一种新型堵水调剖用酚醛交联剂的研究

doi:10.16085/j.issn.1000-6613.2016-2180

化工进展 ›› 2017, Vol. 36 ›› Issue (09): 3400-3406.DOI: 10.16085/j.issn.1000-6613.2016-2180

一种新型堵水调剖用酚醛交联剂的研究

孙磊, 徐鸿志, 郝志伟, 张贵清, 夏烨, 刘小攀, 王宇宾

中国石油集团工程技术研究院, 天津 300457

收稿日期:2016-11-24 修回日期:2017-05-25 出版日期:2017-09-05 发布日期:2017-09-05
通讯作者: 孙磊(1987-),男,博士,工程师,主要从事油田化学提高采收率方面的研究。
作者简介:孙磊(1987-),男,博士,工程师,主要从事油田化学提高采收率方面的研究。E-mail:sunlei3@cnpc.com.cn

Study on a novel phenol-formaldehyde crosslinker for water shutoff and profile control

SUN Lei, XU Hongzhi, HAO Zhiwei, ZHANG Guiqing, XIA Ye, LIU Xiaopan, WANG Yubin

CNPC Research Institute of Engineering Technology, Tianjin 300457, China

Received:2016-11-24 Revised:2017-05-25 Online:2017-09-05 Published:2017-09-05

摘要/Abstract

摘要： 水溶性低聚合度酚醛树脂交联剂，因其将苯酚和甲醛进行一定程度的反应，与常规酚醛单体类交联剂相比，挥发性和毒性较低，因而被广泛应用于油田堵水调剖作业。但此类交联剂在室温下放置一段时间后极易出现固化情况，保存稳定性不足，严重影响交联剂的使用。针对这一不足，本文通过分子设计制备了一种新型酚醛类交联剂，该交联剂稳定性优异，50℃条件下可存贮60天左右。利用该交联剂制备凝胶体系，成胶黏度可达20000mPa·s，成胶适用温度范围为60~120℃，可耐受钠离子20000mg/L、钙离子5000mg/L及pH=5~9的地层环境，成胶60天后凝胶黏度保留率约为75%，封堵率94%左右。相比于常规酚醛类交联剂具有更广阔的适用性。

关键词: 交联剂, 合成, 聚合物, 凝胶, 封堵率

Abstract: Water-soluble,low polymerization degree phenolic resin crosslinker,synthesized by phenol and formaldehyde through a certain degree of reaction,has lower volatile and toxicity compared to conventional phenolic monomer crosslinking agent. Therefore,it is widely used in oil field water shut off Profile operation. However,this kind of crosslinking agent is easy to cure at room temperature that has greatly limited its application. In this paper,a novel phenolic crosslinking agent is prepared by molecular design. The cross-linking agent has excellent stability and can be stored for 60 days at 50℃. The gelation system can be prepared by using this crosslinking agent. The gelation strength is up to 20000mPa·s and the gelation temperature ranges from 60℃ to 120℃. It can tolerate 20000 mg/L of sodium ion,5000mg/L of calcium ion,and pH 5-9. The gel retention rate is around 75% after 60 days,and the blocking rate is about 94%. Compared with the conventional phenolic crosslinking agent it has a wider applicability.

Key words: crosslinking agent, synthesis, polymers, gels, blocking rate

中图分类号:

TQ326.4

孙磊, 徐鸿志, 郝志伟, 张贵清, 夏烨, 刘小攀, 王宇宾. 一种新型堵水调剖用酚醛交联剂的研究[J]. 化工进展, 2017, 36(09): 3400-3406.

SUN Lei, XU Hongzhi, HAO Zhiwei, ZHANG Guiqing, XIA Ye, LIU Xiaopan, WANG Yubin. Study on a novel phenol-formaldehyde crosslinker for water shutoff and profile control[J]. Chemical Industry and Engineering Progress, 2017, 36(09): 3400-3406.

