化工进展 ›› 2023, Vol. 42 ›› Issue (11): 6086-6092.DOI: 10.16085/j.issn.1000-6613.2022-2386

• 资源与环境化工 • 上一篇    

电石炉净化灰矿化模拟烟气中CO2特性分析

王毅斌1(), 马佳慧1, 林翅1, 冯敬武1, 谭厚章1(), 贺力海2, 杨建伟2   

  1. 1.西安交通大学热流科学与工程教育部重点实验室,陕西 西安 710049
    2.新疆中泰矿冶有限公司热电厂,新疆 乌鲁木齐 830001
  • 收稿日期:2022-12-30 修回日期:2023-03-06 出版日期:2023-11-20 发布日期:2023-12-15
  • 通讯作者: 谭厚章
  • 作者简介:王毅斌(1990—),男,副研究员,硕士生导师,研究方向为固废利用。E-mail:ybwang6639@mail.xjtu.edu.cn
  • 基金资助:
    国家自然科学基金(51906198)

Characteristic analysis on CO2 mineralization by purified dusts from calcium carbide furnace

WANG Yibin1(), MA Jiahui1, LIN Chi1, FENG Jingwu1, TAN Houzhang1(), HE Lihai2, YANG Jianwei2   

  1. 1.MOE Key Laboratory of Thermo-Fluid Science and Engineering, Department of Thermal Engineering, Xi’an Jiaotong University, Xi’an 710049, Shaanxi, China
    2.Thermal Power Plant of Xinjiang Zhongtai Mining and Metallurgy Co. , Ltd. , Urumchi 830001, Xinjiang, China
  • Received:2022-12-30 Revised:2023-03-06 Online:2023-11-20 Published:2023-12-15
  • Contact: TAN Houzhang

摘要:

电石生产过程中会产生大量富碱性灰、渣废弃物,具有捕集和矿化CO2的潜力。本文以某电石炉烟气脱除的净化灰为研究对象,以去离子水为浸取剂,对比研究了矿化反应温度、CO2体积分数、液固比对净化灰浸取液吸收CO2中pH和矿化效率的影响,同时也对比了湿法直接矿化和间接矿化的反应差异。实验结果表明,净化灰浸取母液的初始pH处于12.7左右,25℃矿化产物为纳米级方解石。提高反应温度,能够缩短矿化反应时间,促使花瓣状方解石型碳酸钙生成,同时碳酸钙颗粒粒径也会变大。降低液固比和提高CO2体积分数也能缩短矿化反应时间。净化灰的CO2直接矿化效率接近60%,明显高于间接矿化效率,但矿化反应时间却远长于间接矿化方式。

关键词: 矿化, 二氧化碳, 净化灰, 电石, 浸取

Abstract:

A lot of alkaline-rich ash and slag wastes which are produced from calcium carbide production has the potential to capture and then mineralize CO2. In this paper, the purified dust removed from the flue gas of a calcium carbide furnace was viewed as the research object and the deionized water was used as leaching agent. The influences of the mineralized reaction temperature, the volume fraction of CO2, the liquid-to-solid ratio on the pH of the leaching solution from purified dust during CO2 absorption process and the mineralization efficiency were studied. At the same time the reaction difference between direct mineralization and indirect mineralization was compared. The experimental results showed that the initial pH of mother liquor leached by deionized water from purified dust was about 12.7. The CO2 mineralized product of purified dust was calcite with nanoscale diameter at 25 ℃. Enhancing the reaction temperature could shorten the required time for mineralization reaction. Meanwhile, it also promoted the formation of flower-shaped aragonite CaCO3 and its particle grew in size. The mineralization reaction time became shorten through reducing the liquid-to-solid ratio and increased the volume fraction of CO2. The efficiency for direct mineralization was close to about 60%, which was greatly higher than indirect mineralization efficiency. But the reaction time required for direct CO2 mineralization was much longer than that for indirect CO2 mineralization.

Key words: mineralization, CO2, purified dusts, calcium carbide, leaching

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