锂离子电池电解液负极成膜添加剂的研究进展

doi:10.16085/j.issn.1000-6613.2016.05.031

化工进展 ›› 2016, Vol. 35 ›› Issue (05): 1477-1483.DOI: 10.16085/j.issn.1000-6613.2016.05.031

锂离子电池电解液负极成膜添加剂的研究进展

周丹, 梁风, 姚耀春

昆明理工大学真空国家工程实验室, 云南省有色金属真空冶金重点实验室, 省部共建复杂有色金属资源清洁利用国家重点实验室, 云南昆明 650093

收稿日期:2015-09-21 修回日期:2015-11-21 出版日期:2016-05-05 发布日期:2016-05-05
通讯作者: 姚耀春,教授,博士生导师。E-mail yaochunyao@gmail.com。
作者简介:周丹(1991-),女,硕士研究生。E-mail zhoukdd@163.com。
基金资助:
国家自然科学基金(51364021)、教育部"创新团队发展计划"(IRT1250)及云南省自然科学基金(2014FA025)项目。

Research progress of negative film-forming additives in electrolyte for Li-ion batteries

ZHOU Dan, LIANG Feng, YAO Yaochun

The National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, State Key Laboratory Breeding Base of Complex Nonferrous Metal Resources Clear Utilization in Yunnan Province, Kunming 650093, Yunnan, China

Received:2015-09-21 Revised:2015-11-21 Online:2016-05-05 Published:2016-05-05

摘要/Abstract

摘要： 解决锂离子电池电极材料和电解液相容性的关键是形成稳定且Li⁺可导的固态电解质界面膜(SEI膜),因此,对优质负极成膜添加剂的研究成为锂离子电池研发中的一个热点。本文综述了锂离子电池电解液成膜添加剂的作用原理,具体介绍了各类负极成膜添加剂的研究现状,从成膜反应机理和理论计算方面详述了近几年来负极成膜添加剂的研究进展。分析了所存在的问题主要是如何快速地挑选出更适宜、更高效的成膜添加剂,并指出了成膜添加剂未来的发展趋势为:①研究各添加剂与电解液的反应机理,着重开发对锂离子电池副反应小的负极成膜添加剂;②通过选择两种或两种以上的添加剂的协同作用,以弥补一种添加剂的不足;③提高无机成膜添加剂在电解液中的溶解度。

关键词: 锂离子电池, 电解质, 成膜添加剂, 固态电解质界面膜(SEI膜)

Abstract: Forming a stable solid electrolyte interface film (SEI film) is the key to solve the compatibility between lithium ion battery electrode material and electrolyte. Therefore, the research of high quality anode film-forming additive in electrolyte for lithium ion battery attracts much attention. The principle of film-forming additives for organic electrolyte in Li-ion batteries was reviewed. The research status of a variety of additives was particularly introduced. The recent progress on negative film-forming additives was reviewed in detail, from the perspectives of film formation mechanisms and quantum calculation. The main problem was how to select more suitable and efficient film-forming additives. In addition, the possible trends in this area were proposed:①Understanding the mechanism of additive reacting with the electrolyte, especially for the negative film forming additive which has minimum side effects for lithium ion battery;②Combining two or more additives together to compensate the deficiencies of one additive;③Increasing the solubility of inorganic film-forming additives in the electrolyte.

Key words: Li-ion battery, electrolytes, film-forming additives, solid electrolyte interface (SEI)

中图分类号:

O646.5
TM912

周丹, 梁风, 姚耀春. 锂离子电池电解液负极成膜添加剂的研究进展[J]. 化工进展, 2016, 35(05): 1477-1483.

ZHOU Dan, LIANG Feng, YAO Yaochun. Research progress of negative film-forming additives in electrolyte for Li-ion batteries[J]. Chemical Industry and Engineering Progree, 2016, 35(05): 1477-1483.

