多孔材料负载型水处理剂对金属离子废水的应用研究进展

doi:10.16085/j.issn.1000-6613.2016.07.036

摘要/Abstract

摘要： 多孔材料负载型水处理剂是以多孔材料为载体而制备的一种高效环保的新型复合材料,具有高比表面积、高效率、易回收等优点,能够广泛应用于去除金属离子废水。本文扼要介绍了近年来国内外关于多孔材料负载型水处理剂的新型制备方法,介绍了超临界技术、微乳液技术、微波技术、溶胶-凝胶技术等制备方法的研究进展,以及各制备方法的特点;同时分析介绍了负载型水处理剂对有色金属离子、稀土离子、贵金属离子废水的应用新进展。特别提出今后该类水处理剂在去除金属离子废水方面的发展方向为:进一步提高水处理剂的活性、吸附性和光催化性协同作用;选择含有功能基团的材料为载体,与金属离子络合作用;制备磁性负载型水处理剂,便于后期回收利用;开发环境友好和可循环使用的水处理剂,提高使用寿命,不造成二次污染。

关键词: 载体, 复合材料, 活性, 水处理剂, 金属离子, 应用

Abstract: Porous material supported water treatment agent is an effective and environmental friendly composite material. It can be widely used to remove metal ions from wastewater. It has advantages of high specific surface area, high efficiency and easy recovery. This paper describes an overview of recent domestic and foreign new methods of porous material supported water treatment agent. Research progresses on preparation of supercritical technology, micro-emulsion technology, microwave technology and sol-gel technology, as well as the preparation method features were introduced. Meanwhile, the application of supported water treatment agent for non-ferrous metal ions, rare earth ions and noble metal ions was reviewed. The direction of development of waste water treatment agent to remove metal ions was specially proposed. More work needs to be done in improving reactivity of waste water treatment agent, adsorption and photocatalytic synergies. Materials containing functional groups as the support should be selected with the metal ions action. Magnetic load water treatment agent should be prepared to facilitate post-recycling. Environmental friendly and recyclable water treatment agent should be developed to improve life and avoid secondary pollution.

Key words: support, composites, reactivity, water treatment agent, metal ion, application

中图分类号:

X703

祝婷, 罗序燕, 邓金梅, 黄瑞宇, 谢小华. 多孔材料负载型水处理剂对金属离子废水的应用研究进展[J]. 化工进展, 2016, 35(07): 2186-2194.

ZHU Ting, LUO Xuyan, DENG Jinmei, HUANG Ruiyu, XIE Xiaohua. Research progress on application of metal ions wastewater with water treatment agent supported on porous materials[J]. Chemical Industry and Engineering Progree, 2016, 35(07): 2186-2194.

