反相微乳液聚合制备丙烯酰胺类聚合物微球的研究进展

doi:10.16085/j.issn.1000-6613.2015.08.026

摘要/Abstract

摘要： 反相微乳液聚合技术具有稳定性好、固含量高、聚合速率快等优点而成为研究热点。本文系统地综述了近年来国内外应用反相微乳液聚合制备丙烯酰胺类聚合物微球的研究进展,概述了微乳液的基本理论及其特征,对稳定微乳液的制备进行了讨论;着重归纳了丙烯酰胺类的反相微乳液聚合,详述了聚合体系各组分的选择,同时探讨了影响聚合反应的因素,认为应研究新型表面活性剂以实现高单体浓度的聚合;介绍了聚合物微球在油田应用中提高采收率方面的应用现状。最后指出了其在深部调剖堵水领域存在的问题,以离子液体代替传统聚合体系组分制备集智能性、复合性、多功能性等综合性能于一体的聚合物微球是其未来发展方向之一。

关键词: 反相微乳液聚合, 聚合物, 制备, 深部调堵堵水, 石油

Abstract: Inverse microemulsion polymerization method with good stability, high solid content, and high polymerization rate has become research highlights. Research on the microspheres of acrylamide copolymers made via inverse microemulsion polymerization both at home and abroad was reviewed. Basic concepts and characteristics of microemulsion were introduced; and the preparation of a stable microemulsion was discussed. Inverse microemulsion polymerization of acrylamides was mainly summarized, the selection of each component of polymerization system was described in detail, and the influencing factors of polymerization were discussed, which can be concluded that new surfactants should be studied in order to realize high concentration in monomer polymerization. The applications of polymer microspheres for improving recovery efficiency in oilfield were introduced. Application problems in deep profile control/water shutoff were stated. To prepare polymer microspheres with the comprehensive performance of intelligence, compound, versatility by replacing the traditional polymerization system components with ionic liquids should be one of focuses in the future.

Key words: inverse microemulsion polymerization, polymers, preparation, deep profile control/water shutoff, petroleum

中图分类号:

TE39

杜荣荣, 刘祥. 反相微乳液聚合制备丙烯酰胺类聚合物微球的研究进展[J]. 化工进展, 2015, 34(08): 3065-3074.

DU Rongrong, LIU Xiang. Research on the microspheres of acrylamide copolymers made via inverse microemulsion polymerization[J]. Chemical Industry and Engineering Progree, 2015, 34(08): 3065-3074.

