化工进展 ›› 2022, Vol. 41 ›› Issue (8): 4268-4276.DOI: 10.16085/j.issn.1000-6613.2021-2094
收稿日期:
2021-10-11
修回日期:
2021-12-14
出版日期:
2022-08-25
发布日期:
2022-08-22
通讯作者:
戈明亮
作者简介:
戈明亮(1970—),男,博士,副教授,研究方向为纳米复合材料及功能材料。E-mail:基金资助:
Received:
2021-10-11
Revised:
2021-12-14
Online:
2022-08-25
Published:
2022-08-22
Contact:
GE Mingliang
摘要:
分析了聚丁二炔作为气敏传感材料的机理,总结了不同结构聚丁二炔衍生物作为气敏传感材料的研究现状。本文以聚氨酯、石墨烯、二硫化钼、纤维素纳米晶等增强材料为例,阐述了聚丁二炔复合材料的气敏增强原理、优点及存在的问题,介绍了如食物腐败的检测、便携腕式传感器等新型传感场合的应用研究。目前,聚丁二炔作为气敏传感材料还处于起步阶段,光学转变机理不明确、侧基改性工艺烦琐、官能团种类有限、易受环境影响失效等问题都亟待解决;未来应拓宽对增强材料的选择,调控复合材料的结构以实现对待测气体的高选择性和高灵敏度响应,更要发挥聚丁二炔复合材料成型工艺简单、与环境相容性好的优点,制备更具功能化的气敏材料。
中图分类号:
戈明亮, 何梓宇. 聚丁二炔气敏传感应用的研究现状及展望[J]. 化工进展, 2022, 41(8): 4268-4276.
GE Mingliang, HE Ziyu. Review and perspective of gas sensing application based on polydiacetylene[J]. Chemical Industry and Engineering Progress, 2022, 41(8): 4268-4276.
1 | 傅凯昱. 热致可逆变色的聚二炔材料的构筑和性质研究[D]. 上海: 复旦大学, 2014. |
FU Kaiyu. The molecular construction and properties of polydiacetylene materials with reversible thermochromism[D]. Shanghai: Fudan University, 2014. | |
2 | KIM H N, REN W X, KIM J S, et al. Fluorescent and colorimetric sensors for detection of lead, cadmium, and mercury ions[J]. Chemical Society Reviews, 2012, 41(8): 3210-3244. |
3 | JEONG J P, CHO E, LEE S C, et al. Detection of foot-and-mouth disease virus using a polydiacetylene immunosensor on solid-liquid phase[J]. Macromolecular Materials and Engineering, 2018, 303(6): 1700640. |
4 | PATTANATORNCHAI T, RUEANGSUWAN J, PHONCHAI N, et al. Reversible thermochromic polydiacetylene/Zn(Ⅱ) ion assemblies prepared via co-assembling in aqueous phase: the essential role of pH[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 594: 124649. |
5 | YAO M S, LI W H, XU G. Metal-organic frameworks and their derivatives for electrically-transduced gas sensors[J]. Coordination Chemistry Reviews, 2021, 426: 213479. |
6 | HYODO T, SHIMIZU Y. Adsorption/combustion-type micro gas sensors: typical VOC-sensing properties and material-design approach for highly sensitive and selective VOC detection[J]. Analytical Sciences, 2020, 36(4): 401-411. |
7 | JUNG H S, CHEN X Q, KIM J S, et al. Recent progress in luminescent and colorimetric chemosensors for detection of thiols[J]. Chemical Society Reviews, 2013, 42(14): 6019-6031. |
8 | LOMONACO T, MANCO E, CORTI A, et al. Release of harmful volatile organic compounds (VOCs) from photo-degraded plastic debris: a neglected source of environmental pollution[J]. Journal of Hazardous Materials, 2020, 394: 122596. |
9 | WANG L Y. Metal-organic frameworks for QCM-based gas sensors: a review[J]. Sensors and Actuators A: Physical, 2020, 307: 111984. |
10 | YANG F, ZHENG Z Q, LIN Z Q, et al. Visible-light-driven room-temperature gas sensor based on carbyne nanocrystals[J]. Sensors and Actuators B: Chemical, 2020, 316: 128200. |
11 | LEE S, LEE J, LEE M, et al. Construction and molecular understanding of an unprecedented, reversibly thermochromic bis-polydiacetylene[J]. Advanced Functional Materials, 2014, 24(24): 3699-3705. |
12 | CHANAKUL A, SAYMUNG R, SEETHA S, et al. Solution-mixing method for large-scale production of reversible thermochromic and acid/base-colorimetric sensors[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 615: 126241. |
13 | PENG J S, CHENG Y R, TOMSIA A P, et al. Thermochromic artificial nacre based on montmorillonite[J]. ACS Applied Materials & Interfaces, 2017, 9(29): 24993-24998. |
14 | PARK J H, AHN D J. Fabrication of sensory structure based on poly(ethylene glycol)-diacrylate hydrogel embedding polydiacetylene[J]. Korean Journal of Chemical Engineering, 2017, 34(7): 2092-2095. |
15 | KIM C, HONG C, LEE K. Structures and strategies for enhanced sensitivity of polydiacetylene(PDA) based biosensor platforms[J]. Biosensors and Bioelectronics, 2021, 181: 113120. |