参考文献

[1] GUPTA V K,JAIN R,NAYAK A,et al. Removal of the hazardous dye-tartrazine by photodegradation on titanium dioxide surface[J]. Materials Science & Engineering C,2011,31(5):1062-1067.
[2] KHANI H,ROFOUEI M K,ARAB P,et al. Multi-walled carbon nanotubes-ionic liquid-carbon paste electrode as a super selectivity sensor:application to potentiometric monitoring of mercury ion(II)[J]. Journal of Hazardous Materials,2010,183(1/2/3):402-409.
[3] GUPTA V K,ALI I,SALEH T A,et al. Chemical treatment technologies for waste-water recycling. lb. An overview[J]. Rsc. Advances,2012,2(16):6380-6388.
[4] SHARMA S,KOTHIYAL N C,RATHORE B S,et al. Use of cellulose acetate-tin (Ⅳ) phosphate composite (CA/TPC) in highly effective removal and recovery of heavy metal ions[J]. International Journal of Industrial Chemistry,2015,6(1):43-58.
[5] ANIRUDHAN T S,JALAJAMONY S,SREEKUMARI S S. Adsorptive removal of Cu(Ⅱ) ions from aqueous media onto 4-ethyl thiosemicarbazide intercalated organophilic calcined hydrotalcite[J]. J. Chem. Eng. Data,2012,58(1):24-31.
[6] HAKIMELAHI M,MOGHADDAM M R A,HASHEMI S H. Biological treatment of wastewater containing an azo dye using mixed culture in alternating anaerobic/aerobic sequencing batch reactors[J]. Biotechnology & Bioprocess Engineering,2012,17(4):875-880.
[7] SALISBURY C,CRONIN D,LIEN F S. Deformation mechanics of a non-linear hyper-viscoelastic porous material,PartⅡ:porous material micro-scale model[J]. Journal of Dynamic Behavior of Materials,2015,1(3):249-258.
[8] HALDAR Ritesh,SIKDAR Nivedita,KUMAR MAJI Tapas. Interpenetration in coordination polymers: structural diversities toward porous functional materials[J]. Materials Today,2015,18(2):97-116.
[9] SUGIYAMA H,WATANABE S,TANAKA H,et al. Adsorption-induced structural transition of an interpenetrated porous coordination polymer: detailed exploration of free energy profiles[J]. Langmuir the Acs Journal of Surfaces & Colloids,2012,28(11):5093-5100.
[10] HIROYASU F,NAKEUN K,BOK G Y,et al. Ultrahigh porosity in metal-organic frameworks[J]. Science,2010,329(5990):424-428.
[11] 徐小妹,潘顺龙,李健生,等.多孔载体负载型Fenton催化剂降解酚类污染物的研究进展[J]. 化工进展,2014,33(6):1465-1474.
[12] FU J W,WANG M H,WANG S T,et al. Supercritical carbon dioxide-assisted preparation of palladium nanoparticles on cyclotriphosphazene-containing polymer nanospheres[J]. Applied Surface Science,2011,257(16):7129-7133.
[13] MORÈRE J,TENORIO M J,TORRALVO M J,et al. Deposition of Pd into mesoporous silica SBA-15 using supercritical carbon dioxide[J]. The Journal of Supercritical Fluids,2011,56(2):213-222.
[14] 张以敏,姜浩锡. 超临界流体沉积技术制备负载型金属催化剂的研究进展[J]. 化工进展,2013,32(8):1825-1831.
[15] AHMADI S J,AKBARI N,SHIRI-YEKTA Z,et al. Removal of strontium ions from nuclear waste using synthesized MnO₂-ZrO₂ nano-composite by hydrothermal method in supercritical condition[J]. Korean Journal of Chemical Engineering,2015,32(3):478-485.
[16] SU F H,HUANG H X. Supercritical carbon dioxide-assisted reactive extrusion for preparation long-chain branching polypropylene and its rheology[J]. The Journal of Supercritical Fluids,2011,56(1):114-120.
[17] LI D C,TAO L,LING Z,et al. Foaming of linear isotactic polypropylene based on its non-isothermal crystallization behaviors under compressed CO₂[J]. The Journal of Supercritical Fluids,2011,60(12):89-97.
[18] ZHANG Y Z,LIAO X M,YIN G F,et al. Preparation of water soluble drugs-loaded microparticles using modified solution enhanced dispersion by supercritical CO₂[J]. Powder Technology,2012,221(5):343-350.
[19] JIN H Y,LI S N,HU D D,et al. Preparation of PLA-PEG nanoparticles by the solution enhanced dispersion with enhanced mass transfer using ultrasound in supercritical CO₂[J]. Powder Technology,2012,227(9):17-23.
[20] JR F R S M,REIS D F,BOSCHETTO D L,et al. Encapsulation of astaxanthin from Haematococcus pluvialis in PHBV by means of SEDS technique using supercritical CO₂[J]. Industrial Crops & Products,2014,54(2):17-21.
