金属氧化物催化固态储氢材料吸放氢性能的研究进展

doi:10.16085/j.issn.1000-6613.2024-1929

化工进展 ›› 2025, Vol. 44 ›› Issue (12): 6996-7018.DOI: 10.16085/j.issn.1000-6613.2024-1929

• 材料科学与技术 • 上一篇

金属氧化物催化固态储氢材料吸放氢性能的研究进展

吴国界¹^,²(), 刘泉宇¹, 彭程¹, 夏思奇¹, 黄东方¹, 周权宝³, 吕朋¹^,²(), 王学刚¹^,²()

^1.东华理工大学水资源与环境工程学院，江西南昌 330013
^2.地下水污染成因与修复江西省重点实验室（东华理工大学），江西南昌 330013
^3.东华理工大学化学与材料科学学院，江西南昌 330013

收稿日期:2024-11-22 修回日期:2025-01-31 出版日期:2025-12-25 发布日期:2026-01-06
通讯作者: 吕朋,王学刚
作者简介:吴国界（2000—），男，硕士研究生，研究方向为环境友好功能材料。E-mail：2251697307@qq.com。
基金资助:
国家自然科学基金(12205042)

Research progress on hydrogen absorption and desorption performance of metal oxide catalyzed solid-state hydrogen storage materials

WU Guojie¹^,²(), LIU Quanyu¹, PENG Cheng¹, XIA Siqi¹, HUANG Dongfang¹, ZHOU Quanbao³, LYU Peng¹^,²(), WANG Xuegang¹^,²()

^1.School of Water Resources and Environmental Engineering, East China University of Technology, Nanchang 330013, Jiangxi, China
^2.Jiangxi Provincial Key Laboratory of Genesis and Remediation of Groundwater Pollution (East China University of Technology), Nanchang 330013, Jiangxi, China
^3.School of Chemistry and Materials Science, East China University of Technology, Nanchang 330013, Jiangxi, China

Received:2024-11-22 Revised:2025-01-31 Online:2025-12-25 Published:2026-01-06
Contact: LYU Peng, WANG Xuegang

摘要/Abstract

摘要：

固态储氢技术是一种采用固态储氢材料来储存氢气的方式，具有储氢密度高、吸放氢压力温和及安全性高等优点。本文提出传统的固态储氢材料面临着活化难、吸放氢速率慢及循环稳定性差等显著问题，严重阻碍氢气的规模化应用。近年来，研究人员发现引入不同金属氧化物作为催化剂，可以显著改善固态储氢材料的活化、吸放氢及循环稳定等性能。文中综述了相关研究表明：通过调控金属氧化物催化剂的种类、添加量及分布状态，可有效改变固态储氢材料的表面结构，降低吸放氢活化能，进而提升储氢性能，但是金属氧化物对固态储氢材料的催化机理仍然缺乏明确的理论指导。因此，文中提出需要对金属氧化物催化剂不断地进行设计、优化及调控，筛选出对固态储氢材料具有优异催化性能的金属氧化物，最终实现金属氧化物催化剂在固态储氢材料领域的规模化应用。

关键词: 固态储氢材料, 金属氧化物, 催化剂, 吸放氢动力学, 储氢技术

Abstract:

Solid hydrogen storage technology is a way to store hydrogen by using solid hydrogen storage materials, which has the advantages of high hydrogen storage density, mild hydrogen absorption and desorption pressure and high safety. However, the traditional solid hydrogen storage materials are faced with significant problems such as difficult activation, slow reaction rate of hydrogen absorption and desorption and poor circulation stability, which seriously hinder the large-scale application of hydrogen. In recent years, researchers found that the introduction of various metal oxides as catalysts can significantly improve the activation, hydrogen absorption and desorption, and cycling stability of hydrogen storage materials. Relevant studies showed that by regulating the type, addition amount and distribution of metal oxide catalysts, the surface structure of hydrogen storage materials can be changed, the activation energy of hydrogen storage materials can be effectively reduced and their hydrogen storage properties can be improved. However, there was still a lack of clear theoretical guidance on the catalytic mechanism of metal oxides for solid hydrogen storage materials. Therefore, researchers should constantly design, optimize and regulate metal oxide catalysts to screen out metal oxides with excellent catalytic performance for solid hydrogen storage materials. Finally, the large-scale application of metal oxide catalyst in the field of solid hydrogen storage materials would be realized.

Key words: hydrogen storage materials, metal oxide, catalyst, hydrogen absorption and desorption kinetics, hydrogen storage technology

中图分类号:

TG139⁺.7

吴国界, 刘泉宇, 彭程, 夏思奇, 黄东方, 周权宝, 吕朋, 王学刚. 金属氧化物催化固态储氢材料吸放氢性能的研究进展[J]. 化工进展, 2025, 44(12): 6996-7018.

WU Guojie, LIU Quanyu, PENG Cheng, XIA Siqi, HUANG Dongfang, ZHOU Quanbao, LYU Peng, WANG Xuegang. Research progress on hydrogen absorption and desorption performance of metal oxide catalyzed solid-state hydrogen storage materials[J]. Chemical Industry and Engineering Progress, 2025, 44(12): 6996-7018.