参考文献

[1] 张国庆, 马莉, 倪佩, 等.锂离子电池低温电解液的研究进展[J].化工进展, 2008, 27(2): 209-213.
[2] YOSHITAKE H, YOSHIO M, KOZAWA A, et al. Functional electrolyte in lithium ion batteries[M]. Japan: Nikkan Kougyou Shinbunsha, 2000.
[3] 贠娇娇, 刘红梅, 郑会元, 等.无机添加剂用于锂离子电池电解液的研究进展[J].储能科学与技术, 2014, 3(6): 584-586.
[4] YAIR Ein-Eli, BORIS Markovsky, DORON Aurbach, et al.The dependence of the performance of Li-C intercalation anodes for Li-ion secondary batteries on the electrolyte solution composition [J].Electro Chimica Acta, 1994, 39: 2559-2569.
[5] DORON Aurbach, ELLA Zinigrad, YARON Cohen, et al.A short review of failuremechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions[J].Solid State Ionics, 2002, 148(3/4): 405-416.
[6] GEUN Chang Chung, HYUNG Jin Kim, SEUNG Il Yu, et al.Origin of graphite exfoliation an investigation of the important role of solvent cointercalazion[J].Electrochem.Soc., 2000, 147: 4391.
[7] 周良, 李芬芳, 樊玉川, 等.锂离子电池有机电解液成膜添加剂的研究现状[J].湖南有色金属, 2006, 26(3): 40-42.
[8] DORON Aurbach, KIRA Gamolsky, BORIS Markovsky, et al.On the use of vinylene carbonate (VC) as an additive to electrolyte solutions for Li-ion batteries[J].Electrchim Acta, 2002, 47(9): 1423-1439.
[9] ANDRZEJ Lewandowski, BEATA Kurc, AGNIESZKA Swiderska Mocek, et al. Graphite LiFePO₄lithium-ion battery working at the heat engine coolant temperature[J].Journal of Power Sources, 2014, 266: 132-137.
[10] MOLLER K C, SANTNER H J, KEM W, et al.In situcharacterization of the SEI formation on graphite in the presence of a vinylene group containing film-forming electrolyte additives[J].Journal of Power Sourses, 2003, 119/120/121: 561-566.
[11] LI S Y, ZHAO W, ZHOU Z F, et al.Studies on electrochemical performances of novel electrolytes for wide-temperature-range lithium-ion batteries[J].ACS Applied Materials & Interfaces, 2014, 6(7): 4920-4926.
[12] WRODNIGG G H, BESENHARD J O, WINTER M.Cyclic and acyclic sulfites: new solvents and electrolyte additives for lithium ion batteries with graphitic anodic[J].Journal of Power Sources, 2001, 97/98: 592-594.
[13] YIM T , SU H K, WOO S G , et al.1, 3-Propanesultone as an effective functional additive to enhance the electrochemical performance of over-lithiated layered oxides[J].Rsc Advances, 2014, 4(37): 19172-19176.
[14] XU M Q, LI W S, ZUO X X, et al.Performance improvement of lithium ion battery using PC as a solvent component and BS as an SEI forming additive[J].J. Power Sources, 2007, 174(2): 705-710.
[15] LEE Y M, NAM K M, HWANG E H, et al.Interfacial origin of performance improvement and fade for 4.6V LiNi_0.5Co_0.2Mn_0.3O₂ battery cathodes[J].Journal of Physical Chemistry C, 2014, 118(20): 10631-10639.
[16] KIM J S, BYUN D, LEE J K.Electrochemical characteristics of amorphous silicon thin film electrode with fluoroethylene carbonate additive[J].Current Applied Physics, 2014, 14(4): 596-602.
[17] SHU Z X, MCMILLAN R S, MURRAY J J, et al.Use of chlorochylene carbonate as an electrolyte solvent for a lithium ion battery containing a graphite anode[J]. J. Electrochimica Soc., 1995, 142(7): 161-162.
[18] 袁中直, 周震涛, 李伟善.电解液组成对锂离子电池碳负极SEI膜性能的影响[J].电池, 2002, 32(6): 354-357.
[19] HAN Gi Beom, RYOU Myung Hyun, CHO Kuk Young, et al.Effect of succinic anhydride as an electrolyte additive on electrochemical characteristics of silicon thin-film electrode[J].Journal of Power Sources, 2010, 195: 3709-3714.
[20] JOACHIM Ufheil, BAERTSCH Martin C, WURSIG Andreas, et al.Maleic Nhydride as an additive to butyrolactone solutions for Li-ion batteries[J].Electrochinica Acta, 2005, 50: 1733-1738.
[21] DORON Aurbach, ORIT Chusid, YAAKOV Carmeli, et al.The correlation between surface chemistry and the performance of Li-carbon intercalation anodes for rechargeable ""rocking-chair""type batteries[J].Journal of The Electrochemical Society, 1994, 141(3): 603-611.
[22] WU Maosung, LIN Jungcheng, CHIANG Pin-Chi Julia.A silver hexafluoro phosphate additive to propylene carbonate-based electrolytes for lithium-ion batteries[J]. Electrochemical and Solid-State Letters, 2004, 7(7): A206-A208.
[23] STUX Arnold, BARKER Jeremy.Additives for inhibiting decomposition of lithium salts and electrolytes containing said additives: US5707760[P].1998-11-31.
[24] KOMABA S, ITABASHI T, KAPLAN B, et al.Enhancement of Li-ion battery performance of graphite anode by sodium ion as an electrolyte additive[J].Electrochemistry Communications, 2003, 5(11): 962-966.
[25] 郑洪河, 张丽娜.无机添加剂Na₂SO₃对石墨负极性能的改善[J].电源技术, 2011, 35(1): 36-38.
[26] ZHUANG Q C, LI J, TIAN L L.Potassium carbonate as film forming electrolyte additive for lithium-ion batteries[J].Journal of Power Sources, 2013, 222: 177-183.
[27] XING L D, LI W S, WANG C Y, et al.Theoretical investigations on oxidative stability of solvents and oxidative decomposition mechanism of ethylene carbonate for lithium ion battery use [J].J.Phys. Chem. B, 2009, 113: 16596-16602.
[28] 蔡宗平, 许梦清, 李伟善, 等.锂离子电池电解液负极成膜添加剂研究进展[J].电池工业, 2008, 13(1): 68-711.
[29] BESENHARD J O, WINTER M, YANG J, et al.Filming mechanism of lithium-carbon anodes in organic and inorganic electrolytes[J].J Power Sources, 1995, 54(2): 228-231.
[30] 罗倩, 巢亚军, 渠冰, 等.锂离子电池中SEI膜的研究方法[J].电源技术, 2015, 139(5): 1086-1090.
[31] ABE K, YOSHITAKE H, KITAKURA T, et al.Additives-containing functional electrolytes for suppressing electrolyte decomposition in lithium-ion batteries[J].Electrochimica Acta, 2004, 49: 4620-4621.
[32] XING L D, BORODIN O, SMITH G, et al.A density function theory study of the role of anions on the oxid ative decomposition reaction of propylene carbonate[J]. J. Phys. Chem. A, 2011, 115: 13896- 13905.
[33] Deng J, Wagner G J, Muller P R.Phase field modeling of solid electrolyte interface formation in lithium ion batteries[J]. Journal of the Electrochemical Society, 2013, 160(3): A487-A496.
[34] 谢晓华, 陈立宝, 高阳, 等.锂离子电池电解液功能组分的设计[J].电池, 2006, 36(6): 435-4371.

