皮胶原在柔性智能可穿戴领域的研究进展

doi:10.16085/j.issn.1000-6613.2023-2119

化工进展 ›› 2024, Vol. 43 ›› Issue (5): 2645-2660.DOI: 10.16085/j.issn.1000-6613.2023-2119

• 催化与材料技术 • 上一篇

皮胶原在柔性智能可穿戴领域的研究进展

李楠¹^,²^,³(), 高党鸽¹^,²^,³(), 吕斌¹^,²^,³, 唐立涛¹^,²^,³, 陈肯¹^,²^,³, 郑驰¹^,²^,³, 马建中¹^,²^,³

^1.陕西科技大学轻工科学与工程学院，陕西西安 710021
^2.陕西科技大学轻化工程国家级实验教学示范中心，陕西西安 710021
^3.西安市绿色化学品与功能材料重点实验室，陕西西安 710021

收稿日期:2023-12-01 修回日期:2024-01-09 出版日期:2024-05-15 发布日期:2024-06-15
通讯作者: 高党鸽
作者简介:李楠（2000—），女，博士研究生，研究方向为皮胶原基摩擦纳米传感器的构筑。E-mail：3357923747@qq.com。
基金资助:
国家自然科学基金(22378250);陕西省自然科学基础研究计划重点（特别支持）(2023JC-XJ-12);陕西省“高层次人才特殊支持计划”青年拔尖人才项目

Research progress of leather collagen in flexible intelligent wearable field

LI Nan¹^,²^,³(), GAO Dangge¹^,²^,³(), LYU Bin¹^,²^,³, TANG Litao¹^,²^,³, CHEN Ken¹^,²^,³, ZHENG Chi¹^,²^,³, MA Jianzhong¹^,²^,³

^1.College of Bioresources Chemistry and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021, Shaanxi, China
^2.National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi’an 710021, Shaanxi, China
^3.Xi’an Key Laboratory of Green Chemicals and Functional Materials, Xi’an 710021, Shaanxi, China

Received:2023-12-01 Revised:2024-01-09 Online:2024-05-15 Published:2024-06-15
Contact: GAO Dangge

摘要/Abstract

摘要：

皮胶原作为一种来源于动物皮肤的天然生物质材料，具有良好的生物相容性、可降解性、低抗原性以及易功能化等优势，在柔性传感、电磁屏蔽、人体热管理和储能等柔性智能可穿戴领域展现出巨大的应用潜力。然而，未经改性的皮胶原存在热稳定性差、机械强度较低以及功能性不足等一些固有缺点，使其在柔性智能可穿戴领域应用受限。本文简要介绍了皮胶原的多层级结构和性能优势，论述了皮胶原的不同改性方法，包括物理交联、化学交联以及共混改性，重点综述了其作为柔性可穿戴材料在柔性传感、电磁屏蔽、人体热管理和超级电容器中的研究进展。最后，就皮胶原在柔性可穿戴电子领域的发展趋势进行了展望，指出开发具有极端环境稳定性、多功能集成型皮胶原柔性可穿戴电子材料，实现皮胶原基柔性智能可穿戴材料的按需定制将成为下一步的研究重点。

关键词: 皮胶原, 改性, 生物质材料, 柔性智能可穿戴, 能量收集, 能量转化

Abstract:

Leather collagen is a kind of natural biomass material derived from animal skin. The advantages of good biocompatibility, degradability, low antigenicity and easy functionalization make the leather collagen showing great application potential in flexible intelligent wearable fields such as flexible sensing, electromagnetic shielding, human thermal management and energy storage. However, some inherent shortcomings, such as poor thermal stability, low mechanical strength and easy to mildew and insufficient functionality, limite the application of leather collagen in the field of flexible intelligent wearable. In this review, the multilevel structure and performance advantages of leather collagen were briefly introduced. Different modification methods of collagen were discussed, including physical crosslinking, chemical crosslinking and blending modification. In addition, this review paid more attention to the research progress of leather collagen as flexible wearable materials in flexible sensing, electromagnetic shielding, human thermal management and supercapacitors. Finally, the development trend of leather collagen in the field of flexible wearable electronics was forecasted, and it was pointed out that the development of multi-functional integrated leather collagen flexible wearable electronic materials with extreme environmental stability and the realization of on-demand customization of flexible intelligent wearable materials based on leather collagen would be the focus of further research.

Key words: leather collagen, modified, biomaterials, flexible intelligent wearable, energy harvesting, energy conversion

中图分类号:

TN304

李楠, 高党鸽, 吕斌, 唐立涛, 陈肯, 郑驰, 马建中. 皮胶原在柔性智能可穿戴领域的研究进展[J]. 化工进展, 2024, 43(5): 2645-2660.

LI Nan, GAO Dangge, LYU Bin, TANG Litao, CHEN Ken, ZHENG Chi, MA Jianzhong. Research progress of leather collagen in flexible intelligent wearable field[J]. Chemical Industry and Engineering Progress, 2024, 43(5): 2645-2660.