参考文献

[1] 王建莉, 王金良, 周晓楠, 等. 乳液聚合在油田开发应用中的研究进展[J]. 石油化工, 2013, 42(2): 243-247.
[2] Leong Y S, Candau F. Inverse microemulsion polymerization[J]. J. Phys. Chem., 1982, 86(13): 2269-2271.
[3] 李素莲, 陈尔凡. 丙烯酰胺-丙烯酸钠反相微乳液体系制备聚合物纳米粒子[J]. 化工进展, 2013, 32(9): 2180-2184, 2193.
[4] 杨志钢. 三次采油技术及进展[J]. 化工进展, 2011, 30(s1): 420-423.
[5] Schulman J H, Stoeckenius W, Prince L M. Mechanism of formation and structure of microemulsions by electron microscopy[J]. J. Phys. Chem., 1959, 63(10): 1677-1680.
[6] Clausse M, Nicolas M L, Zradba A, et al. Water/ionic surfactant/alkanol/hydrocarbon system: Influence of certain constitution and composition parameters upon realms of existence and transport properties of microemulsion type media. Rosano H L, Clausse M, ed. Microemulsion Systems[M]. New York: Marcel Dekker, 1987: 15-63.
[7] 白静, 冯彩霞, 杨青松, 等. Span80-Tween60/液体石蜡/AM/AA反相微乳液体系稳定性研究[J]. 石油勘探与开发, 2012, 41(9): 919-921.
[8] 张浩勤, 孟晓红, 邱建华, 等. 丙烯酰胺/对苯乙烯磺酸钠的反相微乳液聚合[J]. 郑州大学学报: 工学版, 2009, 30(3): 110-113.
[9] 魏欣, 加文君, 曹静, 等. 反相乳液法制备P(AM-AA-AMPS)聚合物微球[J]. 石油与天然气化工, 2014, 43(5): 539-542.
[10] Silva J M, Ortega-Gudiño P, Rabelero M, et al. Increasing solid content in latexes of polyacrylamide nanoparticles made by semi-continuous inverse heterophase polymerization[J]. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 2013, 50(6): 596-601.
[11] 滕大勇, 丁秋炜, 徐俊英, 等. 高固含量聚丙烯酰胺反相微乳液的制备[J]. 现代化工, 2011, 31(6): 58-61.
[12] 曹毅, 邹希光, 杨舒然, 等. JYC-1聚合物微球乳液膨胀性能及调驱适应性研究[J]. 油田化学, 2011, 28(4): 385-389.
[13] 司晓慧. 二甲基二烯丙基氯化铵丙烯酰胺的反相乳液和微乳液共聚合研究[D]. 济南: 山东大学, 2009.
[14] 马智国, 王永鹤, 康宏元, 等. 一种交联聚合物微球的合成及性能评价[J]. 西安石油大学学报: 自然科学版, 2014, 29(4): 96-100, 11.
[15] 张素霞, 王光华, 李蕾, 等. 新复合引发体系在反相微乳液中合成聚丙烯酰胺的研究[J]. 武汉科技大学学报: 自然科学版, 2006, 29(6): 563-566.
[16] 谭雪梅, 万涛, 胡俊燕, 等. 聚合物智能纳米凝胶的反相微乳液聚合法合成与性能[J]. 高分子材料科学与工程, 2014, 30(5): 20-24.
[17] 王凤贺, 卢时, 雷武, 等. 丙烯酰胺反相微乳液聚合体系及其微观结构[J]. 化工学报, 2006, 57(6): 1447-1452.
[18] Chang K T, Frampton H, Morgan J C. Composition and method for recovering hydrocarbon fluids from a subterranean reservoir: US, 6454003B1[P]. 2003-06-26.
[19] 赵勇, 何炳林, 哈润华. 反相微乳液中疏水缔合型聚丙烯酰胺的合成及其性能研究[J]. 高分子学报, 2000(5): 550-553.
[20] 陈文汨, 梁高杰, 胡琴. 丙烯酰胺反相微乳液的制备研究[J]. 当代化工, 2013, 42(9): 1218-1221, 1224.
[21] 赵楠. 油田用水凝胶微球的制备与评价[D]. 东营: 中国石油大学, 2009.
[22] 潘岳, 于小荣, 王海林. AM/AMPS/SSS三元反相乳液聚合体系稳定性研究[J]. 应用化工, 2012, 41(2): 321-323, 328.
[23] 赵楠, 葛际江, 张贵才, 等. 反相微乳液聚合制备聚丙烯酰胺水凝胶微球研究[J]. 西安石油大学学报: 自然科学版, 2008, 23(6): 78-82, 85.
[24] Xie L, Shao Z Q, Wang H Q. Polymerization of acrylamide inverse microemulsion initiated directly by UV radiation[J]. E-Polymers, 2011, 11(1): 874-882.
