文冠果生物柴油与0#柴油混配物的混配规律

doi:10.16085/j.issn.1000-6613.2016-2304

化工进展 ›› 2017, Vol. 36 ›› Issue (07): 2451-2456.DOI: 10.16085/j.issn.1000-6613.2016-2304

文冠果生物柴油与0^#柴油混配物的混配规律

尚琼^1,2,3, 马明广^1,2, 白林^2,3, 李晓春⁴, 赵国虎^1,2,3

1 城市环境污染控制甘肃省高校省级重点实验室, 甘肃兰州 730070;
2 兰州城市学院化学与环境工程学院, 甘肃兰州 730070;
3 兰州城市学院绿色化学实验与教学研究所, 甘肃兰州 730070;
4 西安石油大学化学化工学院, 陕西西安 710065

收稿日期:2016-12-13 修回日期:2017-02-17 出版日期:2017-07-05 发布日期:2017-07-05
通讯作者: 赵国虎,院长,教授,研究方向为非线性分析化学、等离子体化学及表面功能材料。
作者简介:尚琼(1984-),女,硕士,讲师,研究方向为化工新能源。E-mail:qiong2003-12@163.com。
基金资助:
兰州市科技局项目（2012-2-99）及甘肃省城市发展研究院项目（2013-GSCFY-KJ02）。

Mixing rules of Xanthoceras sorbifolia Bunge oil biodiesel and 0^# diesel blends

SHANG Qiong^1,2,3, MA Mingguang^1,2, BAI Lin^2,3, LI Xiaochun⁴, ZHAO Guohu^1,2,3

1 Provincial Key Laboratory of Gansu Higher Education for City Environmental Pollution Control, Lanzhou 730070, Gansu, China;
2 School of Chemistry and Environmental Engineering, Lanzhou City University, Lanzhou 730070, Gansu, China;
3 Institute of Green Chemistry Experiment and Teaching, Lanzhou City University, Lanzhou 730070, Gansu, China;
4 College of Chemistry & Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, Shaanxi, China

Received:2016-12-13 Revised:2017-02-17 Online:2017-07-05 Published:2017-07-05

摘要/Abstract

摘要： 以甘肃产文冠果油为原料，在制备生物柴油的基础上，通过测试文冠果生物柴油与0^#柴油混配物（生物柴油体积分数分别为0、5%、20%、40%、60%、80%、100%）的密度、运动黏度、冷滤点、闪点等理化性质，研究了生物柴油体积分数对混配物理化性质的影响规律。结果表明，混配物的密度与混配物中生物柴油的体积分数呈良好的线性关系；混配物的运动黏度可用公式100ln（υρ）=X₁ln（υ₁ρ₁）+X₂ln（υ₂ρ₂）预测，计算值和实测值的相对偏差在±1%之内；混配物的冷滤点（CFPP）、闪点（FP）与生物柴油的体积分数（X）关系分别符合三次多项式CFPP=0.7344-0.1058X+0.00187X²-1.3875×10^-5X³和FP=57.2638+0.6836X-0.01762X²+1.8983×10^-4X³。随着生物柴油体积分数的增加，混配物的密度、运动黏度和闪点不断增大，而冷滤点逐渐降低，通过0^#柴油与生物柴油混配，可提高油品在储存、运输和使用过程的理化性能。

关键词: 文冠果油, 生物柴油, 0^#柴油, 混配物, 理化性质, 混配规律

Abstract: With Xanthoceras sorbifolia Bunge oil from Gansu province as raw materials,biodiesel was prepared and blended with the 0^# diesel fuels at 0,5%,20%,40%,60%,80% and 100% on a volume basis.The key properties of blends,such as density,kinematic viscosity,cold filter plug point and flash point were measured.Additionally,the influence of volume fraction of biodiesel on the blends properties was discussed.The density of blends was linear with the volume fraction of biodiesel and its value increased with the increasing of volume fraction of biodiesel.A mixing equation 100ln100ln (υρ)=X₁ln (υ₁ρ₁)+X₂ln(υ₂ρ₂) was used to predict the kinematic viscosities of the blends.For all blends,it was found that there was an excellent agreement between the measured and estimated values of the kinematic viscosities with the relative absolute error less than 1%.An empirical equation CFPP=0.7344-0.1058X+0.00187X²-1.3875×10^-5X³ could be used to correlate the cold filter plugging point (CFPP) and the volume fraction of biodiesel (X).The experimental data of flash point (FP) was also correlated as a function of biodiesel volume fraction(X) by empirical third-degree equation,which was given by FP=57.2638+0.6836X-0.01762X²+1.8983×10^-4X³.According to the results,the density,kinematic viscosities and flash point of the blends increased with the increase of volume fraction of biodiesel in the blends,whereas the CFPP of blends decreased.The physicochemical properties of blends were improved when mixing 0^# diesel fuels with biodiesel,in the purpose of storage,utilization and transportation.

