表面活性剂对水基纳米流体特性影响的研究进展

doi:10.16085/j.issn.1000-6613.2015.04.002

摘要/Abstract

摘要： 表面活性剂作为一种分散剂,广泛应用于新型换热工质——纳米流体中.研究纳米流体的各种特性对于其在实际的能量传递系统中的应用有重要意义.重点总结和比较了水基纳米流体中表面活性剂对体系的稳定性、热导率和黏度影响的实验研究,阐述了纳米流体中表面活性剂的作用机理,对目前的研究中存在的问题进行了分析.最后,提出了有助于完善表面活性剂对水基纳米流体特性影响的4点建议:混合表面活性剂的组合及其配比对纳米流体的稳定性、热导率和黏度的影响;使用分子动力模拟等方法来研究表面活性剂对纳米流体特性的影响;表面活性剂影响下的纳米流体的稳定性和热导率及黏度之间的关系;纳米流体中众多不确定因素的量化分析.

关键词: 表面活性剂, 纳米流体, 稳定性, 热导率, 黏度

Abstract: Surfactants have been widely used in nanofluids——the new heat transfer working fluid as a dispersant. It's very important to study the characteristics of nanofluids in actual energy transfer system. Experimental study on the effect of surfactants on stability,thermal conductivity and viscosity of H₂O-based nanofluids was specially summarized and compared,mechanism of surfactants in nanofluids and problems existing in current studies were stated and analyzed. Finally,four suggestions helping to improve effects of surfactants on the characteristics of H₂O-based nanofluids were put forward,including the impact of mixed surfactant composition and proportion on stability,thermal conductivity and viscosity of nanofluids; methods,such as molecular dynamics simulations,to study effects of surfactants on the nanofluid properties; relationship between stability and thermal conductivity and viscosity in nanofluids with surfactants; and quantitative analysis of many uncertainties in nanofluids.

Key words: surfactants, nanofluids, stability, thermal conductivity, viscosity

中图分类号:

TQ047.4

张亚楠, 刘妮, 由龙涛, 柳秀婷. 表面活性剂对水基纳米流体特性影响的研究进展[J]. 化工进展, 2015, 34(04): 903-910,920.

ZHANG Yanan, LIU Ni, YOU Longtao, LIU Xiuting. Research progress in the effect of surfactants on the characteristics of H₂O-based nanofluids[J]. Chemical Industry and Engineering Progree, 2015, 34(04): 903-910,920.

