柔性基材用水性UV导电油墨的研制

doi:10.16085/j.issn.1000-6613.2015.08.031

化工进展 ›› 2015, Vol. 34 ›› Issue (08): 3105-3109.DOI: 10.16085/j.issn.1000-6613.2015.08.031

柔性基材用水性UV导电油墨的研制

肖志坚¹, 屈贞财 ²

1 浙江东方职业技术学院工程技术系, 浙江温州325011;
2 河南牧业经济学院包装印刷系, 河南郑州 450046

收稿日期:2014-12-15 修回日期:2015-03-25 出版日期:2015-08-05 发布日期:2015-08-05
通讯作者: 肖志坚(1977—),男,副教授,硕士,华南理工大学访问学者,主要研究印刷包装材料和工艺。E-mail t7571231@163.com。
作者简介:肖志坚(1977—),男,副教授,硕士,华南理工大学访问学者,主要研究印刷包装材料和工艺。E-mail t7571231@163.com。
基金资助:
浙江省高职高专院校中青年专业带头人专业领军项目(LJ2013153)、浙江省科技厅2012年新产品试制计划(2012D60SA300006, 2012D60SA300008)及河南省2014年科技攻关项目(142102210441)。

Preparation of water-borne UV conductive ink for flexible substrates

XIAO Zhijian¹, QU Zhencai²

1 Department of Engineering Technology, Zhejiang Dongfang Vocational and Technical College, Wenzhou 325011, Zhejiang, China;
2 Department of Packaging and Printing, Henan University of Animal Husbandry & Economy, Zhengzhou 450046, Henan, China

Received:2014-12-15 Revised:2015-03-25 Online:2015-08-05 Published:2015-08-05

摘要/Abstract

摘要： 以水合肼(N₂H₄·H₂O)为还原剂,聚乙烯吡咯烷酮(PVP)为保护剂,通过液相还原硝酸银溶液制备纳米银粉。以制备的银粉纳米粒子为导电填料,以水性聚氨酯丙烯酸树脂为连接料,以乙醇和去离子水为溶剂,并辅以其他助剂,制备出水性UV导电油墨。经TEM表征和马尔文粒度仪测试,纳米银粉的平均粒径为5nm。最后用300目的涤纶丝网版在铜版纸基上印刷,在105℃下处理15min,用UV固化干燥后,测试墨层的电导率和附着力,并用SEM表征了墨层烧结后的形貌特征,结果表明:研制的用于柔性基材的水性UV导电油墨经190℃低温烧结2min,电导率为1.84×10⁴S/m,经3M胶带撕拉,墨层不发生脱落现象。

关键词: 液相, 还原, 纳米粒子, 溶剂, 水性UV导电油墨

Abstract: Nano-silver was prepared by chemical reduction method in silver nitrate solutions, using N₂H₄·H₂O as deoxidizer and polyvinylpyrrolidone (PVP) as polymeric protective agent. Prepared silver nanoparticles was added as filler, aqueous polyurethane acrylic resin was added as binder, ethanol and deionized water were added as the diluent, and a water-based UV conductive ink was prepared with other additives. The average diameter of the nano silver is 5 nm by SEM characterization and nano-size analyzer. Then prepared ink was printed on a coated paper with polyester screen plate in 300 mesh, processing under 105℃ for 15min, the conductivity of the ink and adhesion were tested after UV cured, the results show that water-based UV conductive ink for flexible substrates was sintered for 2 min at 190℃, and the conductivity was 1.84 × 10⁴S/m. There was no deinking occurred after tearing off with 3M adhesive tape.

Key words: liquid phase, reduction, nanoparticles, solvents, water-based UV conductive ink

中图分类号:

TS802.3

肖志坚, 屈贞财 . 柔性基材用水性UV导电油墨的研制[J]. 化工进展, 2015, 34(08): 3105-3109.

XIAO Zhijian, QU Zhencai. Preparation of water-borne UV conductive ink for flexible substrates[J]. Chemical Industry and Engineering Progree, 2015, 34(08): 3105-3109.

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柔性基材用水性UV导电油墨的研制

Preparation of water-borne UV conductive ink for flexible substrates

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