图/表 17

参考文献 81

[82]	LEE Gil-Jae, SHIM Jae-Hyeok, CHO Young Whan, et al. Reversible hydrogen storage in NaAlH₄ catalyzed with lanthanide oxides[J]. International Journal of Hydrogen Energy, 2007, 32(12): 1911-1915.
[83]	LIU Jinming, YONG Hui, ZHAO Yang, et al. Synergistic enhancement of hydrogen storage performance of Mg-La-Ni alloy by CeO₂@C composite catalyst[J]. International Journal of Hydrogen Energy, 2024, 55: 141-152.
[84]	LI Xia, ZHANG Yanghuan, YANG Tai, et al. Hydriding/dehydriding properties of NdMgNi alloy with catalyst CeO₂ [J]. Journal of Rare Earths, 2016, 34(4): 407-412.
[85]	YUAN Zeming, SUI Yongqi, ZHAI Tingting, et al. Influence of CeO₂ nanoparticles on microstructure and hydrogen storage performance of Mg-Ni-Zn alloy[J]. Materials Characterization, 2021, 178: 111248.
[86]	ZHANG Yanghuan, LI Yaqin, SHANG Hongwei, et al. Hydrogen storage performance of the as-milled YMgNi alloy catalyzed by CeO₂ [J]. International Journal of Hydrogen Energy, 2018, 43(3): 1643-1650.
[87]	YIN Yi, LI Bo, YUAN Zeming, et al. Enhanced hydrogen storage performance of Mg-Cu-Ni system catalyzed by CeO₂ additive[J]. Journal of Rare Earths, 2020, 38(9): 983-993.
[88]	ISMAIL M, HALIM YAP F A, YAHYA M S. Improved hydrogen storage properties of Mg-Li-Al-H composite system by milling with Fe₂O₃ powder[J]. Advanced Powder Technology, 2017, 28(9): 2151-2158.
[89]	MUSTAFA N S, ISMAIL M. Enhanced hydrogen storage properties of 4MgH₂+LiAlH₄ composite system by doping with Fe₂O₃ nanopowder[J]. International Journal of Hydrogen Energy, 2014, 39(15): 7834-7841.
[90]	LI Ziliang, LI Ping, WAN Qi, et al. Dehydrogenation improvement of LiAlH₄ catalyzed by Fe₂O₃ and Co₂O₃ nanoparticles[J]. The Journal of Physical Chemistry C, 2013, 117(36): 18343-18352.
[91]	TOME Kudzaishe Caren, XI Senliang, FU Yuanyi, et al. Remarkable catalytic effect of Ni and ZrO₂nanoparticles on the hydrogen sorption properties of MgH₂ [J]. International Journal of Hydrogen Energy, 2022, 47(7): 4716-4724.
[92]	GUEMOU Samuel, GAO Dongqiang, WU Fuying, et al. Enhanced hydrogen storage kinetics of MgH₂ by the synergistic effect of Mn₃O₄/ZrO₂ nanoparticles[J]. Dalton Transactions, 2023, 52(3): 609-620.
[93]	SHUKLA Vivek, YADAV Thakur Prasad. Notable catalytic activity of CuO nanoparticles derived from metal-organic frameworks for improving the hydrogen sorption properties of MgH₂ [J]. International Journal of Energy Research, 2022, 46(9): 12804-12819.
[94]	RATHER Sami ullah. Hydrogen uptake of cobalt and copper oxide-multiwalled carbon nanotube composites [J]. International Journal of Hydrogen Energy, 2017, 42(16): 11553-11559.
[95]	ZHANG Yanhui, JIAO Lifang, YUAN Huatang, et al. Study on the electrochemical properties of MgNi-CuO hydrogen storage composite materials[J]. Journal of Alloys and Compounds, 2009, 481(1/2): 639-643.
[96]	JUBAIR Ahammed, RAHMAN Md Akhlakur, KHAN Md Maksudur Rahman, et al. Catalytic role of binary oxides (CuO and Al₂O₃) on hydrogen storage in MgH₂ [J]. Environmental Progress & Sustainable Energy, 2023, 42(1): e13940.
[97]	ABDELLATIEF M, CAMPOSTRINI R, LEONI M, et al. Effects of SnO₂ on hydrogen desorption of MgH₂ [J]. International Journal of Hydrogen Energy, 2013, 38(11): 4664-4669.
[98]	LI Ping, WAN Qi, LI Ziliang, et al. MgH₂ dehydrogenation properties improved by MnFe₂O₄ nanoparticles[J]. Journal of Power Sources, 2013, 239: 201-206.
[99]	ZHAI Fuqiang, LI Ping, SUN Aizhi, et al. Significantly improved dehydrogenation of LiAlH₄ destabilized by MnFe₂O₄ nanoparticles[J]. The Journal of Physical Chemistry C, 2012, 116(22): 11939-11945.
[100]	WAN Qi, LI Ping, LI Ziliang, et al. Improved hydrogen storage performance of MgH₂-LiAlH₄ composite by addition of MnFe₂O₄ [J]. The Journal of Physical Chemistry C, 2013, 117(51): 26940-26947.
[101]	IDRIS N H, MUSTAFA N S, ISMAIL M. MnFe₂O₄ nanopowder synthesised via a simple hydrothermal method for promoting hydrogen sorption from MgH₂ [J]. International Journal of Hydrogen Energy, 2017, 42(33): 21114-21120.
[102]	WAN Qi, LI Ping, LI Ziliang, et al. NaAlH4 dehydrogenation properties enhanced by MnFe₂O₄ nanoparticles[J]. Journal of Power Sources, 2014, 248: 388-395.
[103]	MUSTAFA N S, SAZELEE N A, ALI N A, et al. Enhancement of hydrogen storage properties of NaAlH₄ catalyzed by CuFe₂O₄ [J]. International Journal of Hydrogen Energy, 2023, 48(90): 35197-35205.
[104]	ISMAIL M, MUSTAFA N S, ALI N A, et al. The hydrogen storage properties and catalytic mechanism of the CuFe₂O₄-doped MgH₂ composite system[J]. International Journal of Hydrogen Energy, 2019, 44(1): 318-324.
[105]	LI Ping, LI Ziliang, ZHAI Fuqiang, et al. NiFe₂O₄ nanoparticles catalytic effects of improving LiAlH₄ dehydrogenation properties[J]. The Journal of Physical Chemistry C, 2013, 117(49): 25917-25925.
[106]	HUANG Yihui, LI Ping, WAN Qi, et al. Improved dehydrogenation performance of NaAlH₄ using NiFe₂O₄ nanoparticles[J]. Journal of Alloys and Compounds, 2017, 709: 850-856.
[107]	HALIM YAP F A, ALI N A, IDRIS N H, et al. Catalytic effect of MgFe₂O₄ on the hydrogen storage properties of Na₃AlH₆-LiBH₄ composite system[J]. International Journal of Hydrogen Energy, 2018, 43(45): 20882-20891.
[108]	ALI N A, IDRIS N H, SAZELEE N A, et al. Catalytic effects of MgFe₂O₄ addition on the dehydrogenation properties of LiAlH₄ [J]. International Journal of Hydrogen Energy, 2019, 44(52): 28227-28234.
[109]	ALI N A, IDRIS Nurul Hayati, DIN M F MD, et al. Nanolayer-like-shaped MgFe₂O₄ synthesised via a simple hydrothermal method and its catalytic effect on the hydrogen storage properties of MgH₂ [J]. RSC Advances, 2018, 8(28): 15667-15674.
[110]	SAZELEE N A, YAHYA M S, IDRIS N H, et al. Desorption properties of LiAlH₄ doped with LaFeO₃ catalyst[J]. International Journal of Hydrogen Energy, 2019, 44(23): 11953-11960.
[111]	Nurul Amirah ALI, AHMAD Muhammad Amirul Nawi, YAHYA Muhammad Syarifuddin, et al. Improved dehydrogenation properties of LiAlH₄ by addition of nanosized CoTiO₃ [J]. Nanomaterials, 2022, 12(21): 3921.
[112]	Nurul Amirah ALI, YAHYA Muhammad Syarifuddin, SAZELEE Noratiqah, et al. Influence of nanosized CoTiO₃ synthesized via a solid-state method on the hydrogen storage behavior of MgH₂ [J]. Nanomaterials, 2022, 12(17): 3043.
[113]	ALI N A, YUSNIZAM N Y, SAZELEE N A, et al. Inclusion of CoTiO₃ to ameliorate the re/dehydrogenation properties of the Mg-Na-Al system[J]. Journal of Magnesium and Alloys, 2024, 12(3): 1215-1226.
