双杆介质阻挡放电降解酸性红73废水

doi:10.16085/j.issn.1000-6613.2017-2630

化工进展 ›› 2018, Vol. 37 ›› Issue (09): 3640-3648.DOI: 10.16085/j.issn.1000-6613.2017-2630

双杆介质阻挡放电降解酸性红73废水

刘丹¹, 张连成¹, 黄逸凡², 朱安娜³, 刘振¹, 闫克平¹

1 浙江大学化学工程与生物工程学院, 浙江杭州 310028;
2 中国科学院深圳先进技术研究院生物医用材料与界面研究中心, 广东深圳 518055;
3 军事科学院防化研究院国民核生化灾害防护国家重点实验室, 北京 102205

收稿日期:2017-12-20 修回日期:2018-01-09 出版日期:2018-09-05 发布日期:2018-09-05
通讯作者: 刘振,副教授,研究方向为脉冲功率和等离子体应用。
作者简介:刘丹(1993-),女,硕士研究生,研究方向为等离子体水处理应用。
基金资助:
国家自然科学基金项目（51377145）。

Degradation of Brilliant Crocein wastewater by double-rod dielectric barrier discharge

LIU Dan¹, ZHANG Liancheng¹, HUANG Yifan², ZHU Anna³, LIU Zhen¹, YAN Keping¹

1 College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China;
2 Center for Ciomedical Materials and Interfaces, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, Guangdong, China;
3 Research Institute of Chemical Defense, Academy of Military Science PLA China, State Key Laboratory of NBC Protection for Civilian, Beijing 102205, China

Received:2017-12-20 Revised:2018-01-09 Online:2018-09-05 Published:2018-09-05

摘要/Abstract

摘要： 研究一种双杆式介质阻挡放电在不同条件下对酸性红73的降解效果，考察了能量密度、初始电导率、初始pH、初始质量浓度和放置时间等因素对染料降解率的影响，并对反应中生成的活性粒子（H₂O₂和O₃）进行了检测。降解实验前后的紫外-可见吸收光谱图表明介质阻挡放电能够破坏酸性红73分子中的偶氮双键和萘环等。实验结果表明：能量密度的增加可以提高酸性红73降解率，当能量密度为265.8kJ/L时，降解率为70.0%，能量效率最高可达2.84mg/（kW·h）。酸性红73的初始质量浓度的增加可以提高反应的能量效率。放电过程中产生的过氧化氢与处理时间呈正相关增长，并可持续存在一段时间进一步引起染料褪色，臭氧则随着时间的增长先增大后减小。

关键词: 介质阻挡放电, 低温等离子体, 废水, 酸性红73, 污染, 氧化

Abstract: A double-rod dielectric barrier discharge (DBD) was applied to degrade the Brilliant Crocein under different parameters, including energy density, initial conductivity, initial pH, and initial mass concentration and standing time. The active particles such as H₂O₂ and O₃ were detected as well. The UV-vis absorption spectra indicated the N=N and naphthalene ring of the Brilliant Crocein were destroyed. The degradation rate increased with the increase of energy density. The degradation rate reached 70.0% with the energy density of 265.8kJ/L, and the corresponding energy efficiency was up to 2.84mg/(kW·h). The energy efficiency improved when the initial mass concentration increased. The yield of hydrogen peroxide was higher with a longer discharge time, and the persistent effects on the degradation of Brilliant Crocein still existed after discharge. However, the ozone increased first and then decreased.

Key words: dielectric barrier discharge (DBD), plasma, waste water, Brilliant Crocein, pollution, oxidation

中图分类号:

刘丹, 张连成, 黄逸凡, 朱安娜, 刘振, 闫克平. 双杆介质阻挡放电降解酸性红73废水[J]. 化工进展, 2018, 37(09): 3640-3648.

LIU Dan, ZHANG Liancheng, HUANG Yifan, ZHU Anna, LIU Zhen, YAN Keping. Degradation of Brilliant Crocein wastewater by double-rod dielectric barrier discharge[J]. Chemical Industry and Engineering Progress, 2018, 37(09): 3640-3648.