图/表 12

图1 皮胶原的来源、结构性能、改性及应用

图2 皮胶原的多层级结构[21]

图3 皮胶原物理交联改性

图4 生物质基醛类交联剂改性皮胶原[52]

图5 皮胶原应用于外供能柔性传感器

图6 皮胶原基自供能柔性传感器的三维网络结构示意图及其在睡眠监测中的应用[93]

图7 皮胶原作为电磁屏蔽材料的应用

图8 皮胶原在电热型皮革中的应用[112]

图9 “里应外合”策略构筑双层可穿戴天然皮肤[116]

图10 皮革/氨基化多壁碳纳米管/醋酸纤维素动态热管理皮革的冷却和加热方式[119]

图11 MPCNS的制备[134]

图12 皮胶原在超级电容器隔膜中的应用[137]

参考文献 137

1	FAN Xin, KE Tao, GU Haibin. Multifunctional, ultra-tough organohydrogel E-skin reinforced by hierarchical goatskin fibers skeleton for energy harvesting and self-powered monitoring[J]. Advanced Functional Materials, 2023, 33(42): 2304015.
2	KENNEDY L J, RATNAJI T, KONIKKARA N, et al. Value added porous carbon from leather wastes as potential supercapacitor electrode using neutral electrolyte[J]. Journal of Cleaner Production, 2018, 197: 930-936.
3	GAO Dangge, GUO Shihao, ZHOU Yingying, et al. Absorption-dominant, low-reflection multifunctional electromagnetic shielding material derived from hydrolysate of waste leather scraps[J]. ACS Applied Materials & Interfaces, 2022, 14(33): 38077-38089.
4	ZHENG Chi, GAO Dangge, Bin LYU, et al. Eco-friendly bionic flexible multifunctional sensors based on biomass-MXene composites[J]. ACS Sustainable Chemistry & Engineering, 2023, 11(15): 5834-5844.
5	Shanghai Jiao Tong University. 125 Questions: Exploration and discovery[M]. Washing D C: Science, 2021.
6	SANDERSON K. Electronic skin: From flexibility to a sense of touch[J]. Nature, 2021, 591(7851): 685-687.
7	姚黎明, 张研柔, 刘振华, 等. 纳米纤维素/MXene柔性电子器件的制备及应用研究进展[J]. 中国造纸学报, 2023, 38(3): 9-17.
	YAO Liming, ZHANG Yanrou, LIU Zhenhua, et al. Progress in the preparation and application of nanocellulose/MXene flexible electronic devices[J]. Transactions of China Pulp and Paper, 2023, 38(3): 9-17.
8	GHODBANE S A, DUNN M G. Physical and mechanical properties of cross-linked type Ⅰ collagen scaffolds derived from bovine, porcine, and ovine tendons[J]. Journal of Biomedical Materials Research Part A, 2016, 104(11): 2685-2692.
9	HU Yang, LIU Lan, GU Zhipeng, et al. Modification of collagen with a natural derived cross-linker, alginate dialdehyde[J]. Carbohydrate Polymers, 2014, 102: 324-332.
10	SHARMA S, THIND S S, KAUR A. In vitro meat production system: Why and how?[J]. Journal of Food Science and Technology, 2015, 52(12): 7599-7607.
11	RAO J R, THANIKAIVELAN P, SREERAM K J, et al. Green route for the utilization of chrome shavings (chromium-containing solid waste) in tanning industry[J]. Environmental Science & Technology, 2002, 36(6): 1372-1376.
12	SUNDAR V J, GNANAMANI A, MURALIDHARAN C, et al. Recovery and utilization of proteinous wastes of leather making: A review[J]. Reviews in Environmental Science and Bio/Technology, 2011, 10(2): 151-163.
13	WANG Lili, CHEN Di, JIANG Kai, et al. New insights and perspectives into biological materials for flexible electronics[J]. Chemical Society Reviews, 2017, 46(22): 6764-6815.
14	TORCULAS M, MEDINA J, XUE Wei, et al. Protein-based bioelectronics[J]. ACS Biomaterials Science & Engineering, 2016, 2(8): 1211-1223.
15	MOGILNER I G, RUDERMAN G, GRIGERA J R. Collagen stability, hydration and native state[J]. Journal of Molecular Graphics and Modelling, 2002, 21(3): 209-213.
16	QU Wenjuan, GUO Tiantian, ZHANG Xinxin, et al. Preparation of tuna skin collagen-chitosan composite film improved by sweep frequency pulsed ultrasound technology[J]. Ultrasonics Sonochemistry, 2022, 82: 105880.
17	Minsik JO, MIN Kyungtaek, ROY B, et al. Protein-based electronic skin akin to biological tissues[J]. ACS Nano, 2018, 12(6): 5637-5645.
18	TAO Hu, HWANG Suk-Won, MARELLI B, et al. Silk-based resorbable electronic devices for remotely controlled therapy and in vivo infection abatement[J]. Proceedings of the National Academy of Sciences of the United States of America, 2014, 111(49): 17385-17389.
19	ZHAO Ping, GAO Dangge, Bin LYU, et al. Fabrication of effective electromagnetic shielding leather with a chromium-free multi-network structure[J]. Journal of Cleaner Production, 2022, 374: 133856.
20	王光宇, 肖美添, 赵鹏, 等. 胶原聚集体及其聚集行为研究进展[J]. 生物技术进展, 2017, 7(6): 587-593.
