高通量合成装置强化金属催化剂制备过程的研究进展

doi:10.16085/j.issn.1000-6613.2023-0937

化工进展 ›› 2024, Vol. 43 ›› Issue (1): 246-259.DOI: 10.16085/j.issn.1000-6613.2023-0937

• 专栏：化工过程强化 • 上一篇

高通量合成装置强化金属催化剂制备过程的研究进展

衡霖宇¹^,²(), 邓卓然²^,³, 程道建²^,³(), 魏彬¹^,², 赵利强⁴

^1.北京化工大学机电工程学院，北京 100029
^2.北京化工大学有机无机复合材料国家重点实验室，北京 100029
^3.北京化工大学化学工程学院，北京 100029
^4.北京化工大学信息科学与技术学院，北京 100029

收稿日期:2023-06-07 修回日期:2023-09-02 出版日期:2024-01-20 发布日期:2024-02-05
通讯作者: 程道建
作者简介:衡霖宇（2000—），男，硕士研究生，研究方向为化工过程及装备。E-mail：L18234722057@163.com。

Progress of high-throughput synthesis device for process reinforcement of metal catalyst preparation

HENG Linyu¹^,²(), DENG Zhuoran²^,³, CHENG Daojian²^,³(), WEI Bin¹^,², ZHAO Liqiang⁴

^1.College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
^2.State Key Laboratory of Organic and Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
^3.College of Chemical Engineering, Beijing University of Chemical Technology Beijing 100029, China
^4.College of Information Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China

Received:2023-06-07 Revised:2023-09-02 Online:2024-01-20 Published:2024-02-05
Contact: CHENG Daojian

摘要/Abstract

摘要：

催化剂性能受制备过程多种因素影响，为优化催化剂制备配方与工艺条件，通常需要大量人工操作的实验试错过程，由此造成的低效率与低精度不可避免。在机械自动化控制水平不断发展的背景下，高通量合成装置的研发与投用将提升实验制备催化剂过程的效率、精度与安全性。本综述从金属催化剂常用的合成方法（包括浸渍法、离子交换法、化学气相沉积法和沉淀沉积法）出发，阐述了薄膜沉积法、微流控技术、自动合成机器人、喷墨打印法等高通量合成装置如何协助强化催化材料制备过程和加速催化剂配方优化进程。本文将着重分析金属催化剂制备工艺的需求与高通量合成装置特征之间的一一对应关系。金属催化剂合成过程对高通量合成技术的需求日益增加，构建一种与合成工艺相适配、实用的金属催化剂高通量合成平台，可以为催化剂的研究带来巨大的推动力。

关键词: 催化剂, 制备, 优化设计, 合成装置, 高通量

Abstract:

Catalyst performance is influenced by a variety of factors in the preparation process. To optimize the catalyst preparation formulations and process conditions, a lot of manual trial and error experiments are usually required, resulting low efficiency and precision. With the development of mechanical automation control, the development and implementation of high-throughput synthesis devices will improve the efficiency, accuracy and safety of the catalyst preparation process. In this review, we describe how high-throughput synthesis devices such as thin film deposition, microfluidics, automated synthesis robots, and inkjet printing can help to enhance the process of catalytic material preparation and accelerate the process of catalyst formulation optimization, starting from the commonly used synthesis methods for metal catalysts including impregnation, ion exchange, chemical vapor deposition, and precipitation deposition. This paper will focus on the one-to-one correspondence between the needs of metal nano-catalyst synthesis processes and the characteristics of high-throughput synthesis devices. As the demand for high-flux synthesis technology is increasing day by day, the construction of a practical platform for high-flux synthesis of metal catalysts can bring great impetus to the research of catalysts.

Key words: catalyst, preparation, optimal design, synthesis equipment, high-throughput

中图分类号:

TQ051

衡霖宇, 邓卓然, 程道建, 魏彬, 赵利强. 高通量合成装置强化金属催化剂制备过程的研究进展[J]. 化工进展, 2024, 43(1): 246-259.

HENG Linyu, DENG Zhuoran, CHENG Daojian, WEI Bin, ZHAO Liqiang. Progress of high-throughput synthesis device for process reinforcement of metal catalyst preparation[J]. Chemical Industry and Engineering Progress, 2024, 43(1): 246-259.

图/表 8

图1 高通量合成实验内容

图2 Arai等[20]使用的自动化合成系统

图3 Bergh等[27]使用的自动合成机器人

图4 基于液滴发生器技术的微流控系统

图5 离心微流控装置

图6 薄膜气相沉积步骤[54]

图7 电沉积自动化系统[67]

图8 基于喷墨打印辅助协同组装方法的MMMO合成方案[80]

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高通量合成装置强化金属催化剂制备过程的研究进展

Progress of high-throughput synthesis device for process reinforcement of metal catalyst preparation

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