[114]	MA Chao, ZHAO Baozhou, YUAN Jianguang, et al. Superior synergistic effect derived from MnTiO₃ nanodiscs for the reversible hydrogen storage properties of MgH₂ [J]. Journal of Alloys and Compounds, 2023, 968: 171774.
[115]	YAHYA M S, ISMAIL M. Catalytic effect of SrTiO₃ on the hydrogen storage behaviour of MgH₂ [J]. Journal of Energy Chemistry, 2019, 28: 46-53.
[116]	ISMAIL M, SAZELEE N A, ALI N A, et al. Catalytic effect of SrTiO₃ on the dehydrogenation properties of LiAlH₄ [J]. Journal of Alloys and Compounds, 2021, 855: 157475.
[117]	SAZELEE Noratiqah, MUSTAFA Nurul Shafikah, YAHYA Muhammad Syarifuddin, et al. Enhanced dehydrogenation performance of NaAlH₄ by the addition of spherical SrTiO₃ [J]. International Journal of Energy Research, 2021, 45(6): 8648-8658.
[1]	OUYANG Liuzhang, LIU Fen, WANG Hui, et al. Magnesium-based hydrogen storage compounds: A review[J]. Journal of Alloys and Compounds, 2020, 832: 154865.
[2]	ZHANG Yanghuan, JIA Zhichao, YUAN Zeming, et al. Development and application of hydrogen storage[J]. Journal of Iron and Steel Research, International, 2015, 22(9): 757-770.
[3]	SCHLAPBACH L, ZÜTTEL A. Hydrogen-storage materials for mobile applications[J]. Nature, 2001, 414(6861): 353-358.
[4]	崔祥勇, 王阳峰. “双碳”背景下石化企业氢气系统协同优化技术研究及应用[J]. 广东化工, 2023, 50(12): 85-88.
	CUI Xiangyong, WANG Yangfeng. Research and application of collaborative optimization technology for hydrogen system in refinery under the background of “Double Carbon” [J]. Guangdong Chemical Industry, 2023, 50(12): 85-88.
[5]	俞和胜, 祁海鹰, 谭忠超. “双碳”背景下传统化石能源脱碳制氢增值化利用技术[J]. 清华大学学报(自然科学版), 2023, 63(8): 1226-1235.
	YU Hesheng, QI Haiying, TAN Zhongchao. Decarbonization, hydrogen production, and value-added utilization of conventional fossil fuels under the background of “double-carbon” [J]. Journal of Tsinghua University (Science and Technology), 2023, 63(8): 1226-1235.
[6]	RASUL M G, HAZRAT M A, SATTAR M A, et al. The future of hydrogen: Challenges on production, storage and applications[J]. Energy Conversion and Management, 2022, 272: 116326.
[7]	廖红波, 张雪霞, 岳嘉玲, 等. 氢气储运技术发展及展望[J]. 太阳能学报, 2024, 45(11): 691-699.
	LIAO Hongbo, ZHANG Xuexia, YUE Jialing, et al. Development and prospect of hydrogen storage and transportation technology[J]. Acta Energiae Solaris Sinica, 2024, 45(11): 691-699.
[8]	韩利, 李琦, 冷国云, 等. 氢能储存技术最新进展[J]. 化工进展, 2022, 41(S1): 108-117.
	HAN Li, LI Qi, LENG Guoyun, et al. Latest research progress of hydrogen energy storage technology[J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 108-117.
[9]	PETITPAS Guillaume. Simulation of boil-off losses during transfer at a LH₂ based hydrogen refueling station [J]. International Journal of Hydrogen Energy, 2018, 43(46): 21451-21463.
[10]	ALLENDORF Mark D, STAVILA Vitalie, SNIDER J L, et al. Challenges to developing materials for the transport and storage of hydrogen[J]. Nature Chemistry, 2022, 14(11): 1214-1223.
[11]	刘木子, 史柯柯, 赵强, 等. 固体储氢材料的研究进展[J]. 化工进展, 2023, 42(9): 4746-4769.
	LIU Muzi, SHI Keke, ZHAO Qiang, et al. Research progress of solid hydrogen storage materials[J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4746-4769.
[12]	刘泉宇, 彭程, 黄东方, 等. 表面处理技术在储氢材料中的应用研究进展[J]. 材料导报, 2024, 38(20): 25-36.
	LIU Quanyu, PENG Cheng, HUANG Dongfang, et al. Research progress on the application of surface treatment technology in hydrogen storage materials[J]. Materials Review, 2024, 38(20): 25-36.
[13]	高佳佳, 米媛媛, 周洋, 等. 新型储氢材料研究进展[J]. 化工进展, 2021, 40(6): 2962-2971.
	GAO Jiajia, MI Yuanyuan, ZHOU Yang, et al. Recent developments in new hydrogen storage materials[J]. Chemical Industry and Engineering Progress, 2021, 40(6): 2962-2971.
[14]	SUN Ze, LU Xiong, NYAHUMA Farai Michael, et al. Enhancing hydrogen storage properties of MgH₂ by transition metals and carbon materials: A brief review[J]. Frontiers in Chemistry, 2020, 8: 552.
[15]	邓文琪. 金属氧化物对镁基材料储氢性能影响及机理研究[D]. 沈阳: 沈阳工业大学, 2024.
	Deng Wenqi. Influence and mechanism of metal oxides on the hydrogen storageperformance of magnesium-based[D]. Shenyang: Shenyang University of Technology, 2024.
[16]	ALI N A, ISMAIL M. Modification of NaAlH₄ properties using catalysts for solid-state hydrogen storage: A review[J]. International Journal of Hydrogen Energy, 2021, 46(1): 766-782.
[17]	顾婷婷, 顾坚, 张喻, 等. 金属硼氢化物基固态储氢体系[J]. 化学进展, 2020, 32(5): 665-686.
[118]	ZHANG Lingchao, WANG Ke, LIU Yongfeng, et al. Highly active multivalent multielement catalysts derived from hierarchical porous TiNb₂O₇ nanospheres for the reversible hydrogen storage of MgH₂ [J]. Nano Research, 2021, 14(1): 148-156.
[119]	HU Song, ZHANG Huanhuan, YUAN Zhenluo, et al. Ultrathin K₂Ti₈O₁₇ nanobelts for improving the hydrogen storage kinetics of MgH₂ [J]. Journal of Alloys and Compounds, 2021, 881: 160571.
[120]	LONG Shiteng, QIN Yang, FU Huafeng, et al. Hydrogen storage properties of MgH₂ modified by efficient Co₃V₂O₈ catalyst[J]. Separation and Purification Technology, 2024, 341: 126901.
[121]	SAZELEE N A, RATHER Sami-ullah, SININ A M, et al. Improved dehydrogenation performance of LiAlH₄ doped with BaMnO₃ [J]. Heliyon, 2024, 10(10): e31190.
[122]	LIU Heng, ZHAI Xiaojie, LI Zhe, et al. Improved electrochemical hydrogen storage performance of Ti₄₉Zr₂₆Ni₂₅ quasicrystal alloy by doping with mesoporous α-Fe₂O₃ particles[J]. International Journal of Hydrogen Energy, 2018, 43(15): 7447-7455.
[17]	GU Tingting, GU Jian, ZHANG Yu, et al. Metal borohydride-based system for solid-state hydrogen storage[J]. Progress in Chemistry, 2020, 32(5): 665-686.
[18]	ZHANG Yanghuan, LI Chen, YUAN Zeming, et al. Research progress of TiFe-based hydrogen storage alloys[J]. Journal of Iron and Steel Research International, 2022, 29(4): 537-551.
[19]	吕朋, 周兴盛, 刘芝辰, 等. 基于机械形变方法的TiFe基储氢合金的研究进展[J]. 东华理工大学学报(自然科学版), 2021, 44(1): 90-95.
	Peng LYU, ZHOU Xingsheng, LIU Zhichen, et al. Research progress of TiFe-based hydrogen storage alloys processed by mechanical deformation method[J]. Journal of East China University of Technology (Natural Science), 2021, 44(1): 90-95.
[20]	RUI Zebao, TANG Minni, JI Weikang, et al. Insight into the enhanced performance of TiO₂ nanotube supported Pt catalyst for toluene oxidation[J]. Catalysis Today, 2017, 297: 159-166.
[21]	LIU Guozhu, TIAN Yajie, ZHANG Bofeng, et al. Catalytic combustion of VOC on sandwich-structured Pt@ZSM-5 nanosheets prepared by controllable intercalation[J]. Journal of Hazardous Materials, 2019, 367: 568-576.
