CO2/N2-紫外光双重响应蠕虫状胶束制备

doi:10.16085/j.issn.1000-6613.2020-2535

化工进展 ›› 2021, Vol. 40 ›› Issue (12): 6785-6791.DOI: 10.16085/j.issn.1000-6613.2020-2535

CO₂/N₂-紫外光双重响应蠕虫状胶束制备

张文鹏¹(), 刘东芳², 吴洋³, 鲁红升³()

^1.中海油能源发展股份有限公司工程技术分公司，天津 300456
^2.西华大学理学院，四川成都 610039
^3.西南石油大学化学化工学院，四川成都 610500

收稿日期:2020-12-21 修回日期:2021-03-29 出版日期:2021-12-05 发布日期:2021-12-21
通讯作者: 鲁红升
作者简介:张文鹏（1982－），男，工程师，硕士研究生，主要从事从事海上油田提高采收率及化学驱研究。E-mail: zhangwp3@cnooc.com.cn。
基金资助:
高分子材料国家重点实验室开放基金(KF201305);四川省教育厅创新团队项目(13TD0025)

Preparation of worm-like micelles with dual response of CO₂/N₂ and ultraviolet light

ZHANG Wenpeng¹(), LIU Dongfang², WU Yang³, LU Hongsheng³()

^1.CNOOC Energy Development Co. , Ltd. , Engineering Technology Branch，Tianjin 300456, China
^2.College of Science，Xihua University, Chengdu 610039, Sichuan, China
^3.College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, China

Received:2020-12-21 Revised:2021-03-29 Online:2021-12-05 Published:2021-12-21
Contact: LU Hongsheng

摘要/Abstract

摘要：

通过N,N-二甲基十二烷基胺（DMA）、十六烷基三甲基溴化铵（CTAB）以及肉桂酸钠（CA）构建了一种具有CO₂/N₂-紫外光双重响应的蠕虫状胶束体系。研究发现DMA、CTAB、CA组成的体系黏度较低，不能形成蠕虫状胶束，向上述体系中引入CO₂后会引起DMA的质子化，从而导致表面活性剂分子在体系中的排列方式发生改变并形成蠕虫状胶束。在通入N₂后蠕虫状胶束会可逆地转变为球状胶束。进一步研究发现，由于CA可以在紫外光的照射下实现反式结构与顺式结构的转变，对已经形成的蠕虫状胶束体系照射紫外光也可以形成黏度较低的球状胶束。

关键词: 表面活性剂, 胶束, 紫外光, 二氧化碳, 响应

Abstract:

A worm-like micelle system with a dual response of CO₂/N₂-UV light was constructed by mixing N,N-dimethyldodecylamine (DMA), cetyltrimethylammonium bromide (CTAB) and sodium cinnamate (CA). Further research found that the system composed of DMA, CTAB and CA had low viscosity and could not form worm-like micelles. However, the introduction of CO₂ can lead to the formation of worm-like micelles, which was due to the protonation of DMA that changed the arrangement of surfactant molecules in the system. After passing N₂, the worm-like micelles would reversibly transform into spherical micelles. Ultraviolet light irradiation can transform worm-like micelles into spherical micelles with lower viscosity because CA can realize the transformation of trans-structure and cis-structure under the irradiation of ultraviolet light.

Key words: surfactants, micelles, ultraviolet light, carbon dioxide, responsive

中图分类号:

O648

张文鹏, 刘东芳, 吴洋, 鲁红升. CO₂/N₂-紫外光双重响应蠕虫状胶束制备[J]. 化工进展, 2021, 40(12): 6785-6791.

ZHANG Wenpeng, LIU Dongfang, WU Yang, LU Hongsheng. Preparation of worm-like micelles with dual response of CO₂/N₂ and ultraviolet light[J]. Chemical Industry and Engineering Progress, 2021, 40(12): 6785-6791.

图/表 14

图1 去离子水在通入CO2和N2之后的电导率变化图

图2 10mmol/L DMA水溶液在通入CO2和N2之后的电导率变化图

图3 DMA在水中与CO2发生质子化的过程

图4 肉桂酸钠在紫外光照射后结构转变

图5 0.1mmol/L肉桂酸钠溶液的紫外吸收谱图

图6 CTAB-CA-DMA-CO2稳态黏度随剪切速率的变化关系图

图7 CTAB-CA-DMA-CO2的动态流变图

图8 胶束体系的CO2和N2响应图片

图9 通入CO2/N2对CTAB-CA-DMA-CO2胶束体系黏度的影响

图10 胶束的微观结构图片

图11 紫外光对CTAB-CA-DMA-CO2体系的稳态流变性影响

图12 紫外光对CTAB-CA-DMA-CO2体系的动态流变性影响

图13 不同体系的动态光散射曲线

图14 CO2和UV对CA-CTAB-DMA三元体系自组装微观结构影响的示意图

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CO₂/N₂-紫外光双重响应蠕虫状胶束制备

Preparation of worm-like micelles with dual response of CO₂/N₂ and ultraviolet light

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