参考文献

[1] Choi S U S. Enhancement thermal conductivity of fluids with nanoparticles[C]//Developments and Applications of Non-Newtonian Flows,New York:ASME Publication,1995:99-105.
[2] 洪欢喜,武卫东,盛伟,等. 纳米流体制备的研究进展[J]. 化工进展,2008,27(12):1923-1928.
[3] Zoubida Haddad,Chérifa Abid,Hakan F Oztop,et al. A review on how the researchers prepare their nanofluids[J]. International Journal of Thermal Sciences,2014,76:168-189.
[4] Ghadimi A,Saidur R,Metselaar H S C. A review of nanofluid stability properties and characterization in stationary conditions[J]. International Journal of Heat and Mass Transfer,2011,54(17-18):4051-4068.
[5] Shoghl S N,Bahrami M. Experimental investigation on pool boiling heat transfer of ZnO,and CuO water-based nanofluids and effect of surfactant on heat transfer coefficient[J]. International Communications in Heat and Mass Transfer,2013,45:122-129.
[6] 张俊,李苏巧,彭林明,等. 纳米流体强化气液传质研究进展[J]. 化工进展,2013,32(4):732-739.
[7] 宣益民,李强. 纳米流体能量传递理论与应用[M]. 北京:科学出版社,2009:24-27.
[8] 彭小飞,俞小莉,夏立峰,等. 纳米流体悬浮稳定性影响因素[J]. 浙江大学学报:工学版,2007,41(4):577-580.
[9] Majid Emami Meibodi,Mohsen Vafaie-Sefti,Ali Morad Rashidi,et al. The role of different parameters on the stability and thermal conductivity of carbon nanotube/water nanofluids[J]. International Communications in Heat and Mass Transfer,2010(37):319-323.
[10] 李金平,吴疆,梁德青,等. 纳米粒子悬浮液中分散剂选择的实验研究[J]. 兰州理工大学学报,2006,32(3):63-66.
[11] 李兴,陈颖,莫松平,等. 表面活性剂对水基纳米流体固液相变特性的影响[J]. 化工学报,2013,49(6):3324-3330.
[12] 郝素菊,张玉柱,蒋武锋,等. 含碳纳米管悬浮液的稳定性[J]. 东北大学学报:自然科学版,2007,28(10):1438-1441.
[13] Zhu D S,Li X F,Wang N,et al. Dispersion behavior and thermal conductivity characteristics of Al₂O₃-H₂O nanofluids[J]. Current Applied Physics,2009,9(1):131-139.
[14] 林海斌,张国贤,黄林林,等. 纳米流体的分散性研究及其热物性测量[J]. 材料导报:研究篇,2010,24(6):29-32.
[15] 程波,杜恺,张小松,等. 氨水-纳米炭黑纳米流体的稳定性[J]. 化工学报,2008,59(s2):49-52.
[16] Yang Liu,Du Kai,Niu Xiaofeng,et al. An experimental and theoretical study of the influence of surfactant on the preparation and stability of ammonia-water nanofluids[J]. International Journal of Refrigeration,2011,34(8):1741-1748.
[17] 宋晓岚,邱冠周,史训达,等. 混合表面活性剂分散纳米CeO₂颗粒的协同效应[J]. 湖南大学学报:自然科学版,2005,32(5):95-99.
[18] 王赛,石西昌. 表面活性剂对纳米氧化锌粒径和形貌的影响研究[J]. 化工新型材料,2007,35(8):43-47.
[19] 莫松平,陈颖,李兴,等. 表面活性剂对二氧化钛纳米流体分散性的影响[J]. 材料导报B:研究篇,2013,27(6):43-46.
[20] 包楚才,李超,皮振邦. 表面活性剂对CdSSe-H₂O纳米流体稳定性影响[J]. 化学工程与装备,2012,7:32-36.
[21] 孙玉利,左敦稳,王宏宇,等. 表面活性剂对纳米CeO₂在水介质中分散性能的影响[J]. 南京航空航天大学学报,2011,43(1):71-74.
[22] 陈金媛,李娜,方金凤. 表面活性剂对纳米TiO₂在水中分散与沉降性能的影响[J]. 浙江工业大学学报,2012,40(6):595-598.
[23] 林本兰,崔升,沈晓东. 分散剂对纳米四氧化三铁磁流体稳定性的影响[J]. 无机盐工业,2011,43(8):25-28.
[24] 王良虎,向军,李菊香. 纳米流体的稳定性研究[J]. 材料导报,2011,25(17):17-20.
[25] 李强. 纳米流体强化换热机理研究[D]. 南京:南京理工大学,2004.
[26] Yang Liu,Du Kai. A thermal conductivity model for low concentrated nanofluids containing surfactants under various dispersion types[J]. International Journal of Refrigeration,2012,35(7):1978-1988.
[27] Dang Liem X,Annapureddy Harsha V R,Sun Xiuquan,et al. Understanding nanofluid stability through molecular simulation[J]. Chemical Physics Letters,2012,551:115-120.
[28] Maxwell J C. Electricity and Magnetism,PartⅡ[M]. 3rd ed. London:Clarendon Press,1904.
[29] Hamilton R L,Crosser O K. Thermal conductivity of heterogeneous two component systems[J]. Ind. Eng. Chem. Fundam.,1962,1(3):182-191.
[30] Yu W,Choi S U S. The role of interfacial layers in the enhanced thermal conductivity of nanofluids:A renovated Maxwell model[J]. J. Nanoparticle Res.,2003,5:167-171.
[31] Bhattacharya P,Saha S K,Yadav A,et al. Brownian dynamics simulation to determine the effective thermal conductivity of nanofluids[J]. J. Appl. Phys.,2004,95(11):6492-6494.
[32] Xue Q Z. Model for thermal conductivity of carbon nanotube based composites[J]. Physica B:Condens. Matter,2005,368(1-4):302-307.
[33] Leong K C,Yang C,Murshed S M S. A model for the thermal conductivity of nanofluids:The effect of interfacial layer[J]. J. Nanoparticle Res.,2006,8:245-254.
[34] Murshed S M S,Leong K C,Yang C. Investigations of thermal conductivity and viscosity of nanofluids[J]. Int. J. Therm. Sci.,2008,47:560-568.
[35] Li X f,Zhu D S,Wang X J,et al. Thermal conductivity enhancement dependent pH and chemical surfactant for Cu-H₂O nanofluids[J]. Thermochimica acta,2008,469(1-2):98-103.
[36] Zhou Mingzheng,Xia Guodong,Li Jian,et al. Analysis of factors influencing thermal conductivity and viscosity in different kinds of surfactant solutions[J]. Experimental Thermal and Fluid Science,2012,36:22–29.
[37] Wusiman Kuerbanjiang,Jeong Hyomin,Tulugan Keilmu,et al. Thermal performance of multi-walled carbon nanotubes (MWCNTs) in aqueous suspensions with surfactants SDBS and SDS[J]. International Communications in Heat and Mass Transfer,2013,41:28-33.
[38] 杨采影. 水基纳米流体分散稳定性及其对导热能力的影响[D]. 广州:广东工业大学,2011.
[39] Einstein A. Investigation on the theory of the brownian movement[R]. New York:Dover,1956.
[40] Batchelor G K. The effect of Brownian motion on the bulk stress in a suspension of spherical particles[J]. J. Fluid Mech.,1977,83(1):97-117.
[41] Hosseini S M,Moghadassi A R,Henneke D E. A new dimensionless group model for determining the viscosity of nanofluids[J]. Journal of Thermal Analysis and Calorimetry,2010,100(3):873-877.
[42] Yang Liu,Du Kai,Ding Yuehong,et al. Viscosity-prediction models of ammonia water nanofluids based on various dispersion types[J].Powder Technology,2012,215/216:210-218.
[43] Li Xinfang,Zhu Dongsheng,Wang Xianju. Experimental investigation on viscosity of Cu-H₂O nanofluids[J]. Journal of Wuhan University of Technology:Materials Science Edition,2009,24(1):98-103.
[44] Ghadimi A,Metselaar I H. The influence of surfactant and ultrasonic processing on improvement of stability,thermal conductivity and viscosity of Titania nanofluid[J]. Experimental Thermal and Fluid Science,2013,51:1-9.