参考文献

[1] 白宝君,周佳,印鸣飞. 聚丙烯酰胺类聚合物凝胶改善水驱波及技术现状及展望[J]. 石油勘探与开发,2015,42(4):481-487. BAI B J,ZHOU J,YIN M F. A comprehensive review of polyacrylamide polymer gels for conformance control[J]. Petroleum Exploration and Development,2015,42(4):481-487.
[2] 许定佳,郑永付,张松,等. 调剖驱油技术中弱凝胶体系研究进展[J]. 化工进展,2015,34(5):1323-1331. XU D J,ZHEN Y F,ZHANG S,et al. Application progress of weak gel systems in oilfield profile control technology[J]. Chemical Industry and Engineering Progress,2015,34(5):1323-1331.
[3] HONG U S,JUNG S L,CHO K H,et al. Wear mechanism of multiphase friction materials with different phenolic resin matrices[J]. Wear,2009,266(7):739-744.
[4] 张羽毳,汪树军. 一种合成水溶性酚醛树脂的简单方法[J]. 中国胶粘剂,2004,13(2):9-11. ZHANG Y H,WANG S J. A simple method for preparing water-soluble phenol-formaldehyde resin[J]. China Adhesives,2004,13(2):9-11.
[5] ZHONG Y,JING X,WANG S,et al. Behavior investigation of phenolic hydroxyl groups during the pyrolysis of cured phenolic resin via molecular dynamics simulation[J]. Polymer Degradation and Stability,2016,125:97-104.
[6] 谭晓明,黄乃瑜,尚永华,等. 硼酸钠/甲阶酚醛树脂配合物结构和反应机理[J]. 华中科技大学学报(自然科学版),2001,29(8):93-95. TAN X M,HUANG N Y,SHANG Y H,et al. Complexes structure of the sodium borate and resol phenol-formaldehyde resin and their reaction mechanism[J]. Journal of Huazhong University of Science and Technology(Natural Science Edition),2001,29(8):93-95.
[7] 黎钢,张松梅,郝立根. 两步碱催化法合成水溶性酚醛树脂[J]. 中国胶粘剂,2003,19(1):18-21. LI G,ZHANG S M,HAO L G. Synthesis the water soluble phenol-formaldehyde resin by two step alkaline catalytic reaction[J]. China Adhesives,2003,19(1):18-21.
[8] 陈精明,敖文亮,吴晓卫,等. 甲阶酚醛树脂的合成研究进展[J]. 热固性树脂,2004,19(6):31-34. CHEN J M,AO W L,WU X W,et al. Review on synthesis of resole[J]. Thermosetting Resin,2004,19(6):31-34.
[9] 王宇宾,孙磊,张贵清,等. 一种复合交联剂的制备及性能评价[J]. 化工进展,2017,36(2):683-688. WANG Y B,SUN L,ZHANG G Q,et al. Preparation and evaluation of a composite crosslinking agent[J]. Chemical Industry and Engineering Progress,2017,36(2):683-688.
[10] 戴春岭,王先友,黄庆华. 水溶性酚醛树脂制备超级电容器用活性炭[J]. 化工学报,2008,59(4):1058-1064. DAI C L,WANG X Y,HUANG Q H. Activated carbon prepared from water solublephenol-formaldehyde resin for application in supercapacitor[J]. Journal of Chemical Industry and Engineering(China),2008,59(4):1058-1064.
[11] 王超,黄玉东. 一步法合成有机硅改性酚醛树脂及其粘接性能[J]. 复合材料学报,2004,21(2):50-54. WANG C,HUANG Y D. Study on preparation thermosetting phenolic resin modified with silicone and its adhesive properties[J]. Acta Materiae Compositae Sinica,2004,21(2):50-54.
[12] 孙立梅,李明远,彭勃,等. 水溶性酚醛树脂稀溶液的稳定性[J]. 中国石油大学学报(自然科学版),2008,32(3):147-151. SUN L M,LI M Y,PENG B,et al. Stability of dilute water soluble phenol-formaldehyde resin solution[J]. Journal of China University of Petroleum(Edition Of Natural Science),2008,32(3):147-151.
[13] 伊廷会. 高性能酚醛树脂改性研究进展[J]. 化工进展,2001,20(9):29-34. YI T H. Advance in the modifying research of high performance phenolic resin[J]. Chemical Industry and Engineering Progress,2001,20(9):29-34.
[14] 周重光,李桂芝,巩爱军. 有机硅改性酚醛树脂热稳定性的研究[J]. 高分子材料科学与工程,2000,16(1):164-165. ZHONG Z G,LI G Z,GONG A J. Study on the thermal stability of organosilicon-phenolic resin[J]. Polymer Materials Science & Engineering,2000,16(1):164-165.
[15] 任蕊,党江敏,刘春玲,等. 高邻位高分子量热塑性酚醛树脂研制[J]. 高分子通报,2011(7):82-89. REN R,DANG J M,LIU C L,et al. Study on high-ortho and high molecular weight thermoplastic phenolic resin[J]. Polymer Bulletin,2011(7):82-89.
[16] 潘艳平,王银,任蕊,等. 高分子量高邻位酚醛树脂的合成与表征[J]. 材料工程,2013(2):83-86. PAN Y P,WANG Y,REN R,et al. Synthesis and characterization of the high molecular weight and high-ortho thermoplastic phenolic resin[J]. Journal of Materials Engineering,2013(2):83-86.
[17] 刘书萌,吴东森,李晓文,等. 甲阶酚醛树脂的合成及其发泡性能研究[J]. 塑料科技,2014,42(2):29-33. LIU S M,WU D S,LI X W,et al. study on synthesis and foaming properties of phenolic resol resin[J]. Plastics Science and Technology,2014,42(2):29-33.
[18] PARK B D,RIEDL B. ¹³C-NMR study on cure-accelerated phenol-formaldehyde resins with carbonates[J]. J. Appl. Polym. Sci.,2000,77(6):1284-1293
[19] 李智立,张银生,冀克俭,等. 酚醛环氧树脂的基质辅助激光解吸电离飞行时间质谱(MALDI-TOF-MS)表征[J]. 材料研究学报,1997,11(4):419-422. LI Z L,ZHANG Y S,JI K J,et al. Characterization of phenol-foramaldehyde epoxy resins by matrix-assisted laser desorption ionization time of flight mass spectrometry[J]. Chinese Journal of Material Research,1997,11(4):419-422.
[20] ZHAO G,DAI C,ZHANG Y,et al. Enhanced foam stability by adding comb polymer gel for in-depth profile control in high temperature reservoirs[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2015,482:115-124.

