银基析氧催化剂的研究进展

doi:10.16085/j.issn.1000-6613.2016.05.023

摘要/Abstract

摘要： 近年来基于阳极析氧催化的电解水制氢技术引起了广泛关注,安全、高效的阳极析氧催化剂是实现该技术的核心。银基析氧催化剂具有操作条件温和、析氧过电位低及结构易于调变的特性,是一种颇具发展前景的新型阳极析氧催化剂。本文综述了Ag基析氧催化剂的制备及其在电解水制氢方面的应用,着重介绍了Ag基析氧催化剂的两种调控改性方法,包括原位调控方法和后制备调控方法,其中原位调控方法主要有电解质溶液的匹配、电解质(浓度、酸碱度、温度)的调变和工作电极的修饰,后制备调控方法主要有金属氧化物复合、石墨烯复合和银氧化物纳米晶的调控。将原位调控和后制备调控相结合,可为制备具有较低过电势、较高催化活性的新型Ag基阳极析氧催化剂提供方法指导和为后续研究提供依据。

关键词: Ag基, 析氧催化剂, 阳极, 电解, 氧化, 制氢

Abstract: Water electrolysis by anodic oxygen evolving catalysis has drawn extensive attention in hydrogen production. Safe and efficient anodic oxygen catalyst is the key to realize the water splitting technology. Ag based catalysts are novel and promising oxygen evolving catalysts, as they can work under mild conditions and have lower oxygen evolution overpotential and modulated structures. Herein, Ag based oxygen-evolving catalysts in the application of water splitting for hydrogen production are presented. The methods of in situ modification such as matching electrolyte, controlling the concentration, pH, and temperature of electrolyte and modifying working electrode, and post-modification such as compositing metal oxidation, compositing graphene and controlling silver oxide nanocrystals, are reviewed. Besides, combining the two methods will provide some guidance and reference for further design of Ag based water oxidation catalyst.

Key words: Ag based, oxygen evolution catalyst, anode, electrolysis, oxidation, hydrogen production

中图分类号:

TK91

李丹丹, 高国锋, 郝根彦, 李晋平, 赵强. 银基析氧催化剂的研究进展[J]. 化工进展, 2016, 35(05): 1428-1432.

LI Dandan, GAO Guofeng, HAO Genyan, LI Jinping, ZHAO Qiang. Progress and prospect of Ag based oxygen-evolving catalysts[J]. Chemical Industry and Engineering Progree, 2016, 35(05): 1428-1432.

