牛血清白蛋白纳米球接枝杨梅单宁的制备以及吸附去除水体中Pb2+的性能

doi:10.16085/j.issn.1000-6613.2018-0885

化工进展 ›› 2019, Vol. 38 ›› Issue (02): 1075-1084.DOI: 10.16085/j.issn.1000-6613.2018-0885

牛血清白蛋白纳米球接枝杨梅单宁的制备以及吸附去除水体中Pb²⁺的性能

冯健¹(),余杰¹,周建^1,²(),张永德²,林晓艳²,罗学刚^1,²

1. 西南科技大学生命科学与工程学院，四川绵阳 621010
2. 西南科技大学生物质教育部工程研究中心，四川;绵阳 621010

收稿日期:2018-04-28 修回日期:2018-06-22 出版日期:2019-02-05 发布日期:2019-02-05
通讯作者: 周建
作者简介:<named-content content-type="corresp-name">冯健</named-content>（1996—），男，本科生。E-mail：<email>1764503194@qq.com</email>。|周建，副研究员，硕士生导师，研究方向为生物质化学与工程。E-mail：<email>zhoujian@swust.edu.cn</email>。
基金资助:
国家自然科学基金(21406182);四川省教育厅科研项目(17ZB0443);核废物与环境安全国防重点学科开放基金(15kffk02)

Removal of Pb²⁺ from aqueous solution using bovine serum albumin nanospheres grafted with bayberry tannin

Jian FENG¹(),Jie YU¹,Jian ZHOU^1,²(),Yongde ZHANG²,Xiaoyan LIN²,Xuegang LUO^1,²

1. School of Life Sciences and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
2. Biomass Engineering Research Center of the Ministry of Education, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China

Received:2018-04-28 Revised:2018-06-22 Online:2019-02-05 Published:2019-02-05
Contact: Jian ZHOU

摘要/Abstract

摘要：

采用去溶剂法和杨梅单宁-戊二醛固化接枝制备得到杨梅单宁（BT）接枝牛血清白蛋白（BSA）纳米球（BSA-BT-NSs）吸附材料，并系统探讨了其在不同吸附条件下对水体中Pb²⁺的吸附去除性能。研究结果表明：50%用量杨梅单宁（基于BSA-NSs量）接枝固化得到的BSA-BT-NSs具有较好的球形结构和良好的分散性。在吸附实验中，Pb²⁺初始浓度为250mg/L、pH 5.0、温度为298K 条件下吸附20min，BSA-BT-NSs（0.4g/L）对Pb²⁺的吸附效果最佳，最大吸附容量为76mg/g，优于多数同类型吸附材料。BSA-BT-NSs对Pb²⁺吸附过程符合Langmuir方程和准二级吸附动力学模型，且吸附后的BSA-BT-NSs经0.1mol/L 硝酸进行解吸取得了92.04％的良好解吸效果，并可再次重复使用。进一步分析其Pb²⁺吸附机理，表明BSA-BT-NSs中的氨基氮原子、羟基和羧基氧原子作为电子供体参与了与Pb²⁺的空轨道发生配位作用。

关键词: 牛血清白蛋白, 杨梅单宁, 铅离子, 吸附, 纳米球

Abstract:

Bayberry tannin grafted bovine serum albumin nanaopheres (BSA-BT-NSs) were prepared using the desolvent method, and the removal performances of Pb²⁺ onto BSA-BT-NSs were investigated systematically under different removal conditions, including pH, adsorbent dose, contact time, and initial Pb²⁺ concentration. The results showed that BSA-BT-NSs dispersed uniformly having a good spherical structure grafting with 50% of bayberry tannin (based on the amount of BSA-NSs). The maximum adsorption capacity of BSA-BT-NSs for Pb²⁺ reached up to 76mg/g using 0.4g/L of adsorbent dosage to treat the Pb²⁺ containing solution with the initial concentration of 250mg/L at pH 5.0 and 298K for 20min．The adsorption processes of Pb²⁺ onto BSA-BT-NSs were well-fitted to Langmuir model and pseudo-secondary adsorption kinetics model, indicating a single layer chemical adsorption. A desorption efficiency of 92.04% was obtained using 0.1mol/L nitric acid as eluent to carry out the desorption experiments of Pb²⁺ on BSA-BT-NSs, which could be reused. Furthermore, nitrogen on amino, oxygen on hydroxyl and carboxyl of BSA-BT-NSs were involved as electron donors to form coordination complexes with the empty orbital of Pb²⁺.

