化工进展 ›› 2021, Vol. 40 ›› Issue (6): 3480-3488.DOI: 10.16085/j.issn.1000-6613.2020-1469
田婷婷1,2(), 李朝阳1,2, 王召东2, 陆慧2, 李新冬1(), 毛艳丽2, 宋忠贤2, 朱新锋2()
收稿日期:
2020-07-29
修回日期:
2020-10-19
出版日期:
2021-06-06
发布日期:
2021-06-22
通讯作者:
李新冬,朱新锋
作者简介:
田婷婷(1996—),女,硕士研究生,研究方向为污水处理技术。E-mail:基金资助:
TIAN Tingting1,2(), LI Chaoyang1,2, WANG Shaodong2, LU Hui2, LI Xindong1(), MAO Yanli2, SONG Zhongxian2, ZHU Xinfeng2()
Received:
2020-07-29
Revised:
2020-10-19
Online:
2021-06-06
Published:
2021-06-22
Contact:
LI Xindong,ZHU Xinfeng
摘要:
活化过硫酸盐高级氧化技术用于降解水体中有机污染物备受关注,其中采用过渡金属活化过硫酸盐降解有机污染物的研究越来越多,也取得了良好的效果。本文综述了近几年来国内外利用以过渡金属为基础的催化剂活化过硫酸盐降解污染物的应用研究;阐述了贵金属催化剂、单金属催化剂、复合金属催化剂(尖晶石结构催化剂、纳米核壳结构催化剂、三维纳米结构催化剂)在水体中降解有机污染物的研究进展;探讨了过渡金属催化剂的优缺点和研究现状,最后提出了该活化体系目前面临的问题,期望为过渡金属活化过硫酸盐降解污染物技术的应用提供参考。
中图分类号:
田婷婷, 李朝阳, 王召东, 陆慧, 李新冬, 毛艳丽, 宋忠贤, 朱新锋. 过渡金属活化过硫酸盐降解有机废水技术研究进展[J]. 化工进展, 2021, 40(6): 3480-3488.
TIAN Tingting, LI Chaoyang, WANG Shaodong, LU Hui, LI Xindong, MAO Yanli, SONG Zhongxian, ZHU Xinfeng. Research progress of transition metal activated persulfate to degrade organic wastewater[J]. Chemical Industry and Engineering Progress, 2021, 40(6): 3480-3488.
活化方式 | 机理 | 主要的自由基种类 | 特点 | 参考文献 |
---|---|---|---|---|
热活化 | S2O SO SO | ·OH和SO | 氧化性强,需要高温环境;在中性或碱性下反应速率高,污水中存在阴离子会影响污染物的降解 | [ |
碱活化 | 2S2O | 还原剂(超氧化物)和SO | 污染物在24h才能被完全降解,反应时间过长,且需要的过硫酸盐和碱的含量很大 | [ |
UV活化 | S2O | ·OH和SO | 受pH的影响较大,会随着污水的成分不同产生不同的副产物,增加二次污染 | [ |
以碳为基础的材料活化 | 利用以碳为基础的材料具有比表面积大、吸附性能高、化学稳定性好等特点将金属离子负载在其表面增加活性位点,提高污染物的降解率 | SO | 催化剂稳定性好,重复使用率高,适用pH范围广,可以降解的污染物种类多,但催化剂的制备过程复杂,制作成本高 | [ |
电活化 | 在电流的作用下,水被电解产生·OH,附着在电极表面的表面活性剂得失电子,两者共同降解污染物 | SO | 受电流密度影响较大,阳极材料受限制,非活性阳极材料需要加入可以产生高活性物质的表面活性剂,成本高 | [ |
超声活化 | 超声波产生的气蚀、高温高压促使过硫酸盐中的O—O键断裂,产生SO | SO | 活化过程受超声功率、频率、pH、温度的影响较大;对处理大量的实际污水存在困难 | [ |
表1 各种活化方式的活化机理比较
活化方式 | 机理 | 主要的自由基种类 | 特点 | 参考文献 |
---|---|---|---|---|
热活化 | S2O SO SO | ·OH和SO | 氧化性强,需要高温环境;在中性或碱性下反应速率高,污水中存在阴离子会影响污染物的降解 | [ |
碱活化 | 2S2O | 还原剂(超氧化物)和SO | 污染物在24h才能被完全降解,反应时间过长,且需要的过硫酸盐和碱的含量很大 | [ |
UV活化 | S2O | ·OH和SO | 受pH的影响较大,会随着污水的成分不同产生不同的副产物,增加二次污染 | [ |
以碳为基础的材料活化 | 利用以碳为基础的材料具有比表面积大、吸附性能高、化学稳定性好等特点将金属离子负载在其表面增加活性位点,提高污染物的降解率 | SO | 催化剂稳定性好,重复使用率高,适用pH范围广,可以降解的污染物种类多,但催化剂的制备过程复杂,制作成本高 | [ |
电活化 | 在电流的作用下,水被电解产生·OH,附着在电极表面的表面活性剂得失电子,两者共同降解污染物 | SO | 受电流密度影响较大,阳极材料受限制,非活性阳极材料需要加入可以产生高活性物质的表面活性剂,成本高 | [ |
超声活化 | 超声波产生的气蚀、高温高压促使过硫酸盐中的O—O键断裂,产生SO | SO | 活化过程受超声功率、频率、pH、温度的影响较大;对处理大量的实际污水存在困难 | [ |
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