二氧化钛纳米管的制备、改性及应用

doi:10.16085/j.issn.1000-6613.2015.05.022

摘要/Abstract

摘要： 二氧化钛纳米管因其特殊的形貌和高度有序的特性成为了目前研究的热点之一.本文系统回顾了近年来有关二氧化钛纳米管的相关研究,着重阐述了二氧化钛纳米管的制备方法,主要包括模板法、阳极氧化法、水热法;在此基础上,详细论述了掺杂、复合等对二氧化钛纳米管进行改性的方法;并简要介绍了二氧化钛纳米管及其复合材料在环境、能源等领域的应用.最后,展望了二氧化钛纳米管的主要研究方向是对形成机理、管形貌调控、表面改性等方面做进一步研究,以期为后续的研究提供参考.

关键词: 粉体技术, 纳米材料, 制备, 改性, 复合材料

Abstract: Titanium dioxide nanotubes have been intensively concerned and studied in recent years due to their special morphology and highly ordered property. This paper reviewed recent advances in titanium dioxide nanotubes. Three kinds of preparation methods were discussed,including template synthesis,electrochemical anodization and hydrothermal synthesis. On this basis,it described the modification methods of titanium dioxide nanotubes in detail,including doping and compositing. The applications of titanium dioxide nanotubes and composites in the field of environment and energy were introduced briefly. Finally,the future studies on the formation mechanism,morphology control and modification of titanium dioxide nanotubes were proposed.

Key words: powder technology, nanomaterials, preparation, modification, composites

中图分类号:

TB383

王俏, 王威, 崔福义, 邵鹏辉, 何皎洁. 二氧化钛纳米管的制备、改性及应用[J]. 化工进展, 2015, 34(05): 1311-1316,1322.

WANG Qiao, WANG Wei, CUI Fuyi, SHAO Penghui, HE Jiaojie. Preparation,modification and application of titanium dioxide nanotubes[J]. Chemical Industry and Engineering Progree, 2015, 34(05): 1311-1316,1322.

参考文献

[1] Yoon J,Jung S,Kim J. Photocatalytic effects for the TiO₂-coated phosphor materials[J]. Materials Chemistry and Physics,2011,125(3):342-346.

[2] 王福祥. 二氧化钛纳米管的制备、改性及其光催化性能研究[D]. 长沙:湖南大学,2012.

[3] Li X F,Zhao Y,Jiao Q Z,et al. Preparation of one-dimensional titanate nanomaterials using different titania sources[J]. Acta Physico-Chimica Sinica,2011,27(8):1996-2000.

[4] 付敏,原鲜霞,马紫峰. TiO₂纳米管制备及其应用研究进展[J]. 化工进展,2005,24(1):42-46.

[5] 刘非拉,肖鹏,周明,等. 二氧化钛纳米管阵列的制备、改性及应用[J]. 无机化学学报,2012,28(5):861-872.

[6] 孔祥荣,彭鹏,孙桂香,等. 二氧化钛纳米管的研究进展[J]. 化学通报,2007(1):8-13.

[7] Hoyer P. Formation of a titanium dioxide nanotube array[J]. Langmuir,1996,12:1411-1413.

[8] Jung J H,Kobayashi H,van Bommel K J C,et al. Creation of novel helical ribbon and double-layered nanotube TiO₂ structures using an organogel template[J]. Chemistry Materials,2002,14:1445-1447.

[9] 李欢欢,陈润锋,马琮,等. 阳极氧化法制备二氧化钛纳米管及其在太阳能电池中的应用[J]. 物理化学学报,2011,27(5):1017-1025.

[10] Gong D,Grimes C A,Varghese O K,et al. Titanium oxide nanotube arrays prepared by anodic oxidation[J]. Journal of Materials Research,2001,16(12):3331-3334.

[11] 廖建军,李士普,曹献坤,等. 有序TiO₂纳米管阵列光催化性能研究进展[J]. 化工进展,2011,30(9):2003-2012.

[12] 龚青,尹荔松,郭智博,等. 阳极氧化法制备氧化钛纳米管阵列及光催化降解氯胺磷[J]. 中南大学学报,2011,42(11):3270-3276．

[13] 刘海津,李通,刘国光,等. 适于工业应用的TiO₂纳米管的阳极氧化法制备[J]. 环境科学学报,2012,32(9):2176-2181.

[14] Macak J M,Tsuchiya H,Ghicov A,et al. TiO₂ nanotubes:Self-organized electrochemical formation,properties and applications[J]. Current Opinion in Soild State and Materials Science,2007,11:3-18.

[15] 管东升,方海涛,逯好峰,等. 阳极氧化TiO₂纳米管阵列的制备与掺杂[J]. 化学进展,2008,20(12):1868-1879.

[16] Albu S P,Kim D,Schmuki P. Growth of aligned TiO₂ bamboo-type nanotubes and highly ordered nanolace[J]. Angewandte Chemie International Edition,2008,120(10):1942-1945.

[17] Zhang X W,Pan J H,Du A J,et al. Combination of one-dimensional TiO₂ nanowire photocatalytic oxidation with microfiltration for water treatment[J]. Water Research,2009,43:1179-1186.

[18] Kasuga T,Hiramatsu M,Hoson A,et al. Formation of titanium oxide nanotube[J]. Langmuir,1998,14(12):3160-3163.

[19] 梁建,马淑芳,韩培德,等. 二氧化钛纳米管的合成及其表征[J]. 稀有金属材料与工程,2005,34(2):287-290.

[20] 钮金芬,姚秉华,彭超,等. 锐钛矿纳米管的微波水热制备及其吸附-光催化性能[J]. 硅酸盐学报,2013,41(1):83-88.

[21] 李纲,刘中清,张昭,等. 水热法制备TiO₂纳米管阵列[J]. 催化学报,2009,30(1):37-42.

[22] Lee K,Mazare A,Schmuki P. One-dimensional titanium dioxide nanomaterials:Nanotubes[J]. Chemical Reviews,2014,114:9385-9454.

[23] Shen Y Q,Wang D P,Ye S. Synthesis and characterization of TiO₂ nanotube arrays with Ag nanoparticles[J]. Journa of the Chinese Ceramic Society,2014,42(3):402-408.

[24] Wang W,Lu C,Ni Y,et al. Preparation and characterization of visible-light-driven N-F-Ta tri-doped TiO₂ photocatalysts[J]. Applied Surface