锂离子电池电解液负极成膜添加剂的研究进展

Research progress of negative film-forming additives in electrolyte for Li-ion batteries

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	马伊, 曹世伟, 王家骏, 林立群, 邢延, 曹腾良, 卢峰, 赵振伦, 张志军. 低共熔溶剂回收废旧锂离子电池正极材料的研究进展[J]. 化工进展, 2023, 42(S1): 219-232.
[2]	王昊, 霍进达, 曲国瑞, 杨家琪, 周世伟, 李博, 魏永刚. 退役锂电池正极材料资源化回收技术研究进展[J]. 化工进展, 2023, 42(5): 2702-2716.
[3]	于捷, 张文龙. 锂离子电池隔膜的发展现状与进展[J]. 化工进展, 2023, 42(4): 1760-1768.
[4]	张艺璇, 胡伟, 刘梦瑶, 鞠敬鸽, 赵义侠, 康卫民. 聚合物电解质在锌离子电池中的研究进展[J]. 化工进展, 2023, 42(3): 1397-1410.
[5]	马文杰, 姚卫棠. 共价有机框架（COFs）在锂离子电池中的应用[J]. 化工进展, 2023, 42(10): 5339-5352.
[6]	陈二军, 张玉玲, 路少磊, 段海洋, 靳文章. 空气纳米气泡的稳定性及理化特性[J]. 化工进展, 2022, 41(9): 4673-4681.
[7]	王玥, 郑晓洪, 陶天一, 刘秀庆, 李丽, 孙峙. 废锂离子电池正极材料中锂元素选择性回收的研究进展[J]. 化工进展, 2022, 41(8): 4530-4543.
[8]	关浩然, 朱丽娜, 朱凌岳, 苑丹丹, 张雨晴, 王宝辉. 利用不同氢源及氮源电化学合成氨研究进展与挑战[J]. 化工进展, 2022, 41(8): 4098-4110.
[9]	程明强, 汝娟坚, 华一新, 王丁, 耿笑, 张文文, 黄皓铭, 王道祥. 低共熔溶剂在废旧锂离子电池正极材料回收中的研究进展[J]. 化工进展, 2022, 41(6): 3293-3305.
[10]	马续, 邹明贵, 崔巍巍, 付安然, 廖小龙, 巩桂芬. 一种水性负极黏结剂的合成及性能[J]. 化工进展, 2022, 41(6): 3138-3145.
[11]	段曼华, 程丹, 肖伟, 杨占旭. 聚丙烯腈/聚酯无纺布微孔复合锂电隔膜的制备及性能[J]. 化工进展, 2022, 41(5): 2615-2622.
[12]	龚鑫, 刘小冬, 温福山, 师楠, 刘东. 中间相炭微球乳化-聚合法制备及电化学性能[J]. 化工进展, 2022, 41(5): 2379-2388.
[13]	温嘉玮, 杨晨林, 成建凤, 黄国勇, 郭学益. 尖晶石型三元高电压正极材料的合成及其性能[J]. 化工进展, 2022, 41(11): 5968-5976.
[14]	胡华坤, 薛文东, 蒋朋, 李勇. 锂离子电池安全添加剂的研究进展[J]. 化工进展, 2022, 41(10): 5441-5455.
[15]	潘迪, 孔江榕, 刘欣楠, 黄美琪, 周涛. 湿化学法制备石榴石型固态电解质Li₇La₃Zr₂O₁₂[J]. 化工进展, 2021, 40(S2): 334-339.