Key words: Xanthoceras sorblfolia Bunge oil, biodiesel, 0^# diesel, blends, physicochemical property, mixing rules

中图分类号:

TQ645

尚琼, 马明广, 白林, 李晓春, 赵国虎. 文冠果生物柴油与0^#柴油混配物的混配规律[J]. 化工进展, 2017, 36(07): 2451-2456.

SHANG Qiong, MA Mingguang, BAI Lin, LI Xiaochun, ZHAO Guohu. Mixing rules of Xanthoceras sorbifolia Bunge oil biodiesel and 0^# diesel blends[J]. Chemical Industry and Engineering Progress, 2017, 36(07): 2451-2456.

参考文献

[1] 鲁厚芳,史国强,刘颖颖,等. 生物柴油生产及性质研究进展[J]. 化工进展,2011,30(1):126-136. LU H F,SHI G Q,LIU Y Y,et al. A review on researches on biodiesels production and their properties[J]. Chemical Industry and Engineering Progress,2011,30(1):126-136.
[2] 闵恩泽. 利用可再生油料资源发展生物炼油化工厂[J]. 化工学报,2006,57(8):1739-1745. MIN E Z. Developing bio-refinery by utilizing renewable vegetable oils[J]. Journal of Chemical Industry and Engineering(China),2006,57(8):1739-1745.
[3] 孔维宝,梁俊玉,马正学,等. 文冠果油的研究进展[J]. 中国油脂,2011,36(11):67-72. KONG W B,LIANG J Y,MA Z X,et al. Research advance of Xanthoceras sorbifolia Bunge oil[J]. China Oils and Fats,2011,36(11):67-72.
[4] 邓红,仇农学,孙俊,等. 超声波辅助提取文冠果籽油的工艺条件优化[J]. 农业工程学报,2007,23(11):249-254. DENG H,QIU N X,SUN J,et al. Optimization of ultrasonic-assisted extraction technology of oil from Xanthoceras sorborifolia burge seeds[J]. Transactions of the Chinese Society of Agricultural Engineering,2007,23(11):249-254.
[5] ZHANG S,ZU Y G,FU Y J,et al. Supercritical carbon dioxide extraction of seed oil from yellow horn(Xanthoceras sorbifolia Bunge.)and its antioxidant activity[J]. Bioresource Technology,2010,101(7):2537-2544.
[6] 麻起,谷克仁,杜雪丽. 文冠果油的超临界CO₂萃取工艺研究[J]. 粮油食品科技,2013,21(4):36-40. MA Q,GU K R,DU X L. Extraction of Xanthoceras sorbifolia Bunge seed oil by supercritical CO₂ extraction[J]. Science and Technology of Cereals,Oils and Foods,2013,21(4):36-40.
[7] LI J,ZU Y G,LUO M,et al. Aqueous enzymatic process assisted by microwave extraction of oil from yellow horn(Xanthoceras sorbifolia Bunge.)seed kernels and its quality evaluation[J]. Food Chemistry,2013,138(4):2152-2158.
[8] 李冰. 亚临界萃取文冠果籽油工艺的响应面优化[J]. 中国油脂,2015,40(2):19-23. LI B. Optimization of subcritical extraction of Xanthocers sorbifolia Bunge seed oil by response surface methodology[J]. China Oils and Fats,2015,40(2):19-23.
[9] ZHANG S,ZU Y G,FU Y J,et al. Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst[J]. Bioresource Technology,2010,101(3):931-936.
[10] 柳杨,衣怀峰,陈宇,等. SBA-15的改性及催化文冠果油制备生物柴油[J]. 化工进展,2011,30(6):1247-1258. LIU Y,YI H F,CHEN Y,et al. Preparation of bildiesel from sorbifolia oil catalyzed by modified SBA-15[J]. Chemical Industry and Engineering Progress,2011,30(6):1247-1258.