一种新型堵水调剖用酚醛交联剂的研究

Study on a novel phenol-formaldehyde crosslinker for water shutoff and profile control

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[2]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[3]	赵巍, 赵德银, 李世瀚, 刘洪达, 孙进, 郭艳秋. 三嗪型天然气管道缓蚀型减阻剂合成与应用[J]. 化工进展, 2023, 42(S1): 391-399.
[4]	王正坤, 黎四芳. 双子表面活性剂癸炔二醇的绿色合成[J]. 化工进展, 2023, 42(S1): 400-410.
[5]	林晓鹏, 肖友华, 管奕琛, 鲁晓东, 宗文杰, 傅深渊. 离子聚合物-金属复合材料（IPMC）柔性电极的研究进展[J]. 化工进展, 2023, 42(9): 4770-4782.
[6]	王少凡, 周颖, 郝康安, 黄安荣, 张如菊, 吴翀, 左晓玲. 具有pH响应性的自愈合蓝光水凝胶[J]. 化工进展, 2023, 42(9): 4837-4846.
[7]	朱传强, 茹晋波, 孙亭亭, 谢兴旺, 李长明, 高士秋. 固体高分子脱硝剂选择性非催化还原NO _x 特性[J]. 化工进展, 2023, 42(9): 4939-4946.
[8]	李伯耿, 罗英武, 刘平伟. 聚合物产品工程研究内容与方法的思考[J]. 化工进展, 2023, 42(8): 3905-3909.
[9]	王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004.
[10]	向阳, 黄寻, 魏子栋. 电催化有机合成反应的活性和选择性调控研究进展[J]. 化工进展, 2023, 42(8): 4005-4014.
[11]	张婷婷, 潘大伟, 巨晓洁, 刘壮, 谢锐, 汪伟, 褚良银. Hg²⁺响应型智能凝胶检测光栅的构建与性能[J]. 化工进展, 2023, 42(8): 4143-4152.
[12]	于静文, 宋璐娜, 刘砚超, 吕瑞东, 武蒙蒙, 冯宇, 李忠, 米杰. 一种吲哚基超交联聚合物In-HCP对水中碘的吸附作用[J]. 化工进展, 2023, 42(7): 3674-3683.
[13]	陆洋, 周劲松, 周启昕, 王瑭, 刘壮, 李博昊, 周灵涛. CeO₂/TiO₂吸附剂煤气脱汞产物的浸出规律[J]. 化工进展, 2023, 42(7): 3875-3883.
[14]	陈森, 殷鹏远, 杨证禄, 莫一鸣, 崔希利, 锁显, 邢华斌. 功能固体材料智能合成研究进展[J]. 化工进展, 2023, 42(7): 3340-3348.
[15]	王帅旗, 王从新, 王学林, 田志坚. 无溶剂快速合成ZSM-12分子筛[J]. 化工进展, 2023, 42(7): 3561-3571.