Key words: bovine serum albumin, bayberry tannin, lead ions, adsorption, nanospheres

中图分类号:

X703

冯健, 余杰, 周建, 张永德, 林晓艳, 罗学刚. 牛血清白蛋白纳米球接枝杨梅单宁的制备以及吸附去除水体中Pb²⁺的性能[J]. 化工进展, 2019, 38(02): 1075-1084.

Jian FENG, Jie YU, Jian ZHOU, Yongde ZHANG, Xiaoyan LIN, Xuegang LUO. Removal of Pb²⁺ from aqueous solution using bovine serum albumin nanospheres grafted with bayberry tannin[J]. Chemical Industry and Engineering Progress, 2019, 38(02): 1075-1084.

图/表 16

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吸附动力学模型	动力学常数 k	Q _e	相关系数 R ²
准一级动力学	0.2308	18.5780	0.9604
准二级动力学	0.0067	61.3497	0.9954

吸附动力学模型	动力学常数 k	Q _e	相关系数 R ²
准一级动力学	0.2308	18.5780	0.9604
准二级动力学	0.0067	61.3497	0.9954

T/K	Langmuir			Freundlich
T/K	Q _m/mg·g^-1	K _L/L·mg^-1	R²	K _f	1/n	R²
288	76.3359	0.0634	0.9997	29.7521	0.1662	0.9837
298	80.6452	0.0752	0.9996	30.4717	0.1772	0.8905
308	72.9927	0.0665	0.9998	29.3297	0.1612	0.9786

T/K	Langmuir			Freundlich
T/K	Q _m/mg·g^-1	K _L/L·mg^-1	R²	K _f	1/n	R²
288	76.3359	0.0634	0.9997	29.7521	0.1662	0.9837
298	80.6452	0.0752	0.9996	30.4717	0.1772	0.8905
308	72.9927	0.0665	0.9998	29.3297	0.1612	0.9786

生物质吸附剂	pH	温度/K	Q _max/mg·g^-1
棕榈壳^[36]	3.0	300	95.2
BSA-BT-NSs	5.0	298	80.65
椰子壳^[37]	5.6	298	76.66
干面包酵母^[38]	5.0	303	60.24
狐尾藻^[39]	5.0	298	53.87
菜豆废弃物^[40]	5.0	293	42.77
大豆皮^[41]	5.0	296	39.37
松果^[42]	—	298	27.53
凤眼莲^[43]	4.84	303	26.32
杏核^[44]	6.5	298	22.85
樟子松锯末^[45]	5.0	298	22.22
HNO₃处理的橄榄树^[46]	5.0	298	14.15
茶叶废料^[47]	5.8	303	1.35

牛血清白蛋白纳米球接枝杨梅单宁的制备以及吸附去除水体中Pb²⁺的性能

Removal of Pb²⁺ from aqueous solution using bovine serum albumin nanospheres grafted with bayberry tannin

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参考文献 58

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合成吸附剂	pH	温度 /K	Q _max /mg·g^-1
合成矿物吸附剂^[48]	3.0	328	157.9
三亚乙基四胺改性聚苯乙烯树脂^[49]	6.0	353	154.71
改性的磁赤铁矿纳米粒子^[50]	6.0	298	118.51
磁性Fe₃O₄ /粉末活性炭复合材料(Fe₃O₄/PAC)^[51]	6.0	323	94.3
壳聚糖修饰的MCM-41-A^[52]	6.0	—	90.91
BSA-BT-NSs	5.0	298	80.65
Pb²⁺离子印迹聚合物（Pb²⁺-IIP）^[53]	6.0	288	42.55
Pb²⁺-印迹聚甲基丙烯酸(IIP/PAN)^[54]	5.7	298	41.4
纳米复合水凝胶（丙烯酸 - 丙烯酰胺）^[55]	6.0	—	35.94

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