[11] 陈燕勤,陈德军,杨再磊,等. 离子液体催化文冠果种仁油超临界甲醇酯交换法制备生物柴油[J]. 新疆农业大学学报,2012,35(1):65-69. CHEN Y Q,CHEN D J,YANG Z L,et al. Biological diesel oil Produced from Xanthocers sorbifolia seed oil by transesterification in supercritical methanol with catalyst of ionic liquid[J]. Journal of Xinjiang Agricultural University,2012,35(1):65-69.
[12] 刘承先. Lewis酸性离子液体催化文冠果种仁油制备生物柴油[J]. 化工新型材料,2015,43(2):37-39,42. LIU C X. Preparation of biodiesel from Sorbifolia seed oil catalyzed by Lewis acid ionic liquid[J]. New Chemical Materials,2015,43(2):37-39,42.
[13] LI J,FU Y J,QU X J,et al. Biodiesel production from yellow horn (Xanthoceras sorbifolia Bunge.)seed oil using ion exchange resin as heterogeneous catalyst[J]. Bioresource Technology,2012,108(2):112-118.
[14] 郝一男,王虎军,王喜明,等. 文冠果生物柴油的生产工艺及其理化性能[J]. 农业工程学报,2014,30(6):172-178. HAO Y N,WANG H J,WANG X M,et al. Production technology of Xanthoceras sorbifolia bunge biodiesel and its physical and chemical properties[J]. Transactions of the Chinese Society of Agricultural Engineering,2014,30(6):172-178.
[15] YAO Z Y,QI J H,YIN L M. Biodiesel production from Xanthoceras sorbifolia in China:opportunities and challenges[J]. Renewable & Sustainable Energy Reviews,2013,24(10):57-65.
[16] CANDEIA R A,SILVA M C D,FILHO J R C,et al. Influence of soybean biodiesel content on basic properties of biodiesel-diesel blends[J]. Fuel,2009,88(4):738-743.
[17] 张惠娟,蒋炜,鲁厚芳,等. 棕榈油生物柴油与0^#柴油混配物性质研究[J]. 中国油脂,2009,34(3):34-37. ZHANG H J,JIANG W,LU H F,et al. Phase composition in the process of biodiesel preparation from palm oil and the properties of biodiesel[J]. China Oils and Fats,2009,34(3):34-37.
[18] 陈明艳,蒋炜,鲁厚芳,等. 麻疯树籽油生物柴油与0^#柴油的混配性质[J]. 化工进展,2009,28(4):629-632. CHEN M Y,JIANG W,LU H F,et al. Properties of Jatropha curcas L. oil biodiesel-diesel blends[J]. Chemical Industry and Engineering Progress,2009,28(4):629-632.
[19] SHANG Q,JIANG W,LU H F,et al. Properties of Tung oil biodiesel and its blends with 0^# diesel[J]. Bioresource Technology,2010,101(2):826-828.
[20] 尚琼,汪淼,赵国虎,等. 胡麻油生物柴油与0^#柴油混配物的性质研究[J]. 甘肃农业大学学报,2016,51(2):140-143. SHANG Q,WANG M,ZHAO G H,et al. Properties of flax oil biodiesel and 0^# diesel blends[J]. Journal of Gansu Agricultural University,2016,51(2):140-143.
[21] 张惠娟,尚琼,鲁厚芳,等. 棕榈油制备生物柴油过程中的物相组成及产品性质[J]. 中国油脂,2008,33(3):49-52. ZHANG H J,SHANG Q,LU H F,et al. Phase composition in the process of biodiesel preparation from palm oil and the properties of biodiesel[J]. China Oils and Fats,2008,33(3):49-52.
[22] 王松汉. 石油化工设计手册(第1卷):石油化工基础数据[M]. 北京:化学工业出版社,2002:820-821. WANG H S. Handbook of petrochemical design(Vol.1):petrochemical basic data[M]. Beijing:Chemical Industry Press,2002:820-821.

