

JIN Shilong^1,2, ZHENG Binru^1,2, LI Na¹, MAO Guoliang¹, WU Wei¹, CUI Kun²

1. Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering, Northeastern Petroleum University, Heilongjiang 163318, Daqing, China;
2. Key Laboratory of Self-Assembly and Chemistry of Organic Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Received:2017-01-19 Revised:2017-04-19 Online:2017-10-05 Published:2017-10-05

摘要/Abstract

摘要： 乙烯-乙酸乙烯酯共聚物（EVA）以其优异的耐低温性、耐氧化性、耐环境应力开裂性和耐腐蚀性等性能，在很多领域得到了广泛应用。近年来，为了赋予其新的性能和功能，拓展其应用领域，对EVA的接枝改性及其应用研究受到广泛关注。文章首先介绍了利用熔融接枝法、溶液接枝法以及乳液接枝法合成EVA接枝聚合物的研究新进展，接着以EVA接枝马来酸酐聚合物为例分析了接枝反应机理，然后对EVA接枝聚合物的表征方法包括仪器法和化学滴定法及应用进行总结和评述。最后对EVA接枝聚合物的合成方法的优缺点、表征方法及其应用的发展前景进行了阐述，指出溶液接枝法是未来的发展趋势，共混相容剂、膜材料和原油降凝材料是其未来比较广泛的应用领域。

关键词: 乙烯-乙酸乙烯酯共聚物, 接枝改性, 接枝机理, 聚合物, 合成, 表征

Abstract: In recent years,ethylene-vinyl acetate copolymer(EVA),due to its excellent low temperature resistance,oxidation resistance,environmental stress cracking resistance,corrosion resistance,etc.,has wide application prospect in a lot of areas. In order to endow it with new properties and functions and expand its applications,stuies of graft modification of EVA and related applications have drawn much attention recently. In this work,recent advances in the synthesis of EVA graft polymer via melt grafting,solution grafting and emulsion grafting was introduced firstly. Then,the grafting mechanism was analyzed using EVA-g-maleic anhydride polymer as an example. Subsequently,the characterization methods including instrument method and chemical titration and the applications of EVA graft polymer were summarized and reviewed. Finally,the advantages and disadvantages of the synthesis methods of EVA grafted polymer,characterization method and its application prospects are elaborated,and we pointed out that the solution grafting method is the future trend. Blending compatible materials,membrane materials and oil dewaxing materials will be the widely used areas in the future.

Key words: ethylene-vinyl acetate copolymer, grafting modification, grafting mechanism, polymer, synthesis, characterization

中图分类号:

O632.1
TQ325

金世龙, 郑斌茹, 历娜, 毛国梁, 吴韦, 崔崑. 乙烯-乙酸乙烯酯共聚物接枝聚合物的合成、表征及应用新进展[J]. 化工进展, 2017, 36(10): 3757-3764.

JIN Shilong, ZHENG Binru, LI Na, MAO Guoliang, WU Wei, CUI Kun. Recent advances in the synthesis,characterization and application of ethylene-vinyl acetate graft polymer[J]. Chemical Industry and Engineering Progress, 2017, 36(10): 3757-3764.

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乙烯-乙酸乙烯酯共聚物接枝聚合物的合成、表征及应用新进展

Recent advances in the synthesis,characterization and application of ethylene-vinyl acetate graft polymer

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