基于生物质双流化床快速热解生产流程模拟的分析

doi:10.16085/j.issn.1000-6613.2016.03.012

化工进展 ›› 2016, Vol. 35 ›› Issue (03): 727-732.DOI: 10.16085/j.issn.1000-6613.2016.03.012

基于生物质双流化床快速热解生产流程模拟的分析

吕奇铮, 徐起翔, 张长森, 张瑞芹

郑州大学化学与分子工程学院, 河南省环境化学与低碳技术重点实验室, 河南郑州 450001

收稿日期:2015-07-27 修回日期:2015-08-18 出版日期:2016-03-05 发布日期:2016-03-05
通讯作者: 张长森,博士,从事生物质能源利用研究。E-mail:zhangcs@zzu.edu.cn.
作者简介:吕奇铮(1990-),男,硕士研究生。
基金资助:
河南省科技厅开放合作项目(142106000046).

Exergy analysis of biomass fast pyrolysis in dual fluidized bed based on process simulation

LÜ Qizheng, XU Qixiang, ZHANG Changsen, ZHANG Ruiqin

Environmental Chemistry & Low Carbon Technologies Lab of Henan Province, Chemistry and Molecular Engineering College, Zhengzhou University, Zhengzhou 450001, Henan, China

Received:2015-07-27 Revised:2015-08-18 Online:2016-03-05 Published:2016-03-05

摘要/Abstract

摘要： 用Aspen Plus 软件模拟了生物质双流化床快速热解生产流程,对流程的干燥、热解、冷凝、燃烧等过程进行了?分析,找出?利用率较低的可能影响因素,并对其改善。结果表明:流程压降对热解过程?利用率影响较小;副产物焦炭完全用作燃烧供热时,整个流程热流?损失较大,65%的焦炭用作燃烧供热时,?利用率由 69%提高到75.6%,模拟结果为生物质热解工业化放大过程能耗优化设计提供了参考依据。

关键词: 生物质, 快速热解, Aspen Plus, ?

Abstract: Fast pyrolysis of biomass in a dual fluidized was simulated using Aspen Plus software,and the process included the following unit operations:drying,pyrolysis,bio-oil condensation,and combustion . Based on the simulation results,exergetic analysis of the whole process was performed in order to optimize the overall exergetic efficiency. Analysis results indicated that the exergetic efficiency increased only slightly with a decrement of system pressure drop while increased significantly from 69% to 75.6% when the pyrolysis char combusted was reduced from 100% to 65%. The conclusions are useful for industrial design of biomass fast pyrolysis.

Key words: biomass, pyrolysis, Aspen Plus, exergy

中图分类号:

吕奇铮, 徐起翔, 张长森, 张瑞芹. 基于生物质双流化床快速热解生产流程模拟的分析[J]. 化工进展, 2016, 35(03): 727-732.

LÜ Qizheng, XU Qixiang, ZHANG Changsen, ZHANG Ruiqin. Exergy analysis of biomass fast pyrolysis in dual fluidized bed based on process simulation[J]. Chemical Industry and Engineering Progree, 2016, 35(03): 727-732.

参考文献

[1] 赵廷林,王鹏,邓大军,等. 生物质热解研究现状与展望[J]. 农业工程技术(新能源产业),2007(5):54-60.

[2] 曾少军,任磊. 清洁发展机制在我国生物质能领域的应用进展[J]. 化工进展,2009,28(5):729-33.

[3] BRIDGWATER A V,PEACOCKE G V C. Fast pyrolysis processes for biomass[J]. Renewable and Sustainable Energy Reviews,2000,4 (1):1-73.

[4] VENDERBOSCH R H , PRINS W. Fast pyrolysis technology development[J]. Biofuels,Bioproducts and Biorefining,2010,4(2): 178-208.

[5] JONES Susanne,MEYER Pimphan,SNOWDEN-SWAN Lesley, et al. Process design and economics for the conversion of lignocellulosic biomass to hydrocarbon fuels. NREL/TP-5100- 61178[R]. Oak Ridge : US Department of Energy Bioenergy Technologies Office,2013.

[6] HEPBASLI A. A key review on exergetic analysis and assessment of renewable energy resources for a sustainable future[J]. Renewable and Sustainable Energy Reviews,2008,12(3):593-661.

