高性能NaA沸石膜的制备及其脱盐性能

doi:10.16085/j.issn.1000-6613.2017-0577

化工进展 ›› 2017, Vol. 36 ›› Issue (11): 4170-4175.DOI: 10.16085/j.issn.1000-6613.2017-0577

高性能NaA沸石膜的制备及其脱盐性能

邢庆达¹, 周亮¹, 李华征¹, 王金渠^1,2, 张文君¹

1. 大连理工大学盘锦校区石油与化学工程学院, 辽宁盘锦 124221;
2. 大连理工大学精细化工国家重点实验室吸附与无机膜研究所, 辽宁大连 116024

收稿日期:2017-04-05 修回日期:2017-05-03 出版日期:2017-11-05 发布日期:2017-11-05
通讯作者: 王金渠,教授,研究方向为沸石分子筛膜的制备。
作者简介:邢庆达(1990-),男,硕士研究生。
基金资助:
国家高新技术研究发展计划项目（2015AA03A602）。

Preparation and desalination performance of high quality NaA zeolite membrane

XING Qingda¹, ZHOU Liang¹, LI Huazheng¹, WANG Jinqu^1,2, ZHANG Wenjun¹

1. School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin Campus, Panjin 124221, Liaoning, China;
2. Institute of Adsorption and Inorganic Membrane, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2017-04-05 Revised:2017-05-03 Online:2017-11-05 Published:2017-11-05

摘要/Abstract

摘要： 以廉价大孔α-Al₂O₃管为载体，通过两步变温热浸渍涂晶法，修饰载体表面缺陷，得到连续而均匀的晶种层。在微波辅助作用下，短时间内有效诱导制备出超薄NaA分子筛膜。将其用于渗透汽化脱盐体系中，研究发现，微波加热法制备的超薄NaA沸石膜水通量明显高于常规加热法制备的较厚NaA沸石膜，水的渗透通量随着盐浓度的增大在小范围内有所降低，而操作温度的升高对水的渗透具有明显促进作用，当原料液浓度为0.6mol/L、操作温度85℃时，水通量达到11.03kg/（m²·h）。同时，离子截留率不受操作温度及原料液浓度的影响，始终保持>99.9%。此外，NaA沸石膜在渗透蒸发脱盐中表现出较高的稳定性，75℃条件下，在0.6mol/L的NaCl溶液中性能可稳定72h以上。该方法在降低制膜成本的同时有效提高了水的渗透通量及离子截留率，表明NaA沸石膜在膜法脱盐的工业化应用领域具有较好的应用前景。

关键词: 大孔&alpha, -Al₂O₃载体, NaA沸石膜, 渗透蒸发, 脱盐, 微波加热

Abstract: A continuous and uniform seed layer was obtained by modifying the surface defects of the low-cost macroporous α-Al₂O₃ tube support by the two-step hot-dip coating method. The ultra-thin NaA zeolite membranes were prepared by microwave-assisted synthesis in a short time,and they were used for pervaporative desalination. It is found that the permeation flux of water decreased slightly with the increase of salt concentration and the increase of operating temperature had a significant effect on the water flux. When the salt concentration of feed was 0.6mol/L and the operating temperature was 85℃,the water flux reached 11.03kg/(m²·h). But the ion retention rate was not affected by the operating temperature and the concentration of the feed solution,and remained at more than 99.9%. In addition,NaA zeolite membrane showed high stability in the pervaporative desalination,and the performance was stable for more than 72h in the 0.6mol/L NaCl solution at 75℃. The method can effectively improve water flux and ions rejection while reducing the cost of membrane preparation,which indicates that NaA zeolite membrane has a good application prospect in the field of membrane desalination.

Key words: macroporous α-Al₂O₃ alumina, NaA zeolite membrane, pervaporation, desalination, microwave heating

中图分类号:

TQ174

邢庆达, 周亮, 李华征, 王金渠, 张文君. 高性能NaA沸石膜的制备及其脱盐性能[J]. 化工进展, 2017, 36(11): 4170-4175.

XING Qingda, ZHOU Liang, LI Huazheng, WANG Jinqu, ZHANG Wenjun. Preparation and desalination performance of high quality NaA zeolite membrane[J]. Chemical Industry and Engineering Progress, 2017, 36(11): 4170-4175.

