化工进展

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我国餐厨废油资源化利用现状及展望

王鹏照,刘熠斌,杨朝合   

  1. 中国石油大学重质油国家重点实验室,山东 青岛 266580
  • 出版日期:2014-04-05 发布日期:2014-04-05

Added value chemicals from used cooking oil:Advances and prospects

WANG Pengzhao,LIU Yibin,YANG Chaohe   

  1. State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Qingdao 266580,Shandong,China
  • Online:2014-04-05 Published:2014-04-05

摘要: 餐厨废油具有明显的废物与资源两重性,研究开发餐厨废油利用新技术,可有效解决食品安全、废油污染等问题。本文介绍了我国餐厨废油的组成性质及其回收现状,阐述了利用餐厨废油生产第一代和第二代生物柴油、表面活性剂、洗涤剂、脂肪酸、合成气等化工产品的工艺现状。由于餐厨废油组成复杂多样,净化处理难度大,因此以其作为原料生产化工产品时,工艺条件苛刻,生产规模小,短期难以实现工业化,而以餐厨废油生产生物柴油表现出了明显的优势。其中利用餐厨废油制备的第一代生物柴油存在热值低、抗氧化稳定性差等缺点,而加氢裂化、催化裂化、微波极化脂肪酸皂类脱羧成烃等工艺制备的第二代生物柴油产品性质更加优良,经济优势显著,具有很大的发展潜力。在综合对比各类生产工艺及其产品优缺点的基础上,对废油资源化利用的发展前景进行了展望。

关键词: 餐厨废油, 生物柴油, 化工产品

Abstract: Considering the duality (waste and resource) of used cooking oil (UCO),studies on utilization technologies of used cooking oil can effectively address many social issues,such as food safety,waste oil pollution,etc. The different chemical compositions and recovery status of UCO are presented,and various added value chemicals like first- and second-generation biodiesel,surfactants,detergents,fatty acids,synthesis gas,and other chemical products from used cooking oil are also summarized. Due to the complicated compositions of UCO provided,the industrialization of chemicals preparation from UCO is limited by harsh process condition and small-scale production,while the biodiesel from UCO shows significant advantages. The fuel properties of first- and second-generation biodiesel fuel from used cooking oil are also reviewed and compared with each other. The first-generation biodiesel has a low cetane number and oxidation stability,while the second-generation biodiesel fuels prepared by advanced technological methods like hydrocracking,catalytic cracking,and polarizing the carboxyl group of fatty acid salt with microwave radiation have better quality and economic advantage. After reviewing some major UCO processes and their advantages/disadvantages,the development prospect of UCO is discussed.

Key words: used cooking oil, biodiesel, chemicals

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