化工进展

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介孔材料Al-SBA-15的合成研究进展

李祥珍,王晓钟,刘 瑜,陈 伟,黄 璐   

  1. 太原理工大学精细化工研究所,山西 太原 030024
  • 出版日期:2013-07-05 发布日期:2013-07-05

Research progress in the synthesis of mesoporous Al-SBA-15 material

LI Xiangzhen,WANG Xiaozhong,LIU Yu,CHEN Wei,HUANG Lu   

  1. Institute of Special Chemicals,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China
  • Online:2013-07-05 Published:2013-07-05

摘要: Al掺杂的介孔SBA-15材料不仅保持了介孔SBA-15材料原有的结构特征,还赋予了材料新的催化活性位,成为近年来介孔材料领域最为活跃的研究对象之一。本文详细阐述了近十几年来Al-SBA-15介孔材料的研究进展,比较了各合成方法之间的区别,并讨论了Si/Al摩尔比、合成方法和反应条件等因素对Al原子嵌入SBA-15介孔骨架的效率以及介孔材料的有序性、稳定性和酸性的影响。同时总结出加深对合成机理的研究,优化合成过程,使用较简单且高效的方法制备具有完全晶化骨架和较高Al含量的介孔Al-SBA-15是未来介孔Al-SBA-15合成研究的新方向。

关键词: 介孔材料, Al-SBA-15, 合成, 性质, 掺杂, 介孔材料, Al-SBA-15

Abstract: Doping of Al into the mesoporous SBA-15 material has become one of the most active study objects in the field of mesoporous materials,because it not only holds the features of original structure of mesoporous SBA-15,but also gives the material a new catalytic active site. This paper was aimed to elaborate the research progress in mesoporous Al-SBA-15 material in recent decades,to compare the differences among various synthesis methods,and to discuss the factors,such as the molar ratio of Si/Al,synthetic methods and reaction conditions,which influence the efficiency of the Al atoms incorpoarated into mesoporous framework of SBA-15 and the orders,stability and acidity of mesoporous material. Meanwhile,it is concluded that deepening the study of synthesis mechanism,optimizing the synthetic process,and using a simpler and more efficient method for the preparation of mesoporous Al-SBA -15 with fully crystalline framework and higher Al content,are among new directions of the synthesis of mesoporous Al-SBA -15.

Key words: mesoporous material, Al-SBA-15, preparation, properties, doping, mesoporous material, Al-SBA-15

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