[25] 张雁, 汪庐山, 王涛, 等. 新型吸水树脂微球的制备及封堵性能研究[J]. 石油钻采工艺, 2012, 34(6): 93-96.
[26] 段文猛, 邓清月, 李爽, 等. 反相乳液聚合制备高相对分子质量和高阳离子度的聚丙烯酰胺[J]. 石油化工, 2011, 40(9): 968-973.
[27] Candau F, Pabon M, Anquetil J Y. Polymerizable microemulsions: some criteria to achieve an optimal formulation[J]. Colloids and Surfaces A, 1999, 153: 47-59.
[28] 王颖, 苏宝根, 邢华斌, 等. 离子液体在微乳液聚合中的应用[J]. 现代化工, 2014, 34(2): 38-43.
[29] Thurecht K J, Gooden P N, Goel S, et al. Free-radical polymerization in ionic liquids[J]. Macromolecules, 2008, 41(8): 2814-2820.
[30] Dhanya S, Bahadur D, Kundu G C, et al. Maleic acid incorporated poly-(N-isopropylacrylamide) polymer nanogels for dual-responsive delivery of doxorubicin hydrochloride[J]. Eur. Polym. J., 2013, 49(1): 22-32.
[31] 徐运欢, 郑成, 林璟, 等. 新型含氟季铵盐表面活性剂的合成与表面性能[J]. 化工进展, 2014, 33(2): 439-444, 452.
[32] 朱明月, 乔卫红, 毕晨光, 等. 乳液聚合中的反应型乳化剂研究进展[J]. 化工进展, 2006, 25(5): 490-494, 501.
[33] 胡应模. 可聚合非离子型表面活性剂的合成及其性能[J]. 应用化学杂志, 2010, 27(4): 409-412.
[34] 范敏. 新型微乳化剂的研制及微乳化油性能研究[D]. 南京: 南京理工大学, 2014.
[35] 孙浩. 离子液体与正丁酸对微乳液相行为和增溶能力的影响[D]. 济南: 山东师范大学, 2013.
[36] 王婷. 过硫酸钾-银氨复合引发烯类单体快速乳液聚合的研究[D]. 武汉: 武汉理工大学, 2011.
[37] 王磊. 提高采收率用聚丙烯酰胺微球的制备与评价[D]. 东营: 中国石油大学, 2010.
[38] 宋岱峰. 功能聚合物微球深部调剖技术研究与应用[D]. 青岛: 山东大学, 2013.
[39] 刘伟, 李兆敏, 李宾飞, 等. 聚合物微球注入参数优化及运移规律研究[J]. 应用基础与工程科学学报, 2011, 19(5): 886-893.
[40] 曾庆桥, 孟庆春, 刘媛, 等. 聚合物微球深部调驱技术在复杂断块油藏的应用[J]. 石油钻采工艺, 2012, 34(5): 91-94.
[41] 鲁光亮, 王健, 鲁道素, 等. 孔喉尺度调堵剂微球在高温高盐条件下的性能[J]. 新疆石油地质, 2009, 30(6): 748-750.
[42] 袁文芳, 刘秀珍, 韦海洋, 等. 聚合物活性微球调驱在文10东块油藏的研究及应用效果[J]. 内蒙古石油化工, 2010(12): 122-125.
[43] 涂伟霞, 夏海虹. 磁性聚合物复合微球调剖堵水剂研究[J]. 石油与天然气化工, 2012, 41(5): 504-507, 540.
[44] 王越, 孙卫, 张奉, 等. 聚合物微球和表面活性剂结合提高采收率实验研究: 以沙埝油田H区块为例[J]. 石油地质与工程, 2011, 25(5): 105-108.
[45] Chang K T, Frampton H, Morgan J C. Composition for recovering hydrocarbon fluids from a subterranean reservoir: US, 2007/7300973[P]. 2007-11-27.
[46] Chauveteau G, Tabary R, Renard M, et al. Controlling in-situ genlation of polyacrylamides by zirconium for water shutoff[C]. US: SPE 50752, 1999.
[47] Choi S K, Ermel Y M, Bryant S L, et al. Transport of a pH-sensitive polymer in porous media for novel mobility-control application[C]. US: SPE 99656, 2006.
[48] Zaitoun A, Tabary R, Rousseau D, et al. Using microgels to shut off water in a gas storage well[C]. US: SPE 106042, 2007.
[49] Sheng J J. Modern Chemical Enhanced Oil Recovery: Theory and Practice[M]. Boston: Gulf Professional Publishing, 2011: 122-129.
[50] Rashidi M. Physico-chemistry characterization of sulfonated polyacrylamide polymers for use in polymer flooding[D]. Bergen: University of Bergen, 2010.