参考文献

[1] ZHAO J, CHEN J, GAO J. Decolorization of azo dyes C.I. Acid Yellow 17 and C.I. Direct Red 31 by dielectric barrier discharge air plasma[J]. IEEE Transactions on Plasma Science, 2010, 38(3):488-495.
[2] 雪晶, 陈砺, 王红林, 等.介质阻挡放电等离子体对茜素红溶液的降解[J].化工学报, 2007, 58(10):2595-2600. XUE Jing, CHEN Li, WANG Honglin, et al. Degradation of alizarin red solution in DBD plasma[J]. Journal of Chemical Industry and Engineering(China), 2007, 58(10):2595-2600.
[3] NG I S, CHEN T, LIN R, et al. Decolorization of textile azo dye and Congo red by an isolated strain of the dissimilatory manganesereducing bacterium Shewanella xiamenensis BC01[J]. Applied Microbiology & Biotechnology, 2014, 98(5):2297-2308.
[4] 商克峰, 鲁娜, 李杰, 等.用气相沿面放电生成臭氧方式降解偶氮染料废水的影响因素分析[J]. 高电压技术, 2012, 38(7):1636-1641. SHANG Kefeng, LU Na, LI Jie, et al. Factor analysis of ozone generation by gas-phase surface discharge for degradation of azo dye wastewater[J]. High Voltage Engineering, 2012, 38(7):1636-1641.
[5] XU L, ZHANG L, DU L, et al. Electro-catalytic oxidation in treating C.I. Acid Red 73 wastewater coupled with nanofiltration and energy consumption analysis[J]. Journal of Membrane Science, 2014, 452(4):1-10.
[6] JORFI S, BARZEGAR G, AHMADI M, et al. Enhanced coagulation-photocatalytic treatment of Acid Red 73 dye and real textile wastewater using UVA/synthesized MgO nanoparticles[J]. Journal of Environmental Management, 2016, 177:111-118.
[7] 李萱萱. 高级氧化技术在处理染料废水中的应用[J]. 化工进展, 2012, 31(s2):219-222. LI Xuanxuan. Application of advanced oxidation in dye wastewater treatment[J]. Chemical Industry and Engineering Progress, 2012, 31(s2):219-222.
[8] THORNTON T D, LADUE D E Ⅲ, SAVAGE P E. Phenol oxidation in supercritical water:formation of dibenzofuran, dibenzo-p-dioxin, and related compounds[J]. Environmental Science & Technology, 1991, 25(8):1507-1510.
[9] LUCK F. Wet air oxidation:past, present and future[J]. Catalysis Today, 1999, 53(1):81-91.
[10] FU F, WANG Q, TANG B. Effective degradation of C.I. Acid Red 73 by advanced Fenton process[J]. Journal of Hazardous Materials, 2010, 174(1):17-22.
[11] CRITTENDEN J C, LIU J, HAND D W, et al. Photocatalytic oxidation of chlorinated hydrocarbons in water[J]. Water Research, 1997, 31(3):429-438.
[12] 李莹, 李柯, 陈杰瑢, 等.低温等离子体杀菌消毒技术的应用进展[J].化工进展, 2004, 23(7):718-722. LI Ying, LE Ke, CHEN Jierong, et al. Application of non-thermal plasma sterilization/disinfection technique[J]. Chemical Industry and Engineering Progress, 2004, 23(7):718-722.
[13] BERMEJO M D, COCERO M J. Supercritical water oxidation:a technical review[J]. AIChE Journal, 2010, 52(11):3933-3951.
[14] ZHU W, BIN Y, LI Z, et al. Application of catalytic wet air oxidation for the treatment of H-acid manufacturing process wastewater[J]. Water Research, 2002, 36(8):1947-1954.
[15] NEYENS E, BAEYENS J. A review of classic Fenton's peroxidation as an advanced oxidation technique[J]. Journal of Hazardous Materials, 2003, 98(1):33-50.
[16] VAMATHEVAN V, AMAL R, BEYDOUN D, et al. Photocatalytic oxidation of organics in water using pure and silver-modified titanium dioxide particles[J]. Journal of Photochemistry & Photobiology A:Chemistry, 2002, 148(1):233-245.
[17] 李红梅, 郑经堂, 张延宗. 高压脉冲放电等离子体技术处理有机废水进展[J].化工进展, 2009, 28(6):1047-1050. LI Hongmei, ZHENG Jingtang, ZHANG Yanzong. Development of high voltage pulse discharged plasma for organic wastewater treatment[J]. Chemical Industry and Engineering Progress, 2009, 28(6):1047-1050.
[18] HUANG F, CHEN L, WANG H, et al. Degradation of methyl orange by atmospheric DBD plasma:analysis of the degradation effects and degradation path[J]. Journal of Electrostatics, 2012, 70(1):43-47.
[19] 杨长河, 曹志荣, 丁堃, 等.介质阻挡放电等离子体处理酸性大红GR废水[J].水处理技术, 2012, 38(5):96-100. YANG Changhe, CAO Zhirong, DING Kun. et al. Degradation of acid scarlet GR wastewater by dielectric barrier discharge[J]. Technology of Water Treatment, 2012, 38(5):96-100.