文冠果生物柴油与0^#柴油混配物的混配规律

Mixing rules of Xanthoceras sorbifolia Bunge oil biodiesel and 0^# diesel blends

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	金鑫, 李玉姗, 解青青, 王梦雨, 夏星帆, 杨朝合. 多孔材料催化丙酮缩甘油合成研究进展[J]. 化工进展, 2023, 42(2): 731-743.
[2]	秦振芳, 廖日红, 马伟芳. 吸收-微藻法固定燃气电厂低浓度CO₂同步产油技术研究进展[J]. 化工进展, 2023, 42(1): 94-106.
[3]	赵建兵, 杨丹, 舒原草, 朱俊波, 普仕萍, 宋晓丹, 刘守庆, 柴希娟, 李雪梅. Na₂CO₃/CF固体碱对菜籽油酯交换反应的催化性能[J]. 化工进展, 2022, 41(7): 3608-3614.
[4]	邹鹏程, 金光远, 李臻峰, 宋春芳, 韩太柏, 祝玉莲. 一种具有模式搅拌的微波反应釜内多物理场特性分析[J]. 化工进展, 2022, 41(5): 2301-2310.
[5]	马鑫, 王霜, 李法社, 张逸水, 蒋上. 生物柴油雾化特性仿真模拟及实验研究[J]. 化工进展, 2022, 41(2): 655-665.
[6]	纪淑兰, 李迅, 王飞. 丝瓜络固定化米根霉催化光皮树油制备生物柴油[J]. 化工进展, 2022, 41(10): 5381-5389.
[7]	朱长辉, 朱文超, 罗嘉, 田保河, 孙佳琳, 邹志云. 微波强化酯交换反应制备生物柴油研究进展[J]. 化工进展, 2022, 41(10): 5145-5154.
[8]	岳倩倩, 高李璟, 肖国民, 魏瑞平, 雷严. 生物柴油连续化生产设备及工艺进展[J]. 化工进展, 2021, 40(S2): 81-88.
[9]	邹帅, 李玉芹, 马怡然, 齐振华, 贾权威. 二乙醇胺强化胶球藻Coccomyxa subellipsoidea C-169固定CO₂和积累油脂[J]. 化工进展, 2021, 40(9): 5222-5230.
[10]	包文君, 李子富, 王雪梅, 高瑞岭, 程世昆, 门玉. 产油酵母利用廉价原料合成油脂的研究进展[J]. 化工进展, 2021, 40(5): 2484-2495.
[11]	孟心宇, 徐杰, 万杰, 刘雁军, 王晓丽, 张君, 郑锋, 阚建飞, 吴功德. 碳酸甘油酯的合成研究及产业化进展[J]. 化工进展, 2020, 39(9): 3739-3749.
[12]	邢海亮,董训赞,韩本勇,耿树香,宁德鲁,马婷,余旭亚. 二氧化碳联合核桃壳提取液促进单针藻Monoraphidium sp. QLZ-3的生长和油脂积累[J]. 化工进展, 2020, 39(4): 1575-1582.
[13]	王霜,王友昊,李法社,王文超,隋猛. 基于紫外吸光度的生物柴油氧化降解程度分析[J]. 化工进展, 2020, 39(2): 506-512.
[14]	张金永, 汪林, 王明新, 肖扬, 韩莹. 机械化学法修复石油烃污染土壤及对土壤特性的影响[J]. 化工进展, 2020, 39(11): 4726-4733.
[15]	滕雯, 陈勇, 隋猛, 李法社. TEPA与[MI][C₆H₂(OH)₃COO]复配对小桐子生物柴油抗氧化性的影响[J]. 化工进展, 2020, 39(11): 4427-4434.

文冠果生物柴油与0#柴油混配物的混配规律

Mixing rules of Xanthoceras sorbifolia Bunge oil biodiesel and 0# diesel blends

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

文冠果生物柴油与0^#柴油混配物的混配规律

Mixing rules of Xanthoceras sorbifolia Bunge oil biodiesel and 0^# diesel blends