[22]	DU Jinpeng, QU Zhenping, DONG Cui, et al. Low-temperature abatement of toluene over Mn-Ce oxides catalysts synthesized by a modified hydrothermal approach[J]. Applied Surface Science, 2018, 433: 1025-1035.
[23]	FENG Xinyi, GUO Jiaxiu, WEN Xinru, et al. Enhancing performance of Co/CeO₂ catalyst by Sr doping for catalytic combustion of toluene[J]. Applied Surface Science, 2018, 445: 145-153.
[24]	王旭凤, 刘建. 掺杂金属氧化物对Mg基储氢合金性能的影响[J]. 稀土, 2018, 39(5): 122-134.
	WANG Xufeng, LIU Jian. Effect of doping of metal oxides on performance of Mg-based hydrogen storage alloy[J].Chinese Rare Earths, 2018, 39(5): 122-134.
[25]	蔡浩, 顾昊, 朱云峰, 等. 催化剂对镁基储氢材料储氢性能影响的研究进展[J]. 材料导报, 2008, 22(11): 115-119.
	CAI Hao, GU Hao, ZHU Yunfeng, et al. Research progress in the influence of catalysts on hydrogen storage property of magnesium-based hydrogen storage materials[J]. Materials Review, 2008, 22(11): 115-119.
[26]	王诗雯, 鲁杨帆, 丁朝, 等. Ti基催化剂改性Mg基储氢材料的研究进展[J]. 稀有金属, 2023, 47(12): 1642-1656.
	WANG Shiwen, LU Yangfan, DING Zhao, et al. Research progress on Ti-based catalysts modified Mg-based hydrogen storage materials[J].Chinese Journal of Rare Metals, 2023, 47(12): 1642-1656.
[27]	任壮禾, 张欣, 高明霞, 等. Ti基催化剂改性的NaAlH₄储氢材料研究进展[J]. 稀有金属, 2021, 45(5): 569-582.
	REN Zhuanghe, ZHANG Xin, GAO Mingxia, et al. Research progress in Ti-based catalysts-modified NaAlH4 hydrogen storage materials[J]. Chinese Journal of Rare Metals, 2021, 45(5): 569-582.
[28]	徐晓红. 复合金属氧化物多孔材料限域催化协同改善LiBH₄储氢性能研究[D]. 天津: 南开大学, 2017.
	XU Xiaohong. An investigation on the hydrogen storage properties of LiBH₄ catalyzed and confined by the porous mixed metal oxide materials[D]. Tianjin: Nankai University, 2017.
[29]	OELERICH W, KLASSEN T, BORMANN R. Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials[J]. Journal of Alloys and Compounds, 2001, 315(1/2): 237-242.
[30]	ROWSELL Jesse L C, YAGHI Omar M. Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks[J]. Journal of the American Chemical Society, 2006, 128(4): 1304-1315.
[31]	PUKAZHSELVAN D, M Sterlin Leo HUDSON, SINHA A S K, et al. Studies on metal oxide nanoparticles catalyzed sodium aluminum hydride[J]. Energy, 2010, 35(12): 5037-5042.
[32]	ZHANG Xin, SHEN Zhengyang, JIAN Ni, et al. A novel complex oxide TiVO_3.5 as a highly active catalytic precursor for improving the hydrogen storage properties of MgH₂ [J]. International Journal of Hydrogen Energy, 2018, 43(52): 23327-23335.
[33]	HUANG H X, YUAN J G, ZHANG B, et al. A noteworthy synergistic catalysis on hydrogen sorption kinetics of MgH₂ with bimetallic oxide Sc₂O₃/TiO₂ [J]. Journal of Alloys and Compounds, 2020, 839: 155387.
[34]	ZHANG Liuting, NYAHUMA Farai Michael, ZHANG Haoyu, et al. Metal organic framework supported niobium pentoxide nanoparticles with exceptional catalytic effect on hydrogen storage behavior of MgH₂ [J]. Green Energy & Environment, 2023, 8(2): 589-600.
[35]	JAIN Ankur, AGARWAL Shivani, ICHIKAWA Takayuki. Catalytic tuning of sorption kinetics of lightweight hydrides: A review of the materials and mechanism[J]. Catalysts, 2018, 8(12): 651.
[36]	SAZELEE N A, IDRIS N H, DIN M F MD, et al. LaFeO₃ synthesised by solid-state method for enhanced sorption properties of MgH₂ [J]. Results in Physics, 2020, 16: 102844.
[37]	ZHUANG Guoxin, CHEN Yawen, ZHUANG Zanyong, et al. Oxygen vacancies in metal oxides: Recent progress towards advanced catalyst design[J]. Science China Materials, 2020, 63(11): 2089-2118.
[38]	BORGSCHULTE A, RECTOR J H, DAM B, et al. The role of niobium oxide as a surface catalyst for hydrogen absorption[J]. Journal of Catalysis, 2005, 235(2): 353-358.
[39]	BARKHORDARIAN Gagik, KLASSEN Thomas, Rüdiger BORMANN. Catalytic mechanism of transition-metal compounds on Mg hydrogen sorption reaction[J]. The Journal of Physical Chemistry B, 2006, 110(22): 11020-11024.
[40]	POLANSKI M, BYSTRZYCKI J. Comparative studies of the influence of different nano-sized metal oxides on the hydrogen sorption properties of magnesium hydride[J]. Journal of Alloys and Compounds, 2009, 486(1/2): 697-701.
[41]	BARTOLETTI Andrea, GONDOLINI Angela, SANGIORGI Nicola, et al. Identification of structural changes in CaCu₃Ti₄O₁₂ on high energy ball milling and their effect on photocatalytic performance[J]. Catalysis Science & Technology, 2023, 13(4): 1041-1058.
[42]	CUI Jie, WANG Hui, LIU Jiangwen, et al. Remarkable enhancement in dehydrogenation of MgH₂ by a nano-coating of multi-valence Ti-based catalysts[J]. Journal of Materials Chemistry A, 2013, 1(18): 5603-5611.
[43]	HUANG Z G, GUO Z P, CALKA A, et al. Effects of iron oxide (Fe₂O₃, Fe₃O₄) on hydrogen storage properties of Mg-based composites[J]. Journal of Alloys and Compounds, 2006, 422(1/2): 299-304.
[44]	WANG Shuai, YONG Hui, YAO Jiwei, et al. Influence of the phase evolution and hydrogen storage behaviors of Mg-RE alloy by a multi-valence Mo-based catalyst[J]. Journal of Energy Storage, 2023, 58: 106397.
[45]	OELERICH W, KLASSEN T, BORMANN R. Comparison of the catalytic effects of V, V₂O₅, VN, and VC on the hydrogen sorption of nanocrystalline Mg[J]. Journal of Alloys and Compounds, 2001, 322(1/2): L5-L9.
[46]	ZHANG Meng, XIAO Xuezhang, LUO Bosang, et al. Superior de/hydrogenation performances of MgH₂ catalyzed by 3D flower-like TiO₂@C nanostructures[J]. Journal of Energy Chemistry, 2020, 46: 191-198.
[47]	SCHWAB George-Maria. Alloy catalysts in dehydrogenation[J]. Discussions of the Faraday Society, 1950, 8: 166.
[48]	RATHI Bhawna, AGARWAL Shivani, SHRIVASTAVA Kriti, et al. Recent advances in designing metal oxide-based catalysts to enhance the sorption kinetics of magnesium hydride[J]. International Journal of Hydrogen Energy, 2024, 53: 131-162.
[49]	ZHANG Yiwen, XIAO Xuezhang, LUO Bosang, et al. Synergistic effect of LiBH₄ and LiAlH₄ additives on improved hydrogen storage properties of unexpected high capacity magnesium hydride[J]. The Journal of Physical Chemistry C, 2018, 122(5): 2528-2538.
[50]	RAFI-UD-DIN, QU Xuanhui, LI Ping, et al. Hydrogen sorption improvement of LiAlH₄ catalyzed by Nb₂O₅ and Cr₂O₃ nanoparticles[J]. The Journal of Physical Chemistry C, 2011, 115(26): 13088-13099.
[51]	WEI Xin, LI Chen, GE Qilu, et al. Improved hydrogen storage performances of the as-milled Mg-Al-Y alloy by co-doping of Tm@C (Tm=Fe, Co, Cu)[J]. Journal of Alloys and Compounds, 2022, 929: 167317.
[52]	MATANOVIC Ivana, ARTYUSHKOVA Kateryna, ATANASSOV Plamen. Understanding PGM-free catalysts by linking density functional theory calculations and structural analysis: Perspectives and challenges[J]. Current Opinion in Electrochemistry, 2018, 9: 137-144.
