β-CD/Al2O3/ATP复合材料对乙腈/正丙醇的吸附分离性能的影响

doi:10.16085/j.issn.1000-6613.2016-2380

化工进展 ›› 2017, Vol. 36 ›› Issue (09): 3407-3413.DOI: 10.16085/j.issn.1000-6613.2016-2380

β-CD/Al₂O₃/ATP复合材料对乙腈/正丙醇的吸附分离性能的影响

王俊, 韶晖, 解丹燕, 冷一欣, 黄春香

常州大学石油化工学院, 江苏省绿色催化材料与技术重点实验室, 江苏常州 213164

收稿日期:2016-12-22 修回日期:2017-04-28 出版日期:2017-09-05 发布日期:2017-09-05
通讯作者: 韶晖,教授,博士,从事分子筛的制备和分离技术的研究。
作者简介:王俊(1986-),男,讲师,博士,从事分离技术的研究。E-mail:wangjunfluid@gmail.com
基金资助:
江苏省青年科学自然基金项目（BK2015026）。

Study on the adsorption performance of β-CD/Al₂O₃/ATP composites for separation of acetonitrile and n-propanol

WANG Jun, SHAO Hui, XIE Danyan, LENG Yixin, HUANG Chunxiang

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China

Received:2016-12-22 Revised:2017-04-28 Online:2017-09-05 Published:2017-09-05

摘要/Abstract

摘要： 以β-CD/Al₂O₃/ATP复合材料为吸附剂，对乙腈和正丙醇体系进行静态和动态吸附实验，考察吸附条件对吸附分离性能的影响。实验结果显示，β-CD/Al₂O₃/ATP对体系具有较好的吸附效果。吸附时间的延长、吸附温度的降低和振荡速率的增大均使得静态饱和吸附量增大。利用Langmuir方程拟合吸附数据，呈现良好的线性关系。伪二级动力学方程较好地描述了乙腈和正丙醇在复合材料上的吸附动力学过程。动态吸附实验结果表明，适当地减小流速和增加柱高，有利于提高吸附分离效果。当流速为0.05L/min，柱高为10cm，β-CD/Al₂O₃/ATP复合材料对乙腈和正丙醇的饱和吸附量分别为182.6mg/g和69.76mg/g，乙腈的选择性达到0.73。

关键词: &beta, -CD, 凹凸棒土, 乙腈, 正丙醇, 吸附分离

Abstract: The static and dynamic adsorption experiments were carried out on the system of acetonitrile and n-propanol with β-CD/Al₂O₃/ATP composites as adsorbent. The effect of the adsorption conditions on separation of the mixture was investigated. The result showed that β-CD/Al₂O₃/ATP composite had good adsorption separation effect to the system. The saturate adsorption capacity of the adsorbent was increased with the extension of adsorption time,the decreasing of adsorption temperature and the increasing of oscillation rate. The experimental data were fitted by the Langmuir equation,showing a good linear relationship. The kinetics of the adsorption of acetonitrile and n-propanol on the composite was well described by the pseudo secondary dynamics equation. The dynamic adsorption experiment showed that appropriate reduction of flow rate and increase of column height was beneficial to improve adsorption and separation efficiency. The saturate adsorption capacities of the β-CD/Al₂O₃/ATP composite material for acetonitrile and n-propanol were 182.6mg/g and 69.76mg/g,respectively. The adsorptive selectivity of acetonitrile was 0.73 with the flow rate of 0.05L/min and the column height of 10cm.

Key words: β-CD, attapulgite (ATP), acetonitrile, n-propanol, adsorption and separation

中图分类号:

TQ424.21

王俊, 韶晖, 解丹燕, 冷一欣, 黄春香. β-CD/Al₂O₃/ATP复合材料对乙腈/正丙醇的吸附分离性能的影响[J]. 化工进展, 2017, 36(09): 3407-3413.

WANG Jun, SHAO Hui, XIE Danyan, LENG Yixin, HUANG Chunxiang. Study on the adsorption performance of β-CD/Al₂O₃/ATP composites for separation of acetonitrile and n-propanol[J]. Chemical Industry and Engineering Progress, 2017, 36(09): 3407-3413.

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β-CD/Al₂O₃/ATP复合材料对乙腈/正丙醇的吸附分离性能的影响

Study on the adsorption performance of β-CD/Al₂O₃/ATP composites for separation of acetonitrile and n-propanol

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