湿法脱硫废水液柱蒸发特性

doi:10.16085/j.issn.1000-6613.2016-2160

化工进展 ›› 2017, Vol. 36 ›› Issue (07): 2698-2706.DOI: 10.16085/j.issn.1000-6613.2016-2160

湿法脱硫废水液柱蒸发特性

洪永强^1,2, 陈桂芳^1,2, 马春元^1,2, 毛岩鹏^1,2, 杨德萍³, 刘晓³, 沈荣胜³

1 山东大学燃煤污染物减排国家工程实验室, 山东济南 250061;
2 山东省能源碳减排技术与资源化利用重点实验室, 山东济南 250061;
3 山东神华山大能源环境有限公司, 山东济南 250014

收稿日期:2016-11-22 修回日期:2017-02-27 出版日期:2017-07-05 发布日期:2017-07-05
通讯作者: 陈桂芳,讲师,主要从事氧化法及蒸发法的废水处理技术研究。
作者简介:洪永强(1992-),男,硕士研究生,主要从事污水的蒸馏特性分析及产物迁移规律研究。E-mail:hongyongqiang@163.com。
基金资助:
国家自然科学基金项目（21307075）。馏特性分析及产物迁移规律研究。

Evaporation characteristics of wet desulfurization wastewater in liquid column form

HONG Yongqiang^1,2, CHEN Guifang^1,2, MA Chunyuan^1,2, MAO Yanpeng^1,2, YANG Deping³, LIU Xiao³, SHEN Rongsheng³

1 National Engineering Lab for Coal-Fired Pollutants Emission Reduction, Shandong University, Jinan 250061, Shandong, China;
2 Shandong Provincial Key Lab of Energy Carbon Reduction and Resource Utilization, Shandong University, Jinan 250061, Shandong, China;
3 Shandong Shenhua Shanda Energy and Environment Company Limited, Jinan 250014, Shandong, China

Received:2016-11-22 Revised:2017-02-27 Online:2017-07-05 Published:2017-07-05

摘要/Abstract

摘要： 提出了一种利用烟气余热基于液柱蒸发浓缩脱硫废水的新型工艺，旨在降低脱硫废水零排放的成本。利用液柱蒸发试验台，研究了不同工艺参数下脱硫废水的液柱蒸发特性，得到了出口烟气湿饱和的边界条件。研究结果表明：在试验参数范围内，烟气裹挟速率、蒸发速率、压力损失范围分别为1.5~53.17kg/h、8.85~45.73kg/h、9~160Pa，出口烟气湿度、出口烟气温度、SO₂去除率范围分别为28.6%rh~99.6%rh、42.5~65.7℃、4.1%~61.0%。出口烟气中盐离子浓度的增加为烟气裹挟废水所致，蒸发过程中盐类不会迁移到烟气中。喷嘴直径为2.5mm时，出口烟气均呈湿饱和态；喷嘴直径为5mm时，蒸发塔内烟气流速大于5.0m/s时，出口烟气呈湿饱和态；喷嘴直径为10.6mm时，出口烟气均呈不饱和态。本实验的实施对于电厂的余热利用和废水零排放项目提供了参考和借鉴意义。

关键词: 湿法脱硫, 液柱蒸发, 余热利用, 进口烟气温度, 蒸发塔烟气流速, 喷嘴直径

Abstract: A new technology of concentrating desulfurization wastewater based on liquid column evaporation using the waste heat of flue gas was proposed in this study,which can reduce the cost of wet desulfurization wastewater zero discharge.The liquid column evaporation test-bed was established and the evaporation characteristics of wet desulfurization wastewater in liquid column form were discussed.The boundary conditions of wet-saturated outlet flue gas were determined.Experimental results showed that in selected range of operating parameters,the range of the carrier rate,evaporation speed and pressure loss are 1.5-53.17kg/h,8.85-45.73kg/h,9-160Pa,respectively.The range of the outlet flue gas humidity,outlet flue gas temperature and removal efficiency of SO₂ are 28.6%-99.6%,42.5-65.7℃,4.1%-61.03%,respectively.The salts do not migrate into the flue gas during liquid column evaporation.Meanwhile,the carrier of flue gas increases the concentration of salts in outlet flue.The outlet flue gas is wet-saturated when the nozzle diameter is 2.5mm,and it is the opposite when the nozzle diameter is 10.6mm.Only when flue gas speed is greater than 5.0m/s,the outlet flue gas is wet-saturated when the nozzle diameter is 5mm.This study provides experiences and references of power plant wet desulfurization wastewater with waste heat utilization and zero discharge.

Key words: wet desulfurization, liquid column evaporation, waste heat utilization, input flue gas temperature, flue gas speed, nozzle diameter

中图分类号:

洪永强, 陈桂芳, 马春元, 毛岩鹏, 杨德萍, 刘晓, 沈荣胜. 湿法脱硫废水液柱蒸发特性[J]. 化工进展, 2017, 36(07): 2698-2706.

HONG Yongqiang, CHEN Guifang, MA Chunyuan, MAO Yanpeng, YANG Deping, LIU Xiao, SHEN Rongsheng. Evaporation characteristics of wet desulfurization wastewater in liquid column form[J]. Chemical Industry and Engineering Progress, 2017, 36(07): 2698-2706.

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湿法脱硫废水液柱蒸发特性

Evaporation characteristics of wet desulfurization wastewater in liquid column form

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