[53]	JACOBSEN Claus J H, Søren DAHL, BOISEN Astrid, et al. Optimal catalyst curves: Connecting density functional theory calculations with industrial reactor design and catalyst selection[J]. Journal of Catalysis, 2002, 205(2): 382-387.
[54]	路站宽. 基于密度泛函理论的高效ORR双原子催化剂的性能筛选和机理研究[D]. 北京: 北京化工大学, 2024.
	LU Zhankuan. Performance screening and mechanism study of efficient ORR diatomic catalysts based on DFT[D]. Beijing: Beijing University of Chemical Technology, 2024.
[55]	Jorge BENAVIDES-HERNÁNDEZ, DUMEIGNIL Franck. From characterization to discovery: Artificial intelligence, machine learning and high-throughput experiments for heterogeneous catalyst design[J]. ACS Catalysis, 2024, 14(15): 11749-11779.
[56]	LAI Nung Siong, Yi Shen TEW, ZHONG Xialin, et al. Artificial intelligence (AI) workflow for catalyst design and optimization[J]. Industrial & Engineering Chemistry Research, 2023, 62(43): 17835-17848.
[57]	董毅. 基于机器学习的多元金属氧化物基催化剂的高效开发与性能研究[D]. 杭州: 浙江大学, 2024.
	DONG Yi. Machine learning-based efficient development and performance study of multimetal oxide-based catalysts[D]. Hangzhou: Zhejiang University, 2024.
[58]	ZHANG Yanghuan, WEI Xin, ZHANG Wei, et al. Catalytic effect comparison of TiO₂ and La₂O₃ on hydrogen storage thermodynamics and kinetics of the as-milled La-Sm-Mg-Ni-based alloy[J]. Journal of Magnesium and Alloys, 2021, 9(6): 2063-2077.
[59]	MA X Z, MARTINEZ-FRANCO E, DORNHEIM M, et al. Catalyzed Na₂LiAlH₆ for hydrogen storage[J]. Journal of Alloys and Compounds, 2005, 404: 771-774.
[60]	SONG Jianzheng, HAN Shumin, FU Ruidong. Effect of La₂O₃-CaO composite additive on the hydrogen storage properties of Mg₂Ni alloy[J]. Materials Science and Engineering: B, 2014, 188: 114-118.
[61]	SONG Myoungyoup, KWON Sungnam, Jong-Soo BAE, et al. Hydrogen-storage properties of melt spun Mg-23.5wt%Ni milled with nano Nb₂O₅ [J]. Journal of Alloys and Compounds, 2009, 478(1/2): 501-506.
[62]	ZHOU Shiming, WEI Dan, WAN Haiyi, et al. Efficient catalytic effect of the page-like MnCo₂O_4.5 catalyst on the hydrogen storage performance of MgH₂ [J]. Inorganic Chemistry Frontiers, 2022, 9(21): 5495-5506.
[63]	VELLINGIRI Lathapriya, ANNAMALAI Karthigeyan, KANDASAMY Ramamurthi, et al. Synthesis and characterization of MWCNT impregnated with different loadings of SnO₂ nanoparticles for hydrogen storage applications[J]. International Journal of Hydrogen Energy, 2018, 43(2): 848-860.
[64]	MOLAEI Maryam, ATAPOUR Masoud. Nickel-based coatings as highly active electrocatalysts for hydrogen evolution reaction: A review on electroless plating cost-effective technique[J]. Sustainable Materials and Technologies, 2024, 40: e00991.
[65]	LIU Xianzhe, ZHANG Xu, TAO Hong, et al. Research progress of tin oxide-based thin films and thin-film transistors prepared by sol-gel method[J]. Acta Physica Sinica, 2020, 69(22): 228102.
[66]	SHAHCHERAGHI A, DEHGHANI F, RAEISSI K, et al. Effects of TiO₂ additive on electrochemical hydrogen storage properties of nanocrystalline/amorphous Mg₂Ni intermetallic alloy[J]. Iranian Journal of Materials Science and Engineering, 2013, 10: 1-9.
[67]	ZHANG Yanghuan, ZHANG Wei, WEI Xin, et al. Catalytic effects of TiO₂ on hydrogen storage thermodynamics and kinetics of the as-milled Mg-based alloy [J]. Materials Characterization, 2021, 176: 111118.
[68]	GAO R G, TU J P, WANG X L, et al. The absorption and desorption properties of nanocrystalline Mg₂Ni_0.75Cr_0.25 alloy containing TiO₂ nanoparticles[J]. Journal of Alloys and Compounds, 2003, 356: 649-653.
[69]	RAFI-UD-DIN, QU Xuanhui, LI Ping, et al. Superior catalytic effects of Nb₂O₅, TiO₂, and Cr₂O₃ nanoparticles in improving the hydrogen sorption properties of NaAlH₄ [J]. The Journal of Physical Chemistry C, 2012, 116(22): 11924-11938.
[70]	SONG Wenjie, MA Wenhao, HE Shuai, et al. TiO₂@C catalyzed hydrogen storage performance of Mg-Ni-Y alloy with LPSO and ternary eutectic structure[J]. Journal of Magnesium and Alloys, 2024, 12(2): 767-778.
[71]	XIAN Kaicheng, NIE Bo, LI Zigen, et al. TiO₂decorated porous carbonaceous network structures offer confinement, catalysis and thermal conductivity for effective hydrogen storage of LiBH₄ [J]. Chemical Engineering Journal, 2021, 407: 127156.
[72]	YIN Yi, LI Bo, YUAN Zeming, et al. Microstructure and improved hydrogen storage properties of Mg₈₅Zn₅Ni₁₀ alloy catalyzed by Cr₂O₃ nanoparticles[J]. Journal of Physics and Chemistry of Solids, 2019, 134: 295-306.
[73]	VIJAY R, SUNDARESAN R, MAIYA M P, et al. Hydrogen storage properties of Mg-Cr₂O₃ nanocomposites: The role of catalyst distribution and grain size[J]. Journal of Alloys and Compounds, 2006, 424(1/2): 289-293.
[74]	POLANSKI Marek, BYSTRZYCKI Jerzy, PLOCINSKI Tomasz. The effect of milling conditions on microstructure and hydrogen absorption/desorption properties of magnesium hydride (MgH₂) without and with Cr₂O₃ nanoparticles[J]. International Journal of Hydrogen Energy, 2008, 33(7): 1859-1867.
[75]	HANADA Nobuko, ICHIKAWA Takayuki, HINO Satoshi, et al. Remarkable improvement of hydrogen sorption kinetics in magnesium catalyzed with Nb₂O₅ [J]. Journal of Alloys and Compounds, 2006, 420(1/2): 46-49.
[76]	BARKHORDARIAN Gagik, KLASSEN Thomas, Rüdiger BORMANN. Effect of Nb₂O₅ content on hydrogen reaction kinetics of Mg[J]. Journal of Alloys and Compounds, 2004, 364(1/2): 242-246.
[77]	OSORIO-GARCÍA M, SUÁREZ-ALCÁNTARA K, TODAKA Y, et al. Low-temperature hydrogenation of Mg-Ni-Nb₂O₅ alloy processed by high-pressure torsion[J]. Journal of Alloys and Compounds, 2021, 878: 160309.
[78]	ZHANG Huaiwei, FU Li, XUAN Weidong, et al. Surface modification of the La_1.7Mg_1.3Ni₉ alloy with trace Y₂O₃ related to the electrochemical hydrogen storage properties[J]. Renewable Energy, 2020, 145: 1572-1577.
[79]	ZHONG H C, HUANG Y S, DU Z Y, et al. Enhanced hydrogen ab/de-sorption of Mg(Zn) solid solution alloy catalyzed by YH₂/Y₂O₃ nanocomposite[J]. International Journal of Hydrogen Energy, 2020, 45(51): 27404-27412.
[80]	WANG Hui, HU Jie, HAN Fuguo, et al. Enhanced joint catalysis of YH₂/Y₂O₃ on dehydrogenation of MgH₂ [J]. Journal of Alloys and Compounds, 2015, 645: S209-S212.
[81]	LAN Zhiqiang, SUN Zhenzhen, DING Yuchuan, et al. Catalytic action of Y₂O₃@graphene nanocomposites on the hydrogen-storage properties of Mg-Al alloys[J]. Journal of Materials Chemistry A, 2017, 5(29): 15200-15207.