参考文献

[1] BORSANI R,REBAGLIATI S. Fundamentals and costing of MSF desalination plants and comparison with other technologies[J]. Desalination, 2005,182(1/2/3):29-37.
[2] ZHANG F,XU S,FENG D,et al. A low-temperature multi-effect desalination system powered by the cooling water of a diesel engine[J]. Desalination,2017,404:112-120.
[3] LEE K P,ARNOT T C,MATTIA D. A review of reverse osmosis membrane materials for desalination——development to date and future potential[J]. Journal of Membrane Science,2011,370(1):1-22.
[4] LI D,WANG H. Recent developments in reverse osmosis desalination membranes[J]. Journal of Materials Chemistry,2010,20(22):4551-4566.
[5] 孙永超,解利昕,高婷婷,等. 反渗透海水淡化预处理工艺[J]. 化工进展,2016,35(11):3658-3662. SUN Yongchao,XIE Lixin,GAO Tingting,ZHOU Xiaokai,et al. A study on different pretreatments process in sea water reverse osmosis(SWRO)desalination[J]. Chemical Industry and Engineering Progress,2016,35(11):3658-3662.
[6] 姜宝鑫,杨庆峰. 反渗透膜生物污染的研究进展[J]. 化工进展,2010,29(8):1554-1561. JIANG Baoxin,YANG Qingfeng. Research advances in biofouling of reverse osmosis membrane[J]. Chemical Industry and Engineering Progress, 2010,29(8):1554-1561.
[7] 陈家岭. 我国反渗透膜材料研究现状[J]. 净水技术,2011,30(3):34-37. CHEN Jialing. A survey of materials research of reverse osmosis(RO)membrane at home[J]. Water Purification Technology,2011,30(3):34-37.
[8] 李永生,王金渠,郭树才. 沸石膜的合成最新进展[J]. 化工进展,2001,20(2):42-47. LI Yongsheng,WANG Jinqu,GUO Shucai. Recent progress of preparation of zeolite membranes[J]. Chemical Industry and Engineering Progress,2001, 20(2):42-47.
[9] 胡子益,李洪波,谭宇鑫,等. 微波合成的NaA型分子筛膜在乙醇脱水中试及3万吨/年工业示范装置的蒸汽渗透性能研究[J]. 化工进展,2016,35(s1):438-442. HU Ziyi,LI Hongbo,TAN Yuxin,et al. Microwave synthesis type NaA zeolite membrane for ethanol dehydration on vaper permeation study of experimental facility and 30000 tons per year industrial demonstration unit[J]. Chemical Industry and Engineering Progress,2016,35(s1):438-442.
[10] 朱美华,夏水莲,刘永生,等. 二次水热合成法制备ZSM-5分子筛膜及其渗透汽化性能[J]. 化工进展,2016,35(9):2885-2891. ZHU Meihua,XIA Shuilian,LIU Yongsheng,et al. Secondary hydrothermal synthesis of ZSM-5 zeolite membrane and its pervaporation performance[J]. Chemical Industry and Engineering Progress,2016,35(9):2885-2891.
[11] LIU Y,WANG X,ZHANG Y,et al. Scale-up of NaA zeolite membranes on α-Al₂O₃ hollow fibers by a secondary growth method with vacuum seeding[J]. Chinese Journal of Chemical Engineering,2015,23(7):1114-1122.
[12] WANG Q,LI N,BOLTO B,et al. Desalination by pervaporation:a review[J]. Desalination,2016,387:46-60.
[13] DROBEK M,YACOU C,MOTUZAS J,et al. Long term pervaporation desalination of tubular MFI zeolite membranes[J]. Journal of Membrane Science,2012,415:816-823.
[14] KHAJAVI S,JANSEN J C,KAPTEIJN F. Production of ultra pure water by desalination of seawater using a hydroxy sodalite membrane[J]. Journal of Membrane Science,2010,356(1):52-57.
[15] VOLKOV A G,PAULA S,DEAMER D W. Two mechanisms of permeation of small neutral molecules and hydrated ions across phospholipid bilayers[J]. Bioelectrochemistry and Bioenergetics,1997,42(2):153-160.
[16] CHO C H,OH K Y,KIM S K,et al. Pervaporative seawater desalination using NaA zeolite membrane:mechanisms of high water flux and high salt rejection[J]. Journal of Membrane Science,2011,371(1):226-238.
[17] HE Y,CUI X,LIU X,et al. Preparation of self-supporting NaA zeolite membranes using geopolymers[J]. Journal of Membrane Science,2013,447:66-72.
[18] ZHOU C,ZHOU J,HUANG A. Seeding-free synthesis of zeolite FAU membrane for seawater desalination by pervaporation[J]. Microporous and Mesoporous Materials,2016,234:377-383.
[19] LI Y,CHEN H,LIU J,et al. Microwave synthesis of LTA zeolite membranes without seeding[J]. Journal of Membrane Science,2006, 277(1):230-239.
[20] ZHU B,HONG Z,MILNE N,et al. Desalination of seawater ion complexes by MFI-type zeolite membranes:temperature and long term stability[J]. Journal of Membrane Science,2014,453:126-135.

