高稳定性超疏水材料研究进展

doi:10.16085/j.issn.1000-6613.2018-1366

摘要/Abstract

摘要：

近年来，众多研究者通过物理或化学方法，将超疏水材料与不同基底或材料结合，制备出了能够抵抗各种机械磨损和溶剂、气体、紫外照射、颗粒、酸碱和细菌的，具有优良耐磨损性和稳定性的超疏水材料。本文主要介绍了超疏水材料表面机械稳定性差的原因以及评估超疏水材料耐磨损性的常见方法，根据制备方法和基底的不同将超疏水材料分为三类，分别从网格类、织物类和涂层类等方面对近年来具有耐磨损性和稳定性超疏水表面的研究成果进行综述，对高稳定性超疏水材料的研究进展有一个全面的认识，并总结了目前在制备高稳定性超疏水材料这一领域存在的一些问题，例如测试高稳定性的方法较少、没有统一的标准等，开发和研究能够二次利用以及多功能超疏水材料仍是一大挑战。

关键词: 超疏水, 耐磨性, 稳定性, 制备

Abstract:

In recent years, researchers have used many physical and chemical methods to prepare superhydrophobic materials in combination with other materials with wear resistance and stability. It is very important to prepare various superhydrophobic surfaces which can be resistant to abrasion and solvents, gases, ultraviolet radiation, acid and alkali. In this paper, the method for testing the wear resistance and stability of superhydrophobic surface as well as the cause of poor wear resistance and stability were introduced. Then, the research results about the wear resistant and stability superhydrophobic surfaces are summarized from the aspects of meshes, fabrics and coatings, so that a comprehensive understanding of the research progress of the stability superhydrophobic materials is attained. The challenges and applications wear resistant and stable superhydrophobic materials are forecasted in this review. Finally, we summarize the problems of stable superhydrophobic materials, for example, there are few methods for testing the stability, and there isn^，t generally accepted standard. In addition, the research and development in secondary utilization and multifunctionlization of superhydrophobic materials are still of big challenges.

Key words: superhydrophobic, wear resistance, stability, preparation

中图分类号:

TQ423

何金梅, 何姣, 袁明娟, 薛萌辉, 刘向荣, 屈孟男. 高稳定性超疏水材料研究进展[J]. 化工进展, 2019, 38(07): 3013-3027.

Jinmei HE, Jiao HE, Mingjuan YUAN, Menghui XUE, Xiangrong LIU, Mengnan QU. Research progress of superhydrophobic materials with high-stability property[J]. Chemical Industry and Engineering Progress, 2019, 38(07): 3013-3027.

图/表 18

图1 超疏水涂层的砂纸磨损实验示意图

图2 超疏水表面耐磨损测试[24]

图3 耐磨超疏水表面磨损后的SEM图[24]

图4 超疏水铝表面制备示意图和水接触角与超疏水表面的胶带测试次数的关系图[25]

图5 聚酯基超疏水表面的制备过程[34]

图6 水接触角与磨损周期关系图和2000次循环机械磨损实验后表面水滴呈球形[35]

图7 磨损测试示意图、磨损距离和水接触角的关系图以及砂纸磨损后的SEM图[36]

图8 经过1000次磨损循环后，氟化的超疏水棉织物的SEM图像[43]

图9 二氧化硅气凝胶示意图和超双疏机械磨损的示意图[44]

图10 聚乳酸无纺布拉伸测试[50]

图11 不同型号的砂纸磨损周期和接触角间的关系和超疏水棉织物与胶带撕裂测试周期的变化[51]

图12 超疏水材料的水接触角和滑动角随摩擦循环次数增加的关系图以及超疏水材料铅笔硬度测试(硬度6B到4H)[57]

图13 砂纸磨损示意图和磨损循环测试图以及刀刮测试图[59]

图14 胶带粘附测试[60]

图15 用于制造基于HMSN的超疏水涂层的示意图[64]

图16 各种环境下对超疏水材料的稳定性测试[65]

图17 金黄色葡萄球菌和大肠杆菌抗菌测试关系图[66]

图18 耐火测试[78]

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