Ag/TiO2纳米催化剂的制备及性能

doi:10.16085/j.issn.1000-6613.2016.03.026

化工进展 ›› 2016, Vol. 35 ›› Issue (03): 820-825.DOI: 10.16085/j.issn.1000-6613.2016.03.026

Ag/TiO₂纳米催化剂的制备及性能

樊国栋^1,2, 王丽娜^1,2, 管园园^1,2, 刘钰维^1,2, 林忱^1,2

1 陕西科技大学化学与化工学院, 陕西西安 710021;
2 教育部轻化工助剂化学与技术重点实验室, 陕西西安 710021

收稿日期:2015-06-22 修回日期:2015-09-17 出版日期:2016-03-05 发布日期:2016-03-05
通讯作者: 樊国栋(1964-),男,博士,教授,研究方向为光降解催化。E-mail:fangd@sust.edu.cn.
基金资助:
陕西省科技攻关项目(2014K08-12)、陕西省教育厅重点实验室科研计划(14JS015)及陕西科技大学研究生创新基金项目。

Preparation and properties of Ag/TiO₂ nanoparticle catalyst

FAN Guodong^1,2, WANG Lina^1,2, GUAN Yuanyuan^1,2, LIU Yuwei^1,2, LIN Chen^1,2

1 College of Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Xi'an 710021, Shaanxi, China;
2 Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Xi'an 710021, Shaanxi, China

Received:2015-06-22 Revised:2015-09-17 Online:2016-03-05 Published:2016-03-05

摘要/Abstract

摘要： 采用溶胶-凝胶法制备了Ag/TiO₂光催化剂。通过X射线衍射(XRD)、场发射扫描电子显微镜(FE-SEM)、N₂吸附-脱附(BET)、透射电子显微镜(TEM)对产物进行了表征。以亚甲基蓝(MB)为降解物,考察了不同Ag含量和不同煅烧温度对样品的光催化性能影响。结果表明,掺杂Ag后,增大了样品的比表面积,800℃时,Ag的引入抑制了TiO₂锐钛矿向金红石相的转变,掺杂后TiO₂的光催化活性大大提高,在500℃煅烧温度下,当Ag的摩尔分数为1%时,在紫外光照射下,经过180min光催化实验,对MB的降解率达到90%.

关键词: 二氧化钛, 纳米粒子, Ag掺杂, 催化剂, 粉体

Abstract: Ag-TiO₂ catalyst was prepared by the sol-gel method. The nanoparticles were characterized by means of X-ray diffraction (XRD),scanning electron microscopy (SEM),N₂ adsorption-desorption isotherm (BET),and transmission electron microscopy (TEM). Degradation of methylene blue (MB) was studied at different doping contents and different calcination temperatures. The results showed that the specific surface areas of the samples increased and the transition from anatase to rutile were greatly inhibited when the calcinated temperatures was 800℃。 Also the photocatalytic activity was found to increase after Ag was doped. When the calcinated temperature was 500℃ and 1% Ag doped TiO₂ nanoparticles were irradiated under ultraviolet light,the degradation rate of MB reached 90% after 180min.

Key words: titanium dioxide, nanoparticles, Ag-doped, catalyst, powders

中图分类号:

O643

樊国栋, 王丽娜, 管园园, 刘钰维, 林忱. Ag/TiO₂纳米催化剂的制备及性能[J]. 化工进展, 2016, 35(03): 820-825.

FAN Guodong, WANG Lina, GUAN Yuanyuan, LIU Yuwei, LIN Chen. Preparation and properties of Ag/TiO₂ nanoparticle catalyst[J]. Chemical Industry and Engineering Progree, 2016, 35(03): 820-825.

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Ag/TiO₂纳米催化剂的制备及性能

Preparation and properties of Ag/TiO₂ nanoparticle catalyst

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