[21] HASHIM N,YUSOH K. Supercritical carbon dioxide-assisted process in synthesis of polymer/clay melt[J]. Macromolecular Research,2015,23(5):1-15.
[22] 陈仕祥,刘红,王翠,等. 微乳液法制备纳米SiO₂/TiO₂及其光催化性能[J]. 化工进展,2012,31(5):1052-1056.
[23] LI Y,GAO L,CHEN W,et al. Preparation and characterization of Ag₂S/PMMA nanocomposites by microemulsion[J]. Acta Metallurgica Sinica,2014,1(1):175-179.
[24] BHARDWAJ P,SINGH V,MANDAL U K,et al. Polyacrylamide and poly(acrylamide-co-2-acrylamido-2-methyl-1-propanesulfonic acid)-silica composite nanogels through in situ microemulsion polymerisation[J]. Journal of Materials Science,2010,45(4):1008-1016.
[25] DING L N,ZHENG M Y,WANG A Q,et al. A novel route to the preparation of carbon supported nickel phosphide catalysts by a microwave heating process[J]. Catalysis Letters,2010,135(3/4):305-311.
[26] HERRING N P,KHALED A Z,MOHAMED M B,et al. Formation mechanisms of gold-zinc oxide hexagonal nanopyramids by heterogeneous nucleation using microwave synthesis.[J]. Langmuir,2011,27(24):15146-15154.
[27] SIAMAKI A R,KHDER A E R S,EL-SHALL M S,et al. Microwave-assisted synthesis of palladium nanoparticles supported on graphene:a highly active and recyclable catalyst for carbon-carbon cross-coupling reactions[J]. Journal of Catalysis,2011,279(1):1-11.
[28] HERRING N P,ALMAHOUDI S H,OLSON C R,et al. Enhanced photocatalytic activity of ZnO-graphene nanocomposites prepared by microwave synthesis[J]. Journal of Nanoparticle Research,2012,14(12):1-13.
[29] WU D,HUO P W,LU Z Y,et al. Preparation of heteropolyacid/TiO₂/fly-ash-cenosphere photocatalyst for the degradation of ciprofloxacin from aqueous solutions[J]. Applied Surface Science,2012,258(18):7008-7015.
[30] 马航,冯霄. 固体催化剂常规制备方法的研究进展[J]. 现代化工,2013,33(10):32-36.
[31] 金云舟,钱君律,伍艳辉. 溶胶-凝胶法制备催化剂的研究进展[J]. 工业催化,2006,14(11):60-63.
[32] 姚楠,熊国兴,张玉红,等. 溶胶凝胶法制备中孔分布集中的氧化物及混合氧化物催化材料[J]. 中国科学(B辑),2001,31(4):355-363.
[33] 张凌峰,胡忠攀,高泽敏,等. 有序介孔碳基金属复合材料的制备及催化应用[J]. 化学进展,2015(8):1-15
[34] 郝星宇,赵丹,庞先勇,等. 离子交换法制备介孔TiO₂/CdS纳米复合光催化剂及性能研究[J]. 宁波大学学报:理工版,2013(4):49-55.
[35] 汪颖军,张莹莹,吴红姣,等. TiO₂-SiO₂复合氧化物的制备及其催化性能的研究进展[J]. 石油化工,2011,39(12):1402-1408.
[36] 毛丽婷,朱丽虹,汪洋. 水热法制备TiO₂/木材复合材料及其防潮阻燃性能[J]. 浙江理工大学学报,2015,33(5):643-648.
[37] İLKNUR Durukan,ÇIĞDEM Arpa ŞAHIN,BEKTAŞ S. Determination of copper traces in water samples by flow injection-flame atomic absorption spectrometry using a novel solidified floating organic drop microextraction method[J]. Microchemical Journal,2011,98(2):215-219.
[38] ÇIĞDEM Arpa ŞAHIN,İLKNUR Tokgöz. A novel solidified floating organic drop microextraction method for preconcentration and determination of copper ions by flow injection flame atomic absorption spectrometry.[J]. Analytica Chimica Acta,2010,667(1/2):83-87.
[39] VISA M,ANDRONIC L,DUTA A. Fly ash-TiO₂ nanocomposite material for multi-pollutants wastewater treatment.[J]. Journal of Environmental Management,2015,150:336-343.
[40] SINGHON Rattiya,HUSSON Jérôme,KNORR Michael,et al. Preparation of silica-supported biosorbents for copper(Ⅱ) removal[J]. Journal of Dispersion Science & Technology,2011,32(12):1735-1741.
[41] LI L Z,WANG Z,MA P M,et al. Preparation of polyvinyl alcohol/chitosan hydrogel compounded with graphene oxide to enhance the adsorption properties for Cu(Ⅱ) in aqueous solution[J]. Journal of Polymer Research,2015,22:1-10.
[42] YALÇIN S,APAK R,İSMAIL Boz. Enhanced copper(Ⅱ) biosorption on SiO₂-alginate gel composite:a mechanistic study with surface characterization[J]. Korean Journal of Chemical Engineering,2015:1-8.
[43] ZHANG Y J,CHI H J,ZHANG W H,et al. Highly efficient adsorption of copper ions by a pvp-reduced graphene oxide based on a new adsorptions mechanism[J]. Nano-Micro Letters,2014,6(1):80-87.
[44] ZHANG S,ZHOU Y F,NIE W Y,et al. Preparation of Fe₃O₄/chitosan/poly(acrylic acid) composite particles and its application in adsorbing copper ion(Ⅱ)[J]. Cellulose,2012,19(6):2081-2091.
[45] ZHAN Y H,LIN J W,LI J. Preparation and characterization of surfactant-modified hydroxyapatite/zeolite composite and its adsorption behavior toward humic acid and copper(Ⅱ)[J]. Environmental Science & Pollution Research,2013,20(4):2512-2526.