高性能NaA沸石膜的制备及其脱盐性能

Preparation and desalination performance of high quality NaA zeolite membrane

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透（RO）膜[J]. 化工进展, 2023, 42(S1): 364-373.
[2]	赵尧, 周志辉, 吴红丹, 胡传智, 张国春, 吴睿鹏. Silicalite-1分子筛膜渗透蒸发条件的响应面分析与优化[J]. 化工进展, 2023, 42(5): 2586-2594.
[3]	宗悦, 张瑞君, 高珊珊, 田家宇. “特殊稳定型”压力驱动薄膜复合（TFC）脱盐膜的研究进展[J]. 化工进展, 2023, 42(4): 2058-2067.
[4]	陈仪, 郭耀励, 叶海星, 李宇璇, 牛青山. 二维纳米材料在渗透汽化脱盐膜中的应用[J]. 化工进展, 2023, 42(3): 1437-1447.
[5]	张赫, 李小可, 熊颖, 文劲. 基于水凝胶界面光蒸发的压裂返排液脱盐降污处理[J]. 化工进展, 2023, 42(2): 1073-1079.
[6]	张国春, 周志辉, 吴红丹. 基于α-Al₂O₃载体管的新型MXene膜异丙醇脱水性能[J]. 化工进展, 2023, 42(10): 5381-5389.
[7]	孙孟威, 刘壮, 谢锐, 巨晓洁, 汪伟, 褚良银. 镧离子插层MoS₂膜的制备及印染高盐水处理[J]. 化工进展, 2023, 42(1): 346-353.
[8]	张华, 刘光全, 张晓飞, 罗臻. 电脱盐废水稳定性分析及破乳技术[J]. 化工进展, 2022, 41(9): 5047-5054.
[9]	洪波. 取消药剂消耗的电脱盐污水物理法预处理[J]. 化工进展, 2022, 41(5): 2788-2796.
[10]	石一慈, 潘艳秋, 王成宇, 范嘉禾, 俞路. 焦耳效应强化气隙式膜蒸馏脱盐过程的实验研究[J]. 化工进展, 2022, 41(5): 2285-2291.
[11]	张群, 陈重军, 谢嘉玮, 邹馨怡. 高盐废水微生物脱盐池处理研究进展[J]. 化工进展, 2022, 41(2): 974-980.
[12]	孙汇莲, 孙灵杰, 赵杨, 孙翔, 张伦祥. 水合物法处理实际复杂废水及高盐废水[J]. 化工进展, 2022, 41(12): 6672-6679.
[13]	白永珍, 尚小标, 刘美红, 魏聪, 张富程, 肖利平, 李广超, 陈君若. 微波加热用透波材料的研究进展[J]. 化工进展, 2022, 41(1): 253-263.
[14]	李赛赛, 詹硕, 李继定, 何静, 王璐莹. 木质素磺酸钙/海藻酸钠渗透汽化膜的制备及性能调控[J]. 化工进展, 2021, 40(S1): 311-318.
[15]	谢松辰, 文剑平, 庞志广, 侯春光, 李志霞, 晋墩尚, 彭跃莲. 膜蒸馏脱盐中膜污染与膜润湿的研究进展[J]. 化工进展, 2021, 40(7): 3942-3956.