复合体系	储氢容量/%	材料开始吸氢至最大氢容量90%所需时间/s	扩散系数/m²·s^-1
Nd₂Mg₁₇-50% Ni	3.192	2.90	7.160×10^–6
Nd₂Mg₁₇-50% Ni-0.5% CeO₂	3.329	0.55	7.237×10^–6
Nd₂Mg₁₇-50% Ni-1.0% CeO₂	3.376	0.65	9.302×10^–6
Nd₂Mg₁₇-50% Ni-1.5% CeO₂	3.320	0.62	9.306×10^–6
Nd₂Mg₁₇-50% Ni-2.0% CeO₂	3.199	0.67	10.265×10^–6

复合体系	储氢容量/%	材料开始吸氢至最大氢容量90%所需时间/s	扩散系数/m²·s^-1
Nd₂Mg₁₇-50% Ni	3.192	2.90	7.160×10^–6
Nd₂Mg₁₇-50% Ni-0.5% CeO₂	3.329	0.55	7.237×10^–6
Nd₂Mg₁₇-50% Ni-1.0% CeO₂	3.376	0.65	9.302×10^–6
Nd₂Mg₁₇-50% Ni-1.5% CeO₂	3.320	0.62	9.306×10^–6
Nd₂Mg₁₇-50% Ni-2.0% CeO₂	3.199	0.67	10.265×10^–6