	WANG Guangyu, XIAO Meitian, ZHAO Peng, et al. Progress on collagen aggregates and their aggregation behavior[J]. Current Biotechnology, 2017, 7(6): 587-593.
21	CHEN Qijue, PEI Ying, TANG Keyong, et al. Structure, extraction, processing, and applications of collagen as an ideal component for biomaterials—A review[J]. Collagen and Leather, 2023, 5(1): 1-27.
22	BAUMANN L, KAUFMAN J, SAGHARI S. Collagen fillers[J]. Dermatologic Therapy, 2006, 19(3): 134-140.
23	SANDERS J E, GOLDSTEIN B S. Collagen fibril diameters increase and fibril densities decrease in skin subjected to repetitive compressive and shear stresses[J]. Journal of Biomechanics, 2001, 34(12): 1581-1587.
24	LIU Xinhua, ZHENG Chi, LUO Xiaomin, et al. Recent advances of collagen-based biomaterials: Multi-hierarchical structure, modification and biomedical applications[J]. Materials Science and Engineering: C, 2019, 99: 1509-1522.
25	CAO Lilong, QIU Xia, JIAO Qin, et al. Polysaccharides and proteins-based nanogenerator for energy harvesting and sensing: A review[J]. International Journal of Biological Macromolecules, 2021, 173: 225-243.
26	BEDI N, SRIVASTAVA D K, SRIVASTAVA A, et al. Marine biological macromolecules as matrix material for biosensor fabrication[J]. Biotechnology and Bioengineering, 2022, 119(8): 2046-2063.
27	DAN Weihua, CHEN Yining, DAN Nianhua, et al. Multi-level collagen aggregates and their applications in biomedical applications[J]. International Journal of Polymer Analysis and Characterization, 2019, 24(8): 667-683.
28	YANG Huan, XU Songcheng, SHEN Lirui, et al. Changes in aggregation behavior of collagen molecules in solution with varying concentrations of acetic acid[J]. International Journal of Biological Macromolecules, 2016, 92: 581-586.
29	DELGADO L M, BAYON Y, PANDIT A, et al. To cross-link or not to cross-link? Cross-linking associated foreign body response of collagen-based devices[J]. Tissue Engineering Part B: Reviews, 2015, 21(3): 298-313.
30	杜田明. 鱼鳞胶原基质的复合改性及其在创面中的初步应用研究[D]. 北京: 中国人民解放军军事医学科学院, 2016.
	DU Tianming. Modification of fish scale collagen matrix and its preliminary application in wound repair[D]. Beijing: PLA Academy of Military Medical Sciences 2016.
31	蔡洁. 新型交联剂的合成及交联改性胶原的研究[D]. 广州: 华南理工大学, 2014.
	CAI Jie. Preparation of new crosslinking agents and studying on crosslinking of collagen with them[D]. Guangzhou: South China University of Technology, 2014.
32	HU Yang, LIU Lan, DAN Weihua, et al. Synergistic effect of carbodiimide and dehydrothermal crosslinking on acellular dermal matrix[J]. International Journal of Biological Macromolecules, 2013, 55: 221-230.
33	MYRONCHENKO S, ZVYAGINTSEVA T, ASHUKINA N. The effect of ultraviolet radiation on the organization and structure of collagen fibers of dermis[J]. Georgian Medical News, 2020(302): 82-85.
34	缪楠. 鲫鱼皮胶原蛋白理化性质及其自组装行为研究[D]. 镇江: 江苏科技大学, 2019.
	MIAO Nan. Study on the physicochemical properties and self-assembly behavior of collagen from carassius auratus skin[D]. Zhenjiang: Jiangsu University of Science and Technology, 2019.
35	YU Xiaoyue, TANG Cuie, XIONG Shanbai, et al. Modification of collagen for biomedical applications: A review of physical and chemical methods[J]. Current Organic Chemistry, 2016, 20(17): 1797-1812.
36	ZHANG Xiaoxia, XU Songcheng, SHEN Lirui, et al. Factors affecting thermal stability of collagen from the aspects of extraction, processing and modification[J]. Journal of Leather Science and Engineering, 2020, 2(1): 1-29.
37	KOZLOWSKA J, STACHOWIAK N, PRUS W. Stability studies of collagen-based microspheres with Calendula officinalis flower extract[J]. Polymer Degradation and Stability, 2019, 163: 214-219.
38	XU Chengzhi, WEI Xu, SHU Feiyi, et al. Induction of fiber-like aggregation and gelation of collagen by ultraviolet irradiation at low temperature[J]. International Journal of Biological Macromolecules, 2020, 153: 232-239.
39	SONG Xiaoyan, DONG Pengfei, GRAVESANDE J, et al. UV-mediated solid-state cross-linking of electrospinning nanofibers of modified collagen[J]. International Journal of Biological Macromolecules, 2018, 120: 2086-2093.