[7] SWAAN ARONS J D,KOOI H V D,SANKARANARAYANAN K. Efficiency and Sustainability in the Energy and Chemical Industries[M]. Netherlands:Delft University of Technology,2004.

[8] LEMS S , SWAAN ARONS J. The sustainability of resource utilization[J]. Green Chemistry,2002,4(4):308-813.

[9] JURASC K M,SUES A,PTASINSKI K J. Exergy analysis of synthetic natural gas production method from biomass[J]. Energy, 2010,35(2):880-888.

[10] ABUADALA A,DINCER I,NATERER G. Exergy analysis of hydrogen production from biomass gasification[J]. International Journal of Hydrogen Energy,2010,35(10):4981-4990.

[11] PTASINSKI K J,PRINS M J,PIERIK A. Exergetic evaluation of biomass gasification[J]. Energy,2007,32(4):568-74.

[12] BOATENG A A,MWLLEN C A,OSGOOD-JACOBS L,et al. Mass balance,energy,and exergy analysis of bio-oil production by fast pyrolysis[J]. Journal of Energy Resources Technology,2012,134 (4):042001.

[13] Aspen Plus. Getting started modeling processes with solids[R/OL]. Cambridge:Aspen Technology,2000.

[14] 张长森,杨力,刘永刚,等. 流化床反应器中生物质的热解研究[J]. 可再生能源,2007(4):29-33.

[15] WRIGHT Mark M,SATRIO Justinus A,BROWN Robert C. Techno-economic analysis of biomass fast pyrolysis to transportation fuels. NREL/TP-6A20-46586[R]. Oak Ridge:US Department of Energy Office of Scientific and Technical Information,2010.

[16] ONARHEIM K,SOLANTAUSTA Y,LEHTO J. Process simulation development of fast pyrolysis of wood using Aspen Plus[J]. Energy & Fuels,2015,29(1):205-217.

[17] RINGER M,PUSTSCHE V,SCAHILL J. Large-scale pyrolysis oil production : a technology assessment and economic analysis. NREL/TP-510-37779[R]. Oak Ridge:US Department of Energy Office of Scientific and Technical Information,2006.

[18] Aspen Plus. Aspen plus model for moving bed coal gasifier[R]. Burlington:Aspen Technology,2010.

[19] JANSE A M C,WESTERHOUT R W J,PRINS W. Modelling of flash pyrolysis of a single wood particle[J]. Chemical Engineering and Processing:Process Intensification,2000,39(3):239-252.

[20] MILLER R,BELLAN J. A generalized biomass pyrolysis model based on superimposed cellulose,hemicelluloseandliqnin kinetics[J]. Combustion Science and Technology,1997,126(1/2/3/4/5/6): 97-137.

[21] 王超,陈冠益,兰维娟,等. 生物质快速热解制油试验及流程模拟[J]. 化工学报,2014,65(2):679-683.

[22] DAHMEN N,HENRICH E,DINJUS E,et al. The bioliq® bioslurry gasification process for the production of biosynfuels , organic chemicals,and energy[J]. Energy,Sustainability and Society,2012, 2(1):1-44.

[23] FRANGOPOULOS C. Exergy , Energy System Analysis , and Optimization[M]. Greece:National Technical University of Athens, 2009.

[24] MORRISD R,SZARGUT J. Standard chemical exergy of some elements and compounds on the planet earth[J]. Energy,1986,11(8): 733-55.

[25] 朱自强. 化工热力学[M]. 北京:化学工业出版社,2010.

[26] PETERS J F,PETRAKOPOULOU F,DUFOUR J. Exergetic analysis of a fast pyrolysis process for bio-oil production[J]. Fuel Processing Technology,2014,119:245-255.

[27] BEJAN A,TSATSARONIS G,MORAN M. Thermal Design and Optimization[M]. Hoboken,NJ,USA:John Wiley & Sons,Wiley Interscience,1996.

[28] 张长森,石文,徐兴敏,等. 花生壳快速热解液化实验[J]. 农业机械学报,2010,41(5):82-85,147.

[29] 张长森,石文,徐兴敏,等. 木屑快速热解液化与产品分析[J]. 化工进展,2010,29(5):952-957.

基于生物质双流化床快速热解生产流程模拟的分析

Exergy analysis of biomass fast pyrolysis in dual fluidized bed based on process simulation

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