丁二酸发酵液色素的活性炭吸附过程

化工进展

丁二酸发酵液色素的活性炭吸附过程

胡俊铎1，2，洪怡1，2，吴昊2，任晓乾1，姜岷1，2，雷科2

1南京工业大学化学化工学院，材料化学工程国家重点实验室；2 南京工业大学生物与制药工程学院，江苏南京 211816

出版日期:2012-12-05 发布日期:2012-12-05

Adsorption process of the pigment from succinic acid fermentation broth on activated carbon

HU Junduo1，2，HONG Yi1，2，WU Hao2，REN Xiaoqian1，JIANG Min1，2，LEI Ke2

1 State Key Laboratory of Materials-Oriented Chemical Engineering，College of Chemistry and Chemical Engineering，Nanjing University of Technology; 2 College of Biotechnology and Pharmaceutical Engineering，Nanjing University of Technology，Nanjing 211816，Jiangsu，China

Online:2012-12-05 Published:2012-12-05

摘要/Abstract

摘要： 以丁二酸发酵液为研究体系，采用静态吸附法研究了颗粒活性炭对丁二酸发酵液色素的吸附过程；并考察了搅拌转速对活性炭吸附色素过程的影响。结果表明活性炭对色素的吸附是以物理吸附为主的吸热过程，其吸附热为12.54 kJ?mol?1，适宜的脱色温度有利于提高活性炭的利用效率，热水解吸可实现活性炭的再生；活性炭对色素的初始吸附速度随搅拌转速增加而增加；在活性炭快速吸附阶段，液膜扩散为主要控速步骤，增加搅拌转速可减少颗粒液膜层的厚度，有效扩散系数随之增加。通过考察进料对活性炭层析柱的脱色效果的影响，结果表明合适的进料流速能提过活性炭的利用率。

关键词: 活性炭, 丁二酸发酵液, 脱色, 热力学

Abstract: By taking the succinic acid fermentation broth as the research object，the adsorption process of the pigment from succinic acid fermentation broth on activated carbon was studied by static absorption method，and the effects of pigments concentration and rotation speed on adsorption were also discussed. The results showed that the adsorption was endothermic process，and physical adsorption was the dominant，the isosteric heat of adsorption is 12.54 kJ/mol，suitable temperature is helpful to increase the adsorption efficiency. The activated carbon can be reused by using hot water. The initial absorbing rate of the activated carbon increased with the rotation speed. Film diffusion was the major rate-controlling step in the fast adsorption phases，the thickness of liquid film decreased with rotation speed，and the effective diffusion coefficient increased，which suggested the adsorption properties of activated carbon column could be improved by optimizing flow rate. And the result showed that the suitable flow ratio was beneficial to improve the utilization ratio of activated carbon.

Key words: activated carbon, succinic acid fermentation broth, decoloration, thermodynamics

胡俊铎1，2，洪怡1，2，吴昊2，任晓乾1，姜岷1，2，雷科2. 丁二酸发酵液色素的活性炭吸附过程[J]. 化工进展.

HU Junduo1，2，HONG Yi1，2，WU Hao2，REN Xiaoqian1，JIANG Min1，2，LEI Ke2. Adsorption process of the pigment from succinic acid fermentation broth on activated carbon[J]. Chemical Industry and Engineering Progree.

[1]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[2]	董佳宇, 王斯民. 超声强化对二甲苯结晶特性及调控机理实验[J]. 化工进展, 2023, 42(9): 4504-4513.
[3]	张丽宏, 金要茹, 程芳琴. 煤气化渣资源化利用[J]. 化工进展, 2023, 42(8): 4447-4457.
[4]	张耀杰, 张传祥, 孙悦, 曾会会, 贾建波, 蒋振东. 煤基石墨烯量子点在超级电容器中的应用[J]. 化工进展, 2023, 42(8): 4340-4350.
[5]	杨许召, 李庆, 袁康康, 张盈盈, 韩敬莉, 吴诗德. 含Gemini离子液体低共熔溶剂热力学性质[J]. 化工进展, 2023, 42(6): 3123-3129.
[6]	马润梅, 杨海超, 李正大, 李双喜, 赵祥, 章国庆. 表面强化镀层对高速轴承腔密封端面变形及摩擦磨损影响分析[J]. 化工进展, 2023, 42(4): 1688-1697.
[7]	田芳, 郭光, 丁克强, 杨凤, 刘翀, 王慧雅. 降解偶氮染料嗜盐菌的分离、降解特性及机制[J]. 化工进展, 2023, 42(4): 2115-2121.
[8]	贺山明, 潘界昌, 徐国钻, 李文君, 梁勇. 粗钨酸钠溶液亚铁盐沉淀法除铬、钒的热力学分析及实验验证[J]. 化工进展, 2023, 42(4): 2171-2179.
[9]	邢献军, 罗甜, 卜玉蒸, 马培勇. H₃PO₄活化核桃壳制备活性炭及在Cr(Ⅵ)吸附中的应用[J]. 化工进展, 2023, 42(3): 1527-1539.
[10]	王晓月, 张伟敏, 姚正阳, 郭晓宏, 李聪明. 逆水煤气变换反应研究进展[J]. 化工进展, 2023, 42(3): 1583-1594.
[11]	孙潇, 朱光涛, 裴爱国. 氢液化装置产业化与研究进展[J]. 化工进展, 2023, 42(3): 1103-1117.
[12]	刘雅娟. 浸没式PAC-AMBRs系统中PAC缓解膜污染的研究进展[J]. 化工进展, 2023, 42(1): 457-468.
[13]	刘楠, 胡一铭, 杨颖, 李红晋, 高竹青, 郝秀丽. 废旧聚丙烯/活性炭微波共裂解制取可燃裂解气与轻质裂解油[J]. 化工进展, 2022, 41(S1): 150-159.
[14]	张辛亥, 赵思琛, 朱辉, 张首石, 王凯. 多种碳材料与碳酸钠复合后脱硫性能对比[J]. 化工进展, 2022, 41(S1): 424-435.
[15]	陈钰, 刘冲, 邱于荟, 贲梓欣, 牟天成. 离子液体和低共熔溶剂绿色回收废旧锂离子电池的研究进展[J]. 化工进展, 2022, 41(S1): 485-496.