化工进展 ›› 2022, Vol. 41 ›› Issue (5): 2404-2415.DOI: 10.16085/j.issn.1000-6613.2021-1014
陈治平1,2,3(), 王苗苗1, 韦晓艺1, 周文武1,2,3(), 杨志远1,2,3, 周安宁1,2,3
收稿日期:
2021-05-12
修回日期:
2021-07-19
出版日期:
2022-05-05
发布日期:
2022-05-24
通讯作者:
周文武
作者简介:
陈治平(1982—),男,博士,硕士生导师,研究方向为多孔材料与催化反应工程。E-mail:基金资助:
CHEN Zhiping1,2,3(), WANG Miaomiao1, WEI Xiaoyi1, ZHOU Wenwu1,2,3(), YANG Zhiyuan1,2,3, ZHOU Anning1,2,3
Received:
2021-05-12
Revised:
2021-07-19
Online:
2022-05-05
Published:
2022-05-24
Contact:
ZHOU Wenwu
摘要:
近年来研究者发现复合分子筛具有孔结构丰富、水热稳定性良好、表面性质可调控等优点,在烃类异构化反应中表现出比单一分子筛更高的反应活性和更好的异构体选择性。本文综述了丝光沸石分子筛(MOR)、Y型分子筛、β分子筛、ZSM系列分子筛、SAPO系列分子筛等两两复合的微孔-微孔复合分子筛和微孔分子筛与MCM-41分子筛、SBA-15分子筛等介孔分子筛复合的微孔-介孔复合分子筛在烷烃异构化、烯烃异构化等反应中的应用研究进展,并对用于烃类异构化复合分子筛的研究与发展方向进行了展望,指出复合分子筛用于真实石油馏分的异构化研究仍需更深入、系统地展开;采用绿色高效的合成方法合成复合分子筛以及探究通过复合分子筛的结构设计和酸性调控,如何进一步提高复合分子筛在烃类异构化反应中的活性和选择性是未来研究的重点。
中图分类号:
陈治平, 王苗苗, 韦晓艺, 周文武, 杨志远, 周安宁. 复合分子筛在烃类异构化反应中的应用研究进展[J]. 化工进展, 2022, 41(5): 2404-2415.
CHEN Zhiping, WANG Miaomiao, WEI Xiaoyi, ZHOU Wenwu, YANG Zhiyuan, ZHOU Anning. Application of composite molecular sieve in hydrocarbon isomerization[J]. Chemical Industry and Engineering Progress, 2022, 41(5): 2404-2415.
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