[46] DASCĂLU D,PITULICE L,IONEL R,et al. The usage of a zeolitic composite for quality improvement of copper contaminated mining wastewaters[J]. International Journal of Environmental Science and Technology,2014,12:1-14.
[47] Lu Ming,LIU Yunguo,HU Xin jiang,et al. Competitive adsorption of Cu(Ⅱ) and Pb(Ⅱ) ions from aqueous solutions by Ca-alginate immobilized activated carbon and Saccharomyces cerevisiae[J]. Journal of Central South University,2013,20(9):2478-2488.
[48] BARATI A,ASGARI M,MIRI T,et al. Removal and recovery of copper and nickel ions from aqueous solution by poly (methacrylamide-co-acrylic acid)/montmorillonite nanocomposites[J]. Environmental Science & Pollution Research International,2013,20
(9):6242-6255.
[49] QI G,ZHANG W G,DAI Y. Synthesis of magnetic expanded graphite and its application to remove Cr(Ⅵ) from wastewater[J]. Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry,2014,44(1):153-160.
[50] BUDNYAK T M,PYLYPCHUK I V,TERTYKH V A,et al. Synthesis and adsorption properties of chitosan-silica nanocomposite prepared by sol-gel method[J]. Nanoscale Research Letters,2015,10(1):1-10.
[51] 曾淦宁,武晓,郑林,等. 负载纳米零价铁铜藻基活性炭的制备及其去除水中Cr(Ⅵ) 的研究[J]. 环境科学,2015,36(2):530-536.
[52] SHI L N,ZHANG X,CHEN Z L. Removal of chromium (Ⅵ) from wastewater using bentonite-supported nanoscale zero-valent iron[J]. Water Research,2011,45(2):886-892.
[53] LIU Q,YANG B C,ZHANG L J,et al. Adsorptive removal of Cr(Ⅵ) from aqueous solutions by cross-linked chitosan/bentonite composite[J]. Korean Journal of Chemical Engineering,2015,32(7):1-9.
[54] WANG J H,YIN X L,TANG W,et al. Combined adsorption and reduction of Cr(Ⅵ) from aqueous solution on polyaniline/multiwalled carbon nanotubes composite[J]. Korean Journal of Chemical Engineering,2015,32(7):1889-1895.
[55] WANG F F,Ge M Q. Organic-inorganic hybrid of chitosan/ poly (vinyl alcohol) containing yttrium(Ⅲ) membrane for the removal of Cr(Ⅵ)[J]. Fibers & Polymers,2013,14(1):28-35.
[56] PARLAYICI S,ESKIZEYBEK V,AVCI A,et al. Removal of chromium (Ⅵ) using activated carbon-supported-functionalized carbon nanotubes[J]. Journal of Nanostructure in Chemistry,2015,5(3):255-263.
[57] FELLENZ N,MARTIN P,MARCHETTI S,et al. Aminopropyl-modified mesoporous silica nanospheres for the adsorption of Cr(Ⅵ) from water[J]. Journal of Porous Materials,2015,22(3):729-738.
[58] 杨佳静,王冠,管振杰,等. 凹凸棒石黏土负载纳米TiO₂的制备表征及对Ni(Ⅱ)吸附研究[J]. 化工新型材料,2014,42(7):166-168.
[59] 吕未然,姜文君.二氧化钛光催化技术在污水处理中的应用[J]. 科技经纬,2014,26(3):52-53.
[60] 刘德汞,钟黎,杨自成,等.壳聚糖交联酸改性粉煤灰的制备及对Mn²⁺的吸附性能研究[J].信阳师范学院学报,2014,27(3):379-383.
[61] HASHEMIAN S,SAFFARI H,RAGABION S. Adsorption of Cobalt(Ⅱ) from aqueous solutions by Fe₃O₄/bentonite nanocomposite[J]. Water Air & Soil Pollution,2015,226(1):1-10.
[62] TONG S S,ZHAO S J,ZHOU W H,et al. Modification of multi-walled carbon nanotubes with tannic acid for the adsorption of La,Tb and Lu ions[J]. Microchimica Acta,2011,174(3/4):257-264.
[63] 徐旸,张永奇,黄小卫,等. 螯合吸附材料ASA-PGMA/SiO₂对稀土离子的吸附性能研究[J]. 中国稀土学报,2012,30(5):538-544.
[64] GALHOUM A A,MAHFOUZ M G,ABDEL-REHEM S T,et al. Diethylenetriamine-functionalized chitosan magnetic nano-based particles for the sorption of rare earth metal ions [Nd(Ⅲ),Dy(Ⅲ) and Yb(Ⅲ)][J]. Cellulose,2015,22(4):2589-2605.
[65] EL-MENSHAWY A M,KENAWY I M,EL-ASMY A A. Modification of chloromethylated polystyrene with 2-mercabtobenzothiazole for application as a new sorbent for preconcentration and determination of Ag+ from different matrices.[J]. Journal of Hazardous Materials,2010,173(1/2/3):523-527.
[66] TAHMASEBI E,YAMINI Y. Polythiophene-coated Fe₃O₄ nanoparticles as a selective adsorbent for magnetic solid-phase extraction of silver(Ⅰ),gold(Ⅲ),copper(Ⅱ) and palladium(Ⅱ)[J]. Microchimica Acta,2014,181:543-551.
[67] 屈文,苏继新,曹丛华,等. 巯基键合硅胶的制备及其对贵金属离子的吸附性能[J]. 贵金属,2010,31(2):14-18.
[68] 何丽红,林婷婷,凌艺辉,等. 聚苯胺-木质素纳米复合物的制备及对银离子的吸附还原性能[J]. 高分子学报,2013,3(3):320-
326.