40	WEADOCK K S, MILLER E J, BELLINCAMPI L D, et al. Physical crosslinking of collagen fibers: Comparison of ultraviolet irradiation and dehydrothermal treatment[J]. Journal of Biomedical Materials Research, 1995, 29(11): 1373-1379.
41	张金伟, 曹念, 陈武勇. 微波辐照对胶原蛋白三股螺旋结构的影响[J]. 光谱学与光谱分析, 2018, 38(5): 1353-1357.
	ZHANG Jinwei, CAO Nian, CHEN Wuyong. Influence of microwave irradiation on collagen triple helix structure[J]. Spectroscopy and Spectral Analysis, 2018, 38(5): 1353-1357.
42	CAO Sheng, LI Hejun, LI Kezhi, et al. A dense and strong bonding collagen film for carbon/carbon composites[J]. Applied Surface Science, 2015, 347: 307-314.
43	BAILEY A J, LIGHT N D, ATKINS E D T. Chemical cross-linking restrictions on models for the molecular organization of the collagen fibre[J]. Nature, 1980, 288(5789): 408-410.
44	CHOY A T H, LEONG K W, CHAN B P. Chemical modification of collagen improves glycosaminoglycan retention of their co-precipitates[J]. Acta Biomaterialia, 2013, 9(1): 4661-4672.
45	ADAMIAK K, SIONKOWSKA A. Current methods of collagen cross-linking: Review[J]. International Journal of Biological Macromolecules, 2020, 161: 550-560.
46	MASTROPASQUA L. Collagen cross-linking: When and how? A review of the state of the art of the technique and new perspectives[J]. Eye and Vision, 2015, 2(1): 1-10.
47	ZHANG Ting, YU Zhe, MA Yun, et al. Modulating physicochemical properties of collagen films by cross-linking with glutaraldehyde at varied pH values[J]. Food Hydrocolloids, 2022, 124: 107270.
48	SCIALLA S, GULLOTTA F, IZZO D, et al. Genipin-crosslinked collagen scaffolds inducing chondrogenesis: A mechanical and biological characterization[J]. Journal of Biomedical Materials Research Part A, 2022, 110(7): 1372-1385. .
49	LI Weilin, FAN Xialian, WANG Ying, et al. A glycidyl methacrylate modified collagen/polyethylene glycol diacrylate hydrogel: A mechanically strong hydrogel for loading levofloxacin[J]. New Journal of Chemistry, 2020, 44: 17027-17032.
50	OCAK B. Chitosan/collagen hydrolysate based films obtained from hide trimming wastes reinforced with chitosan nanoparticles[J]. Food Biophysics, 2021, 16(3): 381-394.
51	DELGADO L M, FULLER K, ZEUGOLIS D I. Collagen cross-linking: biophysical, biochemical, and biological response analysis[J]. Tissue Engineering Part A, 2017, 23(19-20): 1064-1077.
52	HAO Dongyu, WANG Xuechuan, LIU Xinhua, et al. Chrome-free tanning agent based on epoxy-modified dialdehyde starch towards sustainable leather making[J]. Green Chemistry, 2021, 23(23): 9693-9703.
53	GAO Dangge, LI Xinjing, CHENG Yiming, et al. The modification of collagen with biosustainable POSS graft oxidized sodium alginate composite[J]. International Journal of Biological Macromolecules, 2022, 200: 557-565.
54	DING Wei, PANG Xiaoyan, DING Zhiwen, et al. Constructing a robust chrome-free leather tanned by biomass-derived polyaldehyde via crosslinking with chitosan derivatives[J]. Journal of Hazardous Materials, 2020, 396: 122771.
55	SPADARO J A, BECKER R O, BACHMAN C H. Size-specific metal complexing sites in native collagen[J]. Nature, 1970, 225(5238): 1134-1136.
56	WISE W R, DAVIS S J, HENDRIKSEN W E, et al. Zeolites as sustainable alternatives to traditional tanning chemistries[J]. Green Chemistry, 2023, 25(11): 4260-4270.
57	CIAMBELLI P, SANNINO D, NAVIGLIO B, et al. Zeolite-chrome tanning: From laboratory to pilot scale[M]//Studies in Surface Science and Catalysis. Amsterdam: Elsevier, 2005, 155: 189-198.
58	BACARDIT A, VAN DER BURGH S, ARMENGOL J, et al. Evaluation of a new environment friendly tanning process[J]. Journal of Cleaner Production, 2014, 65: 568-573.
59	庄辰, 陶芙蓉, 于润慧, 等. 明胶/胶原改性的研究进展[J]. 化学通报, 2015, 78(3): 202-207.
	ZHUANG Chen, TAO Furong, YU Runhui, et al. Progress in gelatin/collagen modification[J]. Chemistry, 2015, 78(3): 202-207.
60	周东艳. 鱼皮胶原蛋白材料及其复合材料的制备及性能研究[D]. 长春: 吉林大学, 2019.
	ZHOU Dongyan. Preparation and characterization of collagen materials of fish skin and its composite materials[D]. Changchun: Jilin University, 2019.
61	张亚飞, 逄欣雨, 叶张靖, 等. 胶原蛋白改性方法与应用[J]. 渔业研究, 2020, 42(2): 185-194.
