卤代丙烯烃命名规则及2,3,3,3-四氟丙烯的概况和氟化合成研究进展

doi:10.16085/j.issn.1000-6613.2017-0727

摘要/Abstract

摘要： 由于零臭氧层破坏潜值和较低的温室效应值，2，3，3，3-四氟丙烯作为1，1，1，2-四氟乙烷的替代物，被认为是理想、高效、环保和最具潜力的第四代新型制冷剂，并已受到汽车空调行业的广泛关注。首先，本文介绍了含卤素丙烯烃的命名规则、四氟丙烯的物化特性和制冷性能；其次，简述了铬基催化剂的制备方法，分析了以1，1，2，3-四氯丙烯为原料经2-氯-3，3，3-三氟丙烯中间体，气相催化氟化合成四氟丙烯的反应条件和反应路径等的研究进展；最后简要探讨了氟氯交换反应的机理。铬基催化剂作为气相氟氯交换反应的主体催化剂，所具有的某些特殊性能是其他许多催化剂难以比拟的，但是铬的化合物有毒，建议开发具有高活性和稳定性的无毒非铬基催化剂。

关键词: 2, 3, 3, 3-四氟丙烯, 化学反应, 温室气体, 催化, 1, 1, 2, 3-四氯丙烯, 2-氯-3, 3, 3-三氟丙烯

Abstract: 2,3,3,3-tetrafluoropropene (HFO-1234yf), as a promising replacement for 1,1,1,2-tetrafluoroethane (HFC-134a), is considered as a new generation refrigerant in automotive air condition system due to its zero ozone depletion potential (ODP) value, a low global warming potential (GWP) value of 4 and excellent refrigerating ability.So HFO-1234yf has been widely concerned in automotive air conditioning industry.To date, a large number of patents were applied for synthetic methods for HFO-1234yf.In those patents, one of the effective routes to synthesize HFC-1234yf is that 1,1,2,3-tetrachloropropene (HCFO1230xa) is fluorinated to synthesis HFC-1234yf via intermediate 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) in the presence of a fluorination Cr-based catalysts.The purpose of this review article is to provide readers with nomenclature rules of fluorinated propene isomers, physicochemical properties, refrigerant's performance of HFO-1234yf and reaction conditions as depicted in the patent and open literature.Emphasis has been placed on catalysts preparation and reaction pathways, which aim at studying Cl/F exchange reaction mechanism.Combining with the urgently need of ODS substitutes technology, preparation of catalytic materials with high catalytic activities and long life-time and non-cr-based catalysts will become research topic.

Key words: 2,3,3,3-tetrafluoropropene chemical reaction greenhouse gas catalysis, 1,1,2,3-tetrachloropropene 2-chloro-3,3,3-trifluoropropene

中图分类号:

贺晋伟, 张梦雪, 周晓猛. 卤代丙烯烃命名规则及2,3,3,3-四氟丙烯的概况和氟化合成研究进展[J]. 化工进展, 2017, 36(S1): 34-42.

HE Jinwei, ZHANG Mengxue, ZHOU Xiaomeng. Advances on the gas-phase catalytic fluorination of 1,1,2,3-tetrachloropropene to 2,3,3,3-tetrafluoropropene[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 34-42.

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