碳酸二甲酯-甲醇共沸体系分离的模拟与控制

doi:10.16085/j.issn.1000-6613.2017.03.012

化工进展 ›› 2017, Vol. 36 ›› Issue (03): 852-862.DOI: 10.16085/j.issn.1000-6613.2017.03.012

碳酸二甲酯-甲醇共沸体系分离的模拟与控制

刘立新¹, 李鲁闽², 刘桂丽¹, 何康³, 孙兰义²

1 青岛理工大学汽车与交通学院, 山东青岛 266520;
2 中国石油大学(华东)化学工程学院, 山东青岛 266580;
3 镇海石化工程股份有限公司设计部, 浙江宁波 315000

收稿日期:2016-07-11 修回日期:2016-09-16 出版日期:2017-03-05 发布日期:2017-03-05
通讯作者: 孙兰义,博士,教授,研究方向为过程模拟与优化、过程控制。
作者简介:刘立新(1972-),女,硕士,副教授,研究方向为道路新材料、工艺、设备及控制。E-mail:llx297403478@163.com。
基金资助:
山东省自然科学基金（ZR2013EEM024）及山东省高等学校科技计划（J14LA08）项目。

Comparison of alternative configurations for separation of dimethyl carbonate-methanol mixture: steady state simulation and dynamic control

LIU Lixin¹, LI Lumin², LIU Guili¹, HE Kang³, SUN Lanyi²

1 College of Automobile and Transportation, Qingdao University of Technology, Qingdao 266520, Shandong, China;
2 College of Chemical Engineering, China University of Petroleum, Qingdao 266580, Shandong, China;
3 Design Department, Zhenhai Petrochemical Engineering Company Limited, Ningbo 315000, Zhejiang, China

Received:2016-07-11 Revised:2016-09-16 Online:2017-03-05 Published:2017-03-05

摘要/Abstract

摘要：

作为一种新环保型化工产品，碳酸二甲酯近年来在各行业中得到了广泛应用。由于碳酸二甲酯产品中常含有与之形成共沸物的甲醇，因此需要特殊工艺对其进行分离。本文利用Aspen Plus软件建立了严格稳态模型，对比了萃取精馏、共沸精馏和变压精馏分离碳酸二甲酯-甲醇二元共沸物的3种分离工艺，并以系统能耗为目标进行单变量分析，得到最低能耗下的萃取精馏、共沸精馏、变压精馏工艺参数。稳态分析结果表明：萃取精馏过程能耗只占变压精馏的29.0%、占共沸精馏的30.2%，其节能优势明显。在此基础上，采用Aspen Dynamics软件对萃取精馏最佳工艺进行了控制研究，提出了两种控制结构。结果表明，含有固定再沸器/进料比例的改进控制结构能够有效地应对进料流量与进料组成扰动，保证碳酸二甲酯和甲醇产品纯度。

关键词: 碳酸二甲酯-甲醇, 共沸物, 精馏, 优化, 控制

Abstract:

Dimethyl carbonate(DMC) is a new kind of industrial product,which has extensively applied in different aspects. Special distillation is required to separate the mixture of DMC and methanol since methanol usually exists in the DMC product. Three special distillation configurations including extractive distillation,azeotropic distillation and pressure swing distillation were proposed to separate the DMC-MeOH azeotrope system. The steady-state simulations of the three processes were established by Aspen Plus,and the optimum parameters of the three processes with minimum energy requirement have been obtained using sensitive analyses. The simulation results showed that energy requirement of extractive distillation accounts for 29.0% of the pressure swing distillation and 30.2% of the azeotropic distillation respectively,which shows a good energy-saving potential. Control of extractive distillation process with minimum energy consumption was investigated using the Aspen Dynamics,and two control structures were proposed. The control structure with fixed reboiler duty/feed rate ratio was proposed based on the basic control structure,and the dynamic simulation results revealed that this control structure can handle feed flow rate and composition disturbances quite effectively.

Key words: dimethyl carbonate-methanol, azeotrope, distillation, optimization, control

中图分类号:

TQ028.1

刘立新, 李鲁闽, 刘桂丽, 何康, 孙兰义. 碳酸二甲酯-甲醇共沸体系分离的模拟与控制[J]. 化工进展, 2017, 36(03): 852-862.

LIU Lixin, LI Lumin, LIU Guili, HE Kang, SUN Lanyi. Comparison of alternative configurations for separation of dimethyl carbonate-methanol mixture: steady state simulation and dynamic control[J]. Chemical Industry and Engineering Progress, 2017, 36(03): 852-862.

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碳酸二甲酯-甲醇共沸体系分离的模拟与控制

Comparison of alternative configurations for separation of dimethyl carbonate-methanol mixture: steady state simulation and dynamic control

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