	ZHANG Yafei, PANG Xinyu, YE Zhangjing, et al. Collagen modification method and application[J]. Journal of Fisheries Research, 2020, 42(2): 185-194.
62	汪晓鹏. 皮胶原蛋白改性高分子制备新型材料的研究[J]. 西部皮革, 2019, 41(13): 37.
	WANG Xiaopeng. Study on preparation of new materials by collagen modified polymer[J]. West Leather, 2019, 41(13): 37.
63	商晋, 郭康权, 陈文强. 葡甘聚糖/壳聚糖/水解胶原蛋白胶粘剂的二氧化钛共混改性[J]. 材料科学与工程学报, 2016, 34(1): 38-44.
	SHANG Jin, GUO Kangquan, CHEN Wenqiang. Improved performance of konjac glucomannan/chitosan/polypeptide adhesive blends by adding TiO₂ [J]. Journal of Materials Science and Engineering, 2016, 34(1): 38-44.
64	SIRIVISOOT S, PARETA R, HARRISON B S. Protocol and cell responses in three-dimensional conductive collagen gel scaffolds with conductive polymer nanofibres for tissue regeneration[J]. Interface Focus, 2014, 4(1): 20130050.
65	KEBEDE Z T, TADESSE M G, CHANE T E, et al. Application of PEDOT: PSS conductive polymer to enhance the conductivity of natural leather: Retanning process[J]. Journal of Nanomaterials, 2023, 2023: 1-9.
66	RYAN A J, KEARNEY C J, SHEN Nian, et al. Electroconductive biohybrid collagen/pristine graphene composite biomaterials with enhanced biological activity[J]. Advanced Materials, 2018, 30(15): e1706442.
67	Hyo-Ryoung LIM, KIM Hee Seok, QAZI R, et al. Wearable flexible hybrid electronics: Advanced soft materials, sensor integrations, and applications of wearable flexible hybrid electronics in healthcare, energy, and environment[J]. Advanced Materials, 2020, 32(15): 1901924.
68	ZHAO Dawei, ZHU Ying, CHENG Wanke, et al. Cellulose: Cellulose-based flexible functional materials for emerging intelligent electronics[J]. Advanced Materials, 2021, 33(28): 2000619.
69	XIONG Zheng, YU Haiyang, GONG Xiao. Designing photothermal superhydrophobic PET fabrics via in situ polymerization and 1,4-conjugation addition reaction[J]. Langmuir: the ACS Journal of Surfaces and Colloids, 2022, 38(28): 8708-8718.
70	HE Jiang, ZHANG Yufei, ZHOU Runhui, et al. Recent advances of wearable and flexible piezoresistivity pressure sensor devices and its future prospects[J]. Journal of Materiomics, 2020, 6(1): 86-101.
71	ABODUREXITI A, YANG Congcong, MAIMAITIYIMING X. High-performance flexible pressure and temperature sensors with complex leather structure[J]. Macromolecular Materials and Engineering, 2020, 305(7): 2000181.
72	HAN Yanting, HU Jinlian, SUN Gang. Recent advances in skin collagen: Functionality and non-medical applications[J]. Journal of Leather Science and Engineering, 2021, 3(1): 1-12.
73	ZHENG Manhui, WANG Xuechuan, OUYANG Yue, et al. Skin-inspired gelatin-based flexible bio-electronic hydrogel for wound healing promotion and motion sensing[J]. Biomaterials, 2021, 276: 121026.
74	WEGENE J D, THANIKAIVELAN P. Conducting leathers for smart product applications[J]. Industrial & Engineering Chemistry Research, 2014, 53(47): 18209-18215.
75	HAMMOCK M L, CHORTOS A, C-K TEE B, et al. 25th Anniversary article: The evolution of electronic skin (e-skin): A brief history, design considerations, and recent progress[J]. Advanced Materials, 2013, 25(42): 5997-6038.
76	WENGER M P E, BOZEC L, HORTON M A, et al. Mechanical properties of collagen fibrils[J]. Biophysical Journal, 2007, 93(4): 1255-1263.
77	ZAN Guangtao, WU Qingsheng. Biomimetic and bioinspired synthesis of nanomaterials/nanostructures[J]. Advanced Materials, 2016, 28(11): 2099-2147.
78	WANG Ziying, MA Zongtao, SUN Jingyao, et al. Recent advances in natural functional biopolymers and their applications of electronic skins and flexible strain sensors[J]. Polymers, 2021, 13(5): 813.
79	MORENO S, BANIASADI M, MOHAMMED S, et al. Biocompatible collagen films as substrates for flexible implantable electronics[J]. Advanced Electronic Materials, 2015, 1(9): 1500154.
80	LIN Kaili, ZHANG Dawei, MACEDO M H, et al. Advanced collagen-based biomaterials for regenerative biomedicine[J]. Advanced Functional Materials, 2019, 29(3): 1804943.
81	MA Lie, GAO Changyou, MAO Zhengwei, et al. Collagen/chitosan porous scaffolds with improved biostability for skin tissue engineering[J]. Biomaterials, 2003, 24(26): 4833-4841.