复合体系	起始脱氢温度/℃	峰值脱氢温度/℃	脱氢量（质量分数）/%	理论吸氢量（质量分数）/%
As-milled MgH₂	361.1	422.7	7.47	7.60
MgH₂+10% ZrO₂	297.0	410.2	5.54	6.84
MgH₂+10% Ni	282.2	385.5	5.95	6.84
MgH₂+5% Ni+5% ZrO₂	255.1	365.5	6.40	6.84

复合体系	起始脱氢温度/℃	峰值脱氢温度/℃	脱氢量（质量分数）/%	理论吸氢量（质量分数）/%
As-milled MgH₂	361.1	422.7	7.47	7.60
MgH₂+10% ZrO₂	297.0	410.2	5.54	6.84
MgH₂+10% Ni	282.2	385.5	5.95	6.84
MgH₂+5% Ni+5% ZrO₂	255.1	365.5	6.40	6.84

种类	催化机理及效果	应用体系	环境影响	文献
TiO₂	改善固态储氢材料的微观结构，减小材料的颗粒尺寸、减少材料颗粒团聚，增强固态储氢材料的吸放氢性能	Mg₂Ni、NaAlH₄、La₇Ce₃Mg₈₀Ni₁、Mg₂Ni_0.75Cr_0.25和La₇Sm₃Mg₈₀Ni₁₀等	TiO₂是相对无害的，并且其不易在环境中降解或迁移	[31,58-59,67-71]
Cr₂O₃	提供表面活性位点，促进氢分子吸附和解离，减小颗粒尺寸，促进相界面、氢扩散通道及成核位点生成，进而改善固态储氢材料的吸放氢动力学性能，增强材料的热稳定性和循环稳定性	MgH₂、LiAlH₄、Mg₈₅Zn₅Ni₁₀和Mg等	Cr₂O₃是相对稳定且低毒的氧化物，同时还不易溶于水，对环境的直接危害也相对较低	[50,69,72-74]
Nb₂O₅	“氢泵”效应，促进氢分子吸附和解离，显著降低固态储氢材料的起始脱氢温度，改善脱氢动力学	NaAlH₄、MgH₂、Mg-23.5-Ni和LiAlH₄等	Nb₂O₅是一种稳定的化合物，在环境中不会轻易降解或释放铌元素，对环境的直接影响较小	[38,61,77]
Y₂O₃	有助于形成更多的氢扩散通道和活性成核位点，提高固态储氢材料的脱氢速率	Mg-Al、Mg_0.97Zn_0.03、Na₂LiAlH₆、La_1.7Mg_1.3Ni₉和MgH₂等	Y₂O₃在环境中较为稳定，通常不会对环境造成显著影响	[59,78-80]
La₂O₃	催化作用相对较弱，可以改善固态储氢材料的脱氢动力学性能，但是可能会降低储氢容量	Mg₂Ni、MgH₂和NaAlH₄等	La₂O₃的环境稳定性高	[31,82]
CeO₂	细化固态储氢材料的颗粒尺寸，增加比表面积，改善储氢热力学参数及降低吸放氢反应活化能等	Nd₂Mg₁₇-50% Ni复合体系、Mg₉₆La₃Ni、YMg₁₁Ni、Mg₈₅Cu₅Ni₁₀、MgH₂和NaAlH₄等	CeO₂在环境中相对稳定，对环境影响有限	[59,82-87]
Fe₂O₃	表面键态和电子态与颗粒内部不同，导致其表面的活性反应位点数量多，降低活化能，改善固态储氢材料的脱氢动力学性能	4MgH₂-Li₃AlH₆复合体系和LiAlH₄等	Fe₂O₃对环境的影响通常较小	[88-90,122]
ZrO₂	可以作为催化剂，也可以作用作为催化剂载体，减少固态储氢材料的晶粒尺寸，改善固态储氢材料的吸放氢动力学性能	MgH₂等	ZrO₂是一种无毒的化合物，对环境影响较小	[91-92]
CuO	可以抑制某些固态储氢材料在吸放氢过程中结构的变化和活性的损失，提高储氢容量和循环稳定性	MgNi、MgH₂和多壁碳纳米管等	CuO是一种稳定的铜化合物，但在水环境中可能导致水体污染	[93-96]
Co₂O₃	促进氢扩散通道的形成，降低固态储氢材料的脱氢反应活化能及增加活性反应位点等，改善固态储氢材料的脱氢性能	LiAlH₄等	Co₂O₃是一种相对稳定的氧化物，但钴化合物对环境和健康的潜在风险需引起重视	[90]
SnO₂	减少颗粒的团聚，提高比表面积，降低起始脱氢温度	MgH₂等	SnO₂是一种稳定的化合物，通常认为对环境无害	[97]
Sm₂O₃	显著改善固态储氢材料的脱氢动力学，增强其循环稳定性	NaAlH₄等	Sm₂O₃的环境稳定性高	[82]

金属氧化物催化固态储氢材料吸放氢性能的研究进展

Research progress on hydrogen absorption and desorption performance of metal oxide catalyzed solid-state hydrogen storage materials