16 | QIAN X M, GARGALO C L, GERNAEY K V, et al. Distinguishing commercial beers using a solution-based sensor array derived from nanoscale polydiacetylene vesicles[J]. ACS Applied Nano Materials, 2020, 3(4): 3439-3448. |
17 | TRAIPHOL N, RUNGRUANGVIRIYA N, POTAI R, et al. Stable polydiacetylene/ZnO nanocomposites with two-steps reversible and irreversible thermochromism: the influence of strong surface anchoring[J]. Journal of Colloid and Interface Science, 2011, 356(2): 481-489. |
18 | SEETHA S, SAYMUNG R, TRAIPHOL R, et al. Controlling self-assembling and color-transition of polydiacetylene/zinc(Ⅱ) ion/zinc oxide nanocomposites by varying pH: effects of surface charge and head group dissociation[J]. Journal of Industrial and Engineering Chemistry, 2019, 72: 423-431. |
19 | ZHANG X N, DENG C, WANG M, et al. Topochemical polymerisation of assembled diacetylene macrocycle bearing dibenzylphosphine oxide in solid state[J]. Supramolecular Chemistry, 2017, 29(2): 94-101. |
20 | 崔丽影, 宋志洋, 赵欣宇, 等. 丁二炔衍生物的制备及其光学特性[J]. 发光学报, 2016, 37(12): 1491-1495. |
CUI Liying, SONG Zhiyang, ZHAO Xinyu, et al. Fabrication and optical property of diacetylene derivative[J]. Chinese Journal of Luminescence, 2016, 37(12): 1491-1495. | |
21 | KIM H N, GUO Z Q, ZHU W H, et al. Recent progress on polymer-based fluorescent and colorimetric chemosensors[J]. Chemical Society Reviews, 2011, 40(1): 79-93. |
22 | VALDEZ M, GUPTA S K, LOZANO K, et al. ForceSpun polydiacetylene nanofibers as colorimetric sensor for food spoilage detection[J]. Sensors and Actuators B: Chemical, 2019, 297: 126734. |
23 | MAEKAWA Y, SAKAMOTO N, KOKADO R, et al. Structural relaxation accompanied by photo-induced chromatic phase transition of polydiacetylenes with butylene-N-difluorophenyl carbamate side chains[J]. Journal of Luminescence, 2013, 133: 86-90. |
24 | 何欣. 红荧烯和聚丁二炔电学性质的实验研究[D]. 武汉: 华中科技大学, 2019. |
HE Xin. The experimental study of the electrical properties of rubrene and polydiacetylenes[D]. Wuhan: Huazhong University of Science and Technology, 2019. | |
25 | PARK J H, CHOI H, CUI C Z, et al. Capillary-driven sensor fabrication of polydiacetylene-on-silica plate in 30 seconds: facile utilization of π-monomers with C18- to C25-long alkyl chain[J]. ACS Omega, 2017, 2(10): 7444-7450. |
26 | 霍景沛, 王淑妮, 刘盈珍, 等. 不同端基的智能聚二乙炔材料的研究进展[J]. 化学推进剂与高分子材料, 2019, 17(4): 16-21. |
HUO Jingpei, WANG Shuni, LIU Yingzhen, et al. Research progress of intelligent polydiacetylene materials with different end groups[J]. Chemical Propellants & Polymeric Materials, 2019, 17(4): 16-21. | |
27 | PARK D H, HEO J M, JEONG W, et al. Smartphone-based VOC sensor using colorimetric polydiacetylenes[J]. ACS Applied Materials & Interfaces, 2018, 10(5): 5014-5021. |
28 | QIAN X M, STÄDLER B. Recent developments in polydiacetylene-based sensors[J]. Chemistry of Materials, 2019, 31(4): 1196-1222. |
29 | CHO S H, SUH J M, EOM T H, et al. Colorimetric sensors for toxic and hazardous gas detection: a review[J]. Electronic Materials Letters, 2021, 17(1): 1-17. |
30 | KASSIS R, BASSIL M, CHOUEIRY A AL. Evaluating the effect of the surface morphology on the colorimetric sensitivity of poly-vinyl-pyrrolidone polydiacetylene composites[J]. Materials Research Express, 2018, 6(1): 015706. |
31 | CHANAKUL A, TRAIPHOL R, TRAIPHOL N. Colorimetric sensing of various organic acids by using polydiacetylene/zinc oxide nanocomposites: effects of polydiacetylene and acid structures[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 489: 9-18. |
32 | LEE S Y, KIM J Y, CHEN X Q, et al. Recent progress in stimuli-induced polydiacetylenes for sensing temperature, chemical and biological targets[J]. Chemical Communications, 2016, 52(59): 9178-9196. |