82	WEI Benmei, ZHONG Huaying, WANG Linjie, et al. Facile preparation of a collagen-graphene oxide composite: A sensitive and robust electrochemical aptasensor for determining dopamine in biological samples[J]. International Journal of Biological Macromolecules, 2019, 135: 400-406.
83	ZOU Binghua, CHEN Yuanyuan, LIU Yihan, et al. Repurposed leather with sensing capabilities for multifunctional electronic skin[J]. Advanced Science, 2018, 6(3): 1801283.
84	QIN Rong, LUO Xiaomin, FENG Jianyan, et al. A novel eco- and user-friendly graphene/leather-based composite for real-time mechano-monitoring of human motion[J]. Journal of Cleaner Production, 2022, 371: 133360.
85	BAI Zhongxue, WANG Xuechuan, HUANG Mengchen, et al. Versatile nano-micro collagen fiber-based wearable electronics for health monitoring and thermal management[J]. Journal of Materials Chemistry A, 2023, 11(2): 726-741.
86	JIMA DEMISIE W, PALANISAMY T, KALIAPPA K, et al. Concurrent genesis of color and electrical conductivity in leathers through in-situ polymerization of aniline for smart product applications[J]. Polymers for Advanced Technologies, 2015, 26(5): 521-527.
87	翟瑞, 郭军, 戴睿, 等. 废弃皮革再生利用与面对的问题[J]. 皮革科学与工程, 2021, 31(5): 33-38.
	ZHAI Rui, GUO Jun, DAI Rui, et al. Recycling of waste leather and its problems[J]. Leather Science and Engineering, 2021, 31(5): 33-38.
88	WANG Xuechuan, OUYANG Yue, LIU Xinhua, et al. A novel bio-inspired multi-functional collagen aggregate based flexible sensor with multi-layer and internal 3D network structure[J]. Chemical Engineering Journal, 2020, 392: 123672.
89	WANG Zhonglin, SONG Jinhui. Piezoelectric nanogenerators based on zinc oxide nanowire arrays[J]. Science, 2006, 312(5771): 242-246.
90	XU Zhenyuan, ZHANG Dongzhi, CAI Haolin, et al. Performance enhancement of triboelectric nanogenerators using contact-separation mode in conjunction with the sliding mode and multifunctional application for motion monitoring[J]. Nano Energy, 2022, 102: 107719.
91	ZHAO Hongfa, XU Minyi, SHU Mingrui, et al. Underwater wireless communication via TENG-generated Maxwell’s displacement current[J]. Nature Communications, 2022, 13: 3325.
92	XIE Yunrui, MA Qianli, YUE Bin, et al. Triboelectric nanogenerator based on flexible Janus nanofiber membrane with simultaneous high charge generation and charge capturing abilities[J]. Chemical Engineering Journal, 2023, 452: 139393.
93	OUYANG Yue, WANG Xuechuan, HOU Mengdi, et al. Skin-inspired wearable self-powered electronic skin with tunable sensitivity for real-time monitoring of sleep quality[J]. Nano Energy, 2022, 91: 106682.
94	ZHANG Shaochun, XIAO Yu, CHEN Huamin, et al. Flexible triboelectric tactile sensor based on a robust MXene/leather film for human-machine interaction[J]. ACS Applied Materials & Interfaces, 2023, 15(10): 13802-13812.
95	CHENG Kui, LI Haoliang, ZHU Mohan, et al. In situ polymerization of graphene-polyaniline@polyimide composite films with high EMI shielding and electrical properties[J]. RSC Advances, 2020, 10(4): 2368-2377.
96	Ze NAN, WEI Wei, LIN Zhenhua, et al. Flexible nanocomposite conductors for electromagnetic interference shielding[J]. Nano-Micro Letters, 2023, 15(1): 1-50.
97	CHEN Yiming, YANG Yang, YE Xiong, et al. Porous aerogel and sponge composites: Assisted by novel nanomaterials for electromagnetic interference shielding[J]. Nano Today, 2021, 38: 101204.
98	郭世豪. 基于废革屑水解物制备柔性电磁屏蔽薄膜的研究[D]. 西安: 陕西科技大学, 2022.
	GUO Shihao. Preparation of flexible electromagnetic shielding films based on hydrolysate of waste leather shavings[D]. Xi’an: Shaanxi University of Science & Technology, 2022.
99	LIU Chang, WANG Xiaoling, HUANG Xin, et al. Absorption and reflection contributions to the high performance of electromagnetic waves shielding materials fabricated by compositing leather matrix with metal nanoparticles[J]. ACS Applied Materials & Interfaces, 2018, 10(16): 14036-14044.
100	ZENG Shulong, HUANG Zhaoxia, JIANG Hao, et al. From waste to wealth: A lightweight and flexible leather solid waste/polyvinyl alcohol/silver paper for highly efficient electromagnetic interference shielding[J]. ACS Applied Materials & Interfaces, 2020, 12(46): 52038-52049.