[20] 陈银生, 张新胜, 袁渭康. 高压脉冲电晕放电等离子体降解废水中苯酚[J]. 环境科学学报, 2002, 22(5):566-569. CHEN Yinsheng, ZHANG Xinsheng, YUAN Weikang. A preliminary study of pulsed high-voltage corona discharge plasma for the degradation of phenol in aqueous solution[J]. High Voltage Engineering, 2002, 22(5):566-569.
[21] 李成榕, 王新新.大气压下的辉光放电[J].高电压技术, 2002, 28(s1):41-43. LI Shurong, WANG Xinxin. Atmospheric pressure glow discharge(APGD)[J]. High Voltage Engineering, 2002, 28(s1):41-43.
[22] 刘亚纳, 严建华, 李晓东, 等.滑动弧等离子体处理酸性橙Ⅱ废水[J].化工学报, 2008, 59(1):221-227. LIU Yana, YAN Jianhua, LI Xiaodong, et al. Degradation of Acid OrangeⅡsolution by gas-liquid gliding arc discharge[J]. Journal of Chemical Industry and Engineering(China), 2008, 59(1):221-227.
[23] ZHANG R B, LI G F, WU V. Degradation of indigo carmine using bipolar pulsed dielectric barrier discharge (DBD) in the water-air mixture[C]//Industry Applications Conference, 2004. Ias Meeting. Conference Record of the IEEE, 2004:808.
[24] BAROCH P, SAITO N, TAKAI O. Special type of plasma dielectric barrier discharge reactor for direct ozonization of water and degradation of organic pollution[J]. Journal of Physics D:Applied Physics, 2008, 41(8):085207.
[25] 卢志刚, 汤兵, 张姿, 等. PAFC的制备及其在酸性红73废水处理中的应用[J].工业水处理, 2014, 34(11):44-47. LU Zhigang, TANG Bing, ZHANG Zi, et al. Preparation of polymeric aluminum ferric chloride flocculants and its application to the treatment of wastewater containing Acid Red 73[J]. Industrial Water Treatment, 2014, 34(11):44-47.
[26] REDDY P M K, RAJU B R, KARUPPIAH J, et al. Degradation and mineralization of methylene blue by dielectric barrier discharge non-thermal plasma reactor[J]. Chemical Engineering Journal, 2013, 217(1):41-47.
[27] KENDALL K. Degradation of pharmaceutical compound pentoxifylline in water by non-thermal plasma treatment[J]. Water Research, 2010, 44(11):3445-3453.
[28] ZHANG R, ZHANG C, CHENG X, et al. Kinetics of decolorization of azo dye by bipolar pulsed barrier discharge in a three-phase discharge plasma reactor[J]. Journal of Hazardous Materials, 2007, 142(1/2):105.
[29] JORFI S, BARZEGAR G, AHMADI M, et al. Enhanced coagulationphotocatalytic treatment of Acid Red 73 dye and real textile wastewater using UVA/synthesized MgO nanoparticles[J]. Journal of Environmental Management, 2016, 177:111-118.
[30] TANG Q, JIANG W, YI Z, et al. Degradation of azo dye Acid Red 88 by gas phase dielectric barrier discharges[J]. Plasma Chemistry & Plasma Processing, 2009, 29(4):291-305.
[31] FU F, WANG Q, TANG B. Effective degradation of C.I. Acid Red 73 by advanced Fenton process[J]. Journal of Hazardous Materials, 2010, 174(1/3):17.
[32] 谷广娜, 孙怀林, 周秀中.硅硅键与苯环之间的相互作用:不对称取代1,2-二苯基二硅烷的紫外吸收性质[J].有机化学, 2014, 34(2):349-354. GU Guangna, SUN Huailin, ZHOU Xiuzhong. Interaction of silicon-silicon bonds and phenyl rings:UV absorption properties of unsymmetrically substituted 1,2-diphenyltetramethyldisilanes[J]. Chinese Journal of Organic Chemistry, 2014, 34(2):349-354.
[33] 吴峰, 华河林, 邓南圣.三种偶氮染料降解历程在紫外-可见光谱上的表现[J]. 环境化学, 2000, 19(4):348-351. WU Feng, HUA Helin, DENG Nansheng. Expression of degradation courses of three azo dyes by UV-vis spectrum[J]. Environmental Chemistry, 2000, 19(4):348-351.
[34] 付江涛.偶氮化合物的固相合成及紫外-可见光谱研究[D].南昌:南昌大学, 2011. FU Jiangtao. Study on synthesis of azo compounds by solid phase and UV-vis spectroscopy[D]. Nanchang:Nanchang University, 2011.
[35] CLEMENTS J S, SATO M, DAVIS R H. Preliminary investigation of prebreakdown phenomena and chemical reactions using a pulsed high-voltage discharge in water[J]. IEEE Trans. Ind. Appl., 1987, 23(2):224-235.
[36] GLAZE W H. Drinking-water treatment with ozone[J]. Environmental Science & Technology, 1987, 21(3):224.
[37] LOCKE B R, SHIH K Y. Review of the methods to form hydrogen peroxide in electrical discharge plasma with liquid water[J]. Plasma Sources Science & Technology, 2011, 20(3):034006.