参考文献

[1] LEWIS N S, NOCERA D G.Powering the planet: chemical challenges in solar energy utilization[J].Proceedings of the National Academy of Sciences, 2006, 103(43): 15729-15735.
[2] LEWIS N S.Toward cost-effective solar energy use[J].Science, 2007, 315(5813): 798-801.
[3] WALTER M G, WARREN E L, MCKONE J R, et al. Solar water splitting cells[J].Chemical Reviews, 2010, 110(11): 6446-6473.
[4] LIANG Y, LI Y, WANG H, et al.Strongly coupled inorganic/nanocarbon hybrid materials for advanced electrocatalysis[J].Journal of the American Chemical Society, 2013, 135(6): 2013-2036.
[5] SMITH R D L, PRÉVOT M S, FAGAN R D, et al.Photochemical route for accessing amorphous metal oxide materials for water oxidation catalysis[J].Science, 2013, 340(6128): 60-63.
[6] BETLEY T A, WU Q, VAN VOORHIS T, et al.Electronic design criteria for O-O bond formation via metal-Oxo complexes[J].Inorganic Chemistry, 2008, 47(6): 1849-1861.
[7] CUKIER R I, NOCERA D G.Proton-coupled electron transfer[J].Annual Review of Physical Chemistry, 1998, 49(1): 337-369.
[8] HUYNH M H V, MEYER T J.Proton-coupled electron transfer[J].Chemical Reviews, 2007, 107(11): 5004-5064.
[9] LEE S W, CARLTON C, RISCH M, et al.The nature of lithium battery materials under oxygen evolution reaction conditions[J].Journal of the American Chemical Society, 2012, 134(41): 16959-16962.
[10] KANAN M W, NOCERA D G.In situ formation of an oxygen-evolving catalyst in neutral water containing phosphate and Co²⁺[J].Science, 2008, 321(5892): 1072-1075.
[11] DINCĂ M, SURENDRANATH Y, NOCERA D G.Nickel-borate oxygen-evolving catalyst that functions under benign conditions[J].Proceedings of the National Academy of Sciences, 2010, 107(23): 10337-10341.
[12] 王维, 赵强, 董晋湘, 等.原位电解合成 Ni-B析氧催化剂及其性能研究[J].太阳能学报, 2011, 32(6): 947-950.
[13] RISCH M, KLINGAN K, HEIDKAMP J, et al.Nickel-oxido structure of a water-oxidizing catalyst film[J]. Chemical Communications, 2011, 47: 11912-11914.
[14] BEDIAKO D K, LASSALLE-KAISEr B, SURENDRANATH Y, et al.Structure-activity correlations in a nickel-borate oxygen evolution catalyst[J].Journal of the American Chemical Society, 2012, 134(15): 6801-6809.
[15] WIECHEN M, BERENDS H-M, KURZ P.Water oxidation catalysed by manganese compounds: from complexes to ‘biomimetic rocks' [J].Dalton Transactions, 2012, 41: 21-31.
[16] WANG W, ZHAO Q, DONG J, et al.A novel silver oxides oxygen evolving catalyst for water splitting[J].International Journal of Hydrogen Energy, 2011, 36: 7374-7380.
[17] ZHAO Q, YU Z, YUAN W, et al. A WO₃/Ag-B_i oxygen-evolution catalyst for splitting water under mild conditions[J].International Journal of Hydrogen Energy, 2012, 37: 13249-13255.
[18] CHEN Z, MEYER T J.Copper(II) catalysis of water oxidation[J].Angewandte Chemie, 2013, 125: 728-731.
[19] DU J, CHEN Z, YE S, et al.Copper as a robust and transparent electrocatalyst for water oxidation[J].Angewandte Chemie, 2015, 54: 2073-2078.
[20] ZHAO Q, HAO G, YUAN W, et al.Novel copper oxides oxygen evolving catalyst in situ for electrocatalytic water splitting[J].Electrochimica Acta, 2015, 152: 280-285.
[21] WU Y.CHEN M, HAN Y, et al.Fast and simple preparation of iron-based thin films as highly efficient water-oxidation catalysts in neutral aqueous solution[J].Angewandte Chemie, 2015, 54: 4870-4875.
[22] FABBRI E, HABEREDER A, WALTAR K, et al.Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction[J].Catalysis Science & Technology, 2014, 4: 3800-3821.
[23] ZHAO Q, YU Z, YUAN W, et al.Metal-C_i oxygen-evolving catalysts generatedin situ in a mild H₂O/CO₂ environment[J].International Journal of Hydrogen Energy, 2013, 38: 5251-5258.
[24] ZHAO Q, YU Z, YUAN W, et al.Modulated crystalline Ag-C_i oxygen-evolving catalysts for electrocatalytic water oxidation[J].International Journal of Hydrogen Energy, 2014, 39: 1364-1370.