101	GAO Dangge, GUO Shihao, ZHOU Yingying, et al. Hydrophobic, flexible electromagnetic interference shielding films derived from hydrolysate of waste leather scraps[J]. Journal of Colloid and Interface Science, 2022, 613: 396-405.
102	张文博, 王佳宁, 卫林峰, 等. 功能型聚合物基电磁屏蔽材料的制备及应用[J]. 化学进展, 2023, 35(7): 1065-1076.
	ZHANG Wenbo, WANG Jianing, WEI Linfeng, et al. Preparation and application of functional polymer-based electromagnetic shielding materials[J]. Progress in Chemistry, 2023, 35(7): 1065-1076.
103	YUAN Bin, LAI Shuangxin, LI Jianjun, et al. Trash into treasure: Stiff, thermally insulating and highly conductive carbon aerogels from leather wastes for high-performance electromagnetic interference shielding[J]. Journal of Materials Chemistry C, 2021, 9(7): 2298-2310.
104	ZENG Shaoning, PIAN Sijie, SU Minyu, et al. Hierarchical-morphology metafabric for scalable passive daytime radiative cooling[J]. Science, 2021, 373(6555): 692-696.
105	WU Jiawei, ZHANG Manni, SU Minyu, et al. Robust and flexible multimaterial aerogel fabric toward outdoor passive heating[J]. Advanced Fiber Materials, 2022, 4(6): 1545-1555.
106	PENG Yucan, CUI Yi. Advanced textiles for personal thermal management and energy[J]. Joule, 2020, 4(4): 724-742.
107	PAN Ruijie, WU Jing, QU Jin, et al. Peak-like three-dimensional CoFe₂O₄/carbon nanotube decorated bamboo fabrics for simultaneous solar-thermal evaporation of water and photocatalytic degradation of bisphenol A[J]. Journal of Materials Science & Technology, 2024, 179: 40-49.
108	PAKDEL E, SHARP J, KASHI S, et al. Antibacterial superhydrophobic cotton fabric with photothermal, self-cleaning, and ultraviolet protection functionalities[J]. ACS Applied Materials & Interfaces, 2023, 15(28): 34031-34043.
109	MA Jianzhong, MA Li, ZHANG Lei, et al. Bio-based waterborne poly(vanillin-butyl acrylate)/MXene coatings for leather with desired warmth retention and antibacterial properties[J]. Engineering, 2023
110	FAN Xiangqian, YANG Yang, SHI Xinlei, et al. A MXene-based hierarchical design enabling highly efficient and stable solar-water desalination with good salt resistance[J]. Advanced Functional Materials, 2020, 30(52): 2007110.
111	MA Zhonglei, XIANG Xiaolian, SHAO Liang, et al. Multifunctional wearable silver nanowire decorated leather nanocomposites for joule heating, electromagnetic interference shielding and piezoresistive sensing[J]. Angewandte Chemie International Edition, 2022, 61(15): e202200705.
112	FAN Ziyang, LU Liang, SANG Min, et al. Wearable safeguarding leather composite with excellent sensing, thermal management, and electromagnetic interference shielding[J]. Advanced Science, 2023, 10(26): e2302412.
113	HUANG Mengchen, YANG Maiping, GUO Xiaojing, et al. Scalable multifunctional radiative cooling materials[J]. Progress in Materials Science, 2023, 137: 101144.
114	XU Zhikui, LI Na, LIU Defang, et al. A new crystal Mg₁₁(HPO₃)₈(OH)₆ for daytime radiative cooling[J]. Solar Energy Materials and Solar Cells, 2018, 185: 536-541.
115	MENG Xin, CHEN Zhaochuan, QIAN Chenlu, et al. Hierarchical superhydrophobic poly(vinylidene fluoride-co-hexafluoropropylene) membrane with a bead (SiO₂ nanoparticles)-on-string (nanofibers) structure for all-day passive radiative cooling[J]. ACS Applied Materials & Interfaces, 2023, 15(1): 2256-2266.
116	XIE Long, WANG Xuechuan, BAI Zhongxue, et al. Facile “synergistic inner-outer activation” strategy for nano-engineering of nature-skin-derived wearable daytime radiation cooling materials[J]. Small, 2023, 19(26): 2207602.
117	ZHANG Kai, LEI Xiaojuan, MO Caiqing, et al. A zero-energy, zero-emission air conditioning fabric[J]. Advanced Science, 2023, 10(11): e2206925.
118	ZHANG Dong, LIANG Qianqian, ZHOU Zhou, et al. Multifunctional bacterial cellulose photothermal aerogels with multi-bonded network assisted by carbon nanotube[J]. Chemical Engineering Journal, 2023: 144436.
119	MO Caiqing, LEI Xiaojuan, TANG Xuelian, et al. Nanoengineering natural leather for dynamic thermal management and electromagnetic interference shielding[J]. Small, 2023, 19(42): 2303368.