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 17

参考文献 81

相关文章 15

编辑推荐

Metrics

本文评价

种类	催化机理及效果	应用体系	环境影响	文献
MnFe₂O₄	提供活性位点，促进氢分子解离和扩散，降低脱氢反应活化能，改善脱氢性能	NaAlH₄、LiAlH₄和MgH₂等	高浓度MnFe₂O₄可能对环境有一定的风险	[98-102]
CuFe₂O₄	减少颗粒尺寸，缓解团聚现象，增加晶界和比表面积，形成具有催化活性的产物，促进氢原子的扩散。降低活化能，可提高脱氢性能	NaAlH₄和MgH₂等	CuFe₂O₄在水环境中可能导致水体污染	[103-104]
NiFe₂O₄	在球磨过程中，可以与部分固态储氢材料形成多价态且能够提供活性位点的中间产物，降低脱氢的起始脱氢温度，提高脱氢速率	LiAlH₄和NaAlH₄等	NiFe₂O₄对环境影响主要由镍浓度主导，高浓度的NiFe₂O₄可能对水体产生一定的影响	[105-106]
MgFe₂O₄	降低脱氢反应活化能，降低起始脱氢温度，提高脱氢速率	Na₃AlH₆-4LiBH₄、MgH₂、NaBH₄和LiAlH₄等	MgFe₂O₄对环境影响总体较低	[107-109]
LaFeO₃	降低脱氢反应活化能，降低起始脱氢温度，提高脱氢速率	LiAlH₄和MgH₂等	作为一种无机氧化物材料，其在使用过程中不会释放有害的副产物	[36, 110]
CoTiO₃	具有高氧化还原活性和稳定性，降低脱氢反应活化能，降低起始脱氢温度，提高脱氢速率	LiAlH₄和MgH₂等	CoTiO₃对环境影响主要与钴的含量相关，钴化合物在高浓度下对水生生物有毒，可能导致水体污染	[111-113]
MnTiO₃	在吸放氢过程中，可以与部分固态储氢材料反应，可以形成多价态及多元素的氧化物，提供催化环境，降低起始脱氢温度并提高脱氢速率	MgH₂等	作为一种无机氧化物材料，具有相对良好的环境兼容性和较低的环境负担	[114]
SrTiO₃	降低脱氢反应活化能，降低起始脱氢温度，提高脱氢速率	LiAlH₄、NaAlH₄和MgH₂等	作为一种无机材料，其通常具有较好的化学稳定性和环境兼容性	[115-117]
MnCoO_4.5	降低脱氢反应活化能，降低起始脱氢温度，提高脱氢速率	MgH₂等	高浓度MnCoO_4.5可能对水体和生态系统造成负面影响	[62]
TiNb₂O₇	球磨过程中生成了多种具有催化活性的产物(如Ti、TiO、NbO₂和Nb等），上述产物对脱氢反应具有促进作用，降低脱氢反应活化能，降低起始脱氢温度	LiAlH₄和NaAlH₄等	TiNb₂O₇对环境影响较低，不易释放有害物质	[118]

[1]	刘哲, 周顺利, 李永祥, 张成喜, 刘宜鹏. 烷基萘合成催化剂研究进展[J]. 化工进展, 2025, 44(S1): 144-158.
[2]	林已杰, 乔鹏, 李心睿, 张宏斌, 王雪芹. TiO₂纳米光催化剂的异质结构建策略与应用研究进展[J]. 化工进展, 2025, 44(S1): 159-177.
[3]	王涛, 张雪冰, 张琪, 陈强, 张魁, 门卓武. 还原碳化温度和CO浓度对工业级费托合成沉淀铁催化剂性能的影响[J]. 化工进展, 2025, 44(S1): 178-184.
[4]	包新德, 刘必烨, 黄仁伟, 洪宇豪, 关鑫, 林金国. 生物质基@CuNiOS复合催化剂的制备及其在有机染料还原中的应用[J]. 化工进展, 2025, 44(S1): 185-196.
[5]	赵思阳, 李陈冉, 刘洋. 副产C₄预积炭调控MTO再生催化剂双烯选择性的工艺优化[J]. 化工进展, 2025, 44(S1): 205-212.
[6]	赵雨龙, 蔡凯, 于善青. 氧化铝孔结构对催化裂化烃类分子吸附扩散及反应性能的影响[J]. 化工进展, 2025, 44(S1): 213-221.
[7]	李军良, 李悦, 孙道来. Cu/SiO₂-Al₂O₃催化1,2-丁二醇加氢脱氧制备1-丁醇[J]. 化工进展, 2025, 44(S1): 222-231.
[8]	刘超, 丁承奥, 吴宝顺, 雷欣宇, 王光应, 余正伟. TiO₂载体粒度对RuO _x -V₂O₅-WO₃/TiO₂催化剂脱硝及抗水硫中毒性能的影响[J]. 化工进展, 2025, 44(S1): 232-242.
[9]	张涵林, 岳学海, 刘俊希, 殷逢俊. 钌锶铱电沉积构筑高稳定性析氧反应电催化剂[J]. 化工进展, 2025, 44(S1): 243-251.
[10]	孙梦圆, 陆诗建, 刘玲, 薛艳阳, 张云蓉, 董琦, 康国俊. 金属有机框架及衍生物在碳捕集领域的研究进展[J]. 化工进展, 2025, 44(9): 5339-5350.
[11]	王文君, 刘瑞鑫, 王军, 张庆磊, 侯立安. 浅析二氧化钛材料可见光降解室内VOCs的研究进展[J]. 化工进展, 2025, 44(9): 5351-5362.
[12]	曾金, 高艳, 王赵鹏, 谢雨芸, 刘俊, 梁旗, 王春英. NaYF₄:Yb,Tm复合TiO₂/Bi₂WO₆光催化降解2,4-二氯苯氧乙酸机制及产物毒性评价[J]. 化工进展, 2025, 44(9): 5416-5431.
[13]	陈子朝, 何方书, 胡强, 杨扬, 陈汉平, 杨海平. 甲烷干重整抗积炭Ni基催化剂研究进展[J]. 化工进展, 2025, 44(9): 4968-4978.
[14]	王振, 张耀远, 吴芹, 史大昕, 陈康成, 黎汉生. 甲烷干重整用Ni/Al₂O₃基催化剂研究进展[J]. 化工进展, 2025, 44(9): 4979-4998.
[15]	张海鹏, 秦珊珊, 王俣萱, 于海彪. 3.0F-Ag _x Co催化剂的制备及其催化分解N₂O[J]. 化工进展, 2025, 44(9): 4999-5005.