[25] TORELLI D A, HARRISON D P, LAPIDES A M, et al.Strategies for stabilization of electrodeposited metal particles in electropolymerized films for H₂O oxidation and H⁺ reduction[J]. ACS Applied Materials & Interfaces, 2013, 5: 7050-7057.
[26] COOK T R, DOGUTAN D K, REECE S Y, et al.Solar energy supply and storage for the legacy and nonlegacy worlds[J].Chemical Reviews, 2010, 110(11): 6474-6502 .
[27] MARSHALL A T, HAVERKAMP R G.Electrocatalytic activity of IrO₂-RuO₂ supported on Sb-doped SnO₂ nanoparticles [J].Electrochimica Acta, 2010, 55(6): 1978-1984.
[28] LOUIE M W, BELL A T.An investigation of thin-film Ni-Fe oxide catalysts for the electrochemical evolution of oxygen[J].Journal of the American Chemical Society, 2013, 135(33): 12329-12337.
[29] SMITH R D L, PRÉVOT M S, FAGAN R D, et al.Water oxidation catalysis: electrocatalytic response to metal stoichiometry in amorphous metal oxide films containing iron, cobalt, and nickel[J].Journal of the American Chemical Society, 2013, 135(31): 11580-11586.
[30] RAJ V, BALAJI P, JOSHI M, et al.Ag grafted ZnO nanoplates for photocatalytic applications[J].Materials Focus, 2014, 3: 385-391.
[31] XIE J, WU Q.One-pot synthesis of ZnO/Ag nanospheres with enhanced photocatalytic activity[J].Materials Letters, 2010, 64: 389-392.
[32] YIN X, QUE W, FEI D, et al.Ag nanoparticle/ZnO nanorods nanocomposites derived by a seed-mediated method and their photocatalytic properties[J].Journal of Alloys and Compounds, 2012, 524: 13-21.
[33] LIN D, WU H, ZHANG R, et al.Enhanced photocatalysis of electrospun Ag-ZnO heterostructured nanofibers[J].Chemistry of Materials, 2009, 21(15): 3479-3484.
[34] HUANG X, XIE M, CHEN Y, et al.Copper-silver oxide nanowires grown on an alloy electrode as an efficient electrocatalyst for water oxidation[J].RSC Advances, 2015, 5: 26150-26156.
[35] 王保伟, 孙启梅.石墨烯在光催化水解制氢中的应用[J].化工进展, 2012, 31(10): 2245-2251.
[36] ZHANG H, LV X, LI Y, et al. P25-graphene composite as a high performance photocatalyst[J].ACS Nano, 2010, 4: 380-386.
[37] ZHANG Y, TANG Z-R, FU X, et al.TiO₂-graphene nanocomposites for gas-phase photocatalytic degradation of volatile aromatic pollutant: is TiO₂-graphene truly different from other TiO₂-carbon composite materials?[J].ACS Nano, 2010, 4(12): 7303-7314.
[38] UPADHYAY S, BAGHERI S, ABD HAMID S B.Enhanced photoelectrochemical response of reduced-graphene oxide/Zn_1-xAg_xO nanocomposite in visible-light region[J].International Journal of Hydrogen Energy, 2014, 39: 11027-11034.
[39] GALLARDO O A D, MOIRAGHI R, MACCHIONE M A, et al. Silver oxide particles/silver nanoparticles interconversion: susceptibility of forward/backward reactions to the chemical environment at room temperature[J].RSC Advances, 2012, 2(7): 2923-2929.
[40] KIM M J, CHO Y S, PARK S H, et al.Facile synthesis and fine morphological tuning of Ag₂O[J].Crystal Growth & Design, 2012, 12(8): 4180-4185.
[41] LYU L M, WANG W C, HUANG M H.Synthesis of Ag₂O nanocrystals with systematic shape evolution from cubic to hexapod structures and their surface properties[J].Chemistry, 2010, 16(47): 14167-14174.
[42] BOOPATHI S, GOPINATH S, BOOPATHI T, et al.Characterization and antimicrobial properties of silver and silver oxide nanoparticles synthesized by cell-free extract of a mangrove-associated pseudomonas aeruginosa M6 using two different thermal treatments[J].Industrial & Engineering Chemistry Research, 2012, 51(17): 5976-5985.
[43] IVANOVA O S, ZAMBORINI F P.Size-dependent electrochemical oxidation of silver nanoparticles[J]. Journal of the American Chemical Society, 2009, 132(1): 70-72.
[44] CLOUD J E, TAYLOR L W, YANG YG.A simple and effective method for controllable synthesis of silver and silver oxide nanocrystals[J].RSC Advances, 2014, 4(47): 24551-24559.