气体水合物相变热研究进展

doi:10.16085/j.issn.1000-6613.2016.07.013

化工进展 ›› 2016, Vol. 35 ›› Issue (07): 2021-2032.DOI: 10.16085/j.issn.1000-6613.2016.07.013

气体水合物相变热研究进展

胡亚飞^1,2, 蔡晶¹, 徐纯刚¹, 李小森¹

1. 中国科学院广州能源研究所, 中国科学院天然气水合物重点实验室, 广东省新能源和可再生能源研究开发与应用重点实验室, 广东广州 510640;
2. 中国科学院大学, 北京 100049

收稿日期:2015-08-26 修回日期:2016-03-10 出版日期:2016-07-05 发布日期:2016-07-05
通讯作者: 李小森,博士,研究员,博士生导师,主要从事天然气水合物方面的研究。E-mail:lixs@ms.giec.ac.cn。
作者简介:胡亚飞(1989-),男,硕士研究生,主要从事气体水合物相变热应用方面的研究。
基金资助:
国家杰出青年科学基金(51225603)、国际合作项目(2015DFA61790)、国家自然科学基金(5137618)及中石油-中科院高端战略联盟计划(2015A-4813-2)项目。

Research progress on phase change heat of gas hydrates

HU Yafei^1,2, CAI Jing¹, XU Chungang¹, LI Xiaosen¹

1. Guangdong Key Laboratory of New and Renewable Energy Research and Development, Key Laboratory of Gas Hydrate, CAS, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China

Received:2015-08-26 Revised:2016-03-10 Online:2016-07-05 Published:2016-07-05

摘要/Abstract

摘要： 气体水合物作为一种特殊的相变材料,在形成与分解过程中会发生相态改变并伴随着相变热的变化。本文从气体水合物相变热的测定和应用两个方面对气体水合物相变热的研究现状进行了综述。对比分析了两种确定气体水合物相变热的方法,两种方法分别为差示扫描量热仪(DSC)实验直接测定法和基于相平衡的Clausius-Clapeyron方程间接计算法。综述了气体水合物相变热的应用研究现状,尤其是在空调蓄冷技术中的应用,其中气体水合物空调蓄冷技术从蓄冷工质和蓄冷装置两个方面进行了阐述。指出了气体水合物相变热应用研究中的重点和难点,为气体水合物相变热应用的进一步发展提供参考。

关键词: 水合物, 相变热, 测量, 蓄冷, 优化

Abstract: Gas hydrates can be employed as a special phase-change material, as they have variable phase change heat changes during their formation or dissociation. This article summarizes the researches of phase change heat of gas hydrates from their measurements and applications. The direct and indirect methods of determining the phase change heat of gas hydrates are compared and analyzed in this work. The direct method is accomplished by using differential scanning calorimetry (DSC) while the indirect calculation method is achieved by Clausius-Clapeyron equation on basis of hydrate phase equilibrium data. The applications of phase change heat of gas hydrates are summarized comprehensively. Especially, the gas hydrates as the cold storage media in air condition systems are introduced in detail. The cold storage based on gas hydrates are discussed from cold storage media and cold storage devices. The key points and difficulties on the applications of phase change heat of gas hydrates are also pointed out. This paper is prone to provide a guide for the further utilization of phase change heat of gas hydrates.

Key words: hydrate, phase change heat, measurement, cold storage, optimization

中图分类号:

TQ026

胡亚飞, 蔡晶, 徐纯刚, 李小森. 气体水合物相变热研究进展[J]. 化工进展, 2016, 35(07): 2021-2032.

HU Yafei, CAI Jing, XU Chungang, LI Xiaosen. Research progress on phase change heat of gas hydrates [J]. Chemical Industry and Engineering Progree, 2016, 35(07): 2021-2032.

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气体水合物相变热研究进展

Research progress on phase change heat of gas hydrates

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