120	XIONG Chuanyin, LI Mengrui, HAN Qing, et al. Screen printing fabricating patterned and customized full paper-based energy storage devices with excellent photothermal, self-healing, high energy density and good electromagnetic shielding performances[J]. Journal of Materials Science & Technology, 2022, 97: 190-200.
121	KRAVCHYK K V, KOVALENKO M V. Perspective on design and technical challenges of Li-garnet solid-state batteries[J]. Science and Technology of Advanced Materials, 2022, 23(1): 41-48.
122	XU Tiezhu, WANG Di, LI Zhiwei, et al. Electrochemical proton storage: From fundamental understanding to materials to devices[J]. Nano-Micro Letters, 2022, 14(1): 1-23.
123	SHAHBAZI FARAHANI F, RAHMANIFAR M S, NOORI A, et al. Trilayer metal-organic frameworks as multifunctional electrocatalysts for energy conversion and storage applications[J]. Journal of the American Chemical Society, 2022, 144(8): 3411-3428.
124	LEE Jaehong, LLERENA ZAMBRANO B, Janghoon WOO, et al. Stretchable electronics: Recent advances in 1D stretchable electrodes and devices for textile and wearable electronics: Materials, fabrications, and applications [J]. Advanced Materials, 2020, 32(5): 1902532.
125	YU Chenyang, AN Jianing, CHEN Qiang, et al. Recent advances in design of flexible electrodes for miniaturized supercapacitors Small Methods, 2020, 6(4): 1900824.
126	YU Yan, PAN Diankun, ZHAO Liang, et al. Paper-like polyphenylene sulfide/aramid fiber electrode with excellent areal capacitance and flame-retardant performance[J]. Advanced Fiber Materials, 2022, 4(5): 1246-1255.
127	MILLER E E, HUA Ye, TEZEL F H. Materials for energy storage: Review of electrode materials and methods of increasing capacitance for supercapacitors[J]. Journal of Energy Storage, 2018, 20: 30-40.
128	JIANG Hao, MA Jan, LI Chunzhong. Mesoporous carbon incorporated metal oxide nanomaterials as supercapacitor electrodes[J]. Advanced Materials, 2012, 24(30): 4197-4202.
129	WANG Guoping, ZHANG Lei, ZHANG Jiujun. A review of electrode materials for electrochemical supercapacitors[J]. Chemical Society Reviews, 2012, 41(2): 797-828.
130	FU Lijun, QU Qunting, HOLZE R, et al. Composites of metal oxides and intrinsically conducting polymers as supercapacitor electrode materials: The best of both worlds?[J]. Journal of Materials Chemistry A, 2019, 7(25): 14937-14970.
131	KONIKKARA N, PUNITHAVELAN N, KENNEDY L J, et al. A new approach to solid waste management: Fabrication of supercapacitor electrodes from solid leather wastes using aqueous KOH electrolyte[J]. Clean Technologies and Environmental Policy, 2017, 19(4): 1087-1098.
132	张璐璐. 氮掺杂碳基超级电容器电极材料的制备及性能研究[D]. 哈尔滨: 哈尔滨理工大学, 2020.
	ZHANG Lulu. Fabrication and properties of nitrogen-doped carbon-based supercapacitor electrode materials[D]. Harbin: Harbin University of Science and Technology, 2020.
133	LIU Pengyun, XING Zhihao, WANG Xue, et al. Nanoarchitectonics of nitrogen-doped porous carbon derived from leather wastes for solid-state supercapacitor[J]. Journal of Materials Science: Materials in Electronics, 2022, 33(8): 4887-4901.
134	NIU Jin, LIU Mengyue, XU Feng, et al. Synchronously boosting gravimetric and volumetric performance: Biomass-derived ternary-doped microporous carbon nanosheet electrodes for supercapacitors[J]. Carbon, 2018, 140: 664-672.
135	WU Hongqin, MU Jiahui, XU Yanglei, et al. Heat-resistant, robust, and hydrophilic separators based on regenerated cellulose for advanced supercapacitors[J]. Small, 2023, 19(1): e2205152.
136	YU Haijun, TANG Qunwei, WU Jihuai, et al. Using eggshell membrane as a separator in supercapacitor[J]. Journal of Power Sources, 2012, 206: 463-468.
137	XU Heng, WANG Yaping, LIAO Xuepin, et al. A collagen-based electrolyte-locked separator enables capacitor to have high safety and ionic conductivity[J]. Journal of Energy Chemistry, 2020, 47: 324-332.

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皮胶原在柔性智能可穿戴领域的研究进展

Research progress of leather collagen in flexible intelligent wearable field

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