33 | KIM M O, KHAN M Q, ULLAH A, et al. Development of VOCs gas sensor with high sensitivity using colorimetric polymer nanofiber: a unique sensing method[J]. Materials Research Express, 2019, 6(10): 105372. |
34 | KIM M, SHIN Y J, SHIN M J, et al. Gas-sensor fabrication by a layer-by-layer technique using polydiacetylene[J]. Journal of Applied Polymer Science, 2017, 134(26): 44997. |
35 | PARK S, LEE G S, CUI C Z, et al. Simple detection of food spoilage using polydiacetylene/poly(vinyl alcohol) hybrid films[J]. Macromolecular Research, 2016, 24(4): 380-384. |
36 | MERGU N, KIM H, HEO G, et al. Fabrication and topochemically controlled diacetylene-based polymer and its colorimetric application toward HCl detection[J]. Dyes and Pigments, 2020, 174: 108061. |
37 | SABA N, TAHIR P, JAWAID M. A review on potentiality of nano filler/natural fiber filled polymer hybrid composites[J]. Polymers, 2014, 6(8): 2247-2273. |
38 | TRAIPHOL N, CHANAKUL A, KAMPHAN A, et al. Role of Zn2+ ion on the formation of reversible thermochromic polydiacetylene/zinc oxide nanocomposites[J]. Thin Solid Films, 2017, 622: 122-129. |
39 | SUPPAKUL P, KIM D Y, YANG J H, et al. Practical design of a diffusion-type time-temperature indicator with intrinsic low temperature dependency[J]. Journal of Food Engineering, 2018, 223: 22-31. |
40 | SONG S, CHO H B, LEE H W, et al. Onsite paper-type colorimetric detector with enhanced sensitivity for alkali ion via polydiacetylene-nanoporous rice husk silica composites[J]. Materials Science and Engineering C, 2019, 99: 900-904. |
41 | DOLAI S, BHUNIA S K, BEGLARYAN S S, et al. Colorimetric polydiacetylene-aerogel detector for volatile organic compounds (VOCs)[J]. ACS Applied Materials & Interfaces, 2017, 9(3): 2891-2898. |
42 | CHANAKUL A, TRAIPHOL N, FAISADCHA K, et al. Dual colorimetric response of polydiacetylene/zinc oxide nanocomposites to low and high pH[J]. Journal of Colloid and Interface Science, 2014, 418: 43-51. |
43 | PHONCHAI N, KHANANTONG C, KIELAR F, et al. Enhancing thermal and chemical sensitivity of polydiacetylene colorimetric sensors: the opposite effect of zinc oxide nanoparticles[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 589: 124459. |
44 | 王晓娜. 石墨烯功能结构的制备和性能及传感应用[D]. 哈尔滨: 哈尔滨工业大学, 2015. |
WANG Xiaona. Synthesis and properties and sensing applications of graphene functional structures[D]. Harbin: Harbin Institute of Technology, 2015. | |
45 | GAO B Y, YUAN G J, REN L L. Polydiacetylene-functionalized alumina aerogels as visually observable sensing materials for detecting VOCs concentration[J]. Journal of Materials Science, 2018, 53(9): 6698-6706. |
46 | WANG T, GUO Y L, WAN P B, et al. A flexible transparent colorimetric wrist strap sensor[J]. Nanoscale, 2017, 9(2): 869-874. |
47 | LI Q F, REN S Y, PENG Y, et al. A colorimetric strip for rapid detection and real-time monitoring of histamine in fish based on self-assembled polydiacetylene vesicles[J]. Analytical Chemistry, 2020, 92(1): 1611-1617. |
48 | NGUYEN L H, OVEISSI F, CHANDRAWATI R, et al. Naked-eye detection of ethylene using thiol-functionalized polydiacetylene-based flexible sensors[J]. ACS Sensors, 2020, 5(7): 1921-1928. |
49 | ARDILA-DIAZ L D, OLIVEIRA T V, SOARES N. Development and evaluation of the chromatic behavior of an intelligent packaging material based on cellulose acetate incorporated with polydiacetylene for an efficient packaging[J]. Biosensors, 2020, 10(6): 59. |
50 | NGUYEN L H, NAFICY S, MCCONCHIE R, et al. Polydiacetylene-based sensors to detect food spoilage at low temperatures[J]. Journal of Materials Chemistry C, 2019, 7(7): 1919-1926. |
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