双杆介质阻挡放电降解酸性红73废水

Degradation of Brilliant Crocein wastewater by double-rod dielectric barrier discharge

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	杨寒月, 孔令真, 陈家庆, 孙欢, 宋家恺, 王思诚, 孔标. 微气泡型下向流管式气液接触器脱碳性能[J]. 化工进展, 2023, 42(S1): 197-204.
[2]	杨建平. 降低HPPO装置反应系统原料消耗的PSE[J]. 化工进展, 2023, 42(S1): 21-32.
[3]	王福安. 300kt/a环氧丙烷工艺反应器降耗减排分析[J]. 化工进展, 2023, 42(S1): 213-218.
[4]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[5]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[6]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[7]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[8]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[9]	郑谦, 官修帅, 靳山彪, 张长明, 张小超. 铈锆固溶体Ce_0.25Zr_0.75O₂光热协同催化CO₂与甲醇合成DMC[J]. 化工进展, 2023, 42(S1): 319-327.
[10]	戴欢涛, 曹苓玉, 游新秀, 徐浩亮, 汪涛, 项玮, 张学杨. 木质素浸渍柚子皮生物炭吸附CO₂特性[J]. 化工进展, 2023, 42(S1): 356-363.
[11]	高雨飞, 鲁金凤. 非均相催化臭氧氧化作用机理研究进展[J]. 化工进展, 2023, 42(S1): 430-438.
[12]	王莹, 韩云平, 李琳, 李衍博, 李慧丽, 颜昌仁, 李彩侠. 城市污水厂病毒气溶胶逸散特征研究现状与未来展望[J]. 化工进展, 2023, 42(S1): 439-446.
[13]	许春树, 姚庆达, 梁永贤, 周华龙. 共价有机框架材料功能化策略及其对Hg(Ⅱ)和Cr(Ⅵ)的吸附性能研究进展[J]. 化工进展, 2023, 42(S1): 461-478.
[14]	顾永正, 张永生. HBr改性飞灰对Hg⁰的动态吸附及动力学模型[J]. 化工进展, 2023, 42(S1): 498-509.
[15]	赵景超, 谭明. 表面活性剂对电渗析减量化工业含盐废水的影响[J]. 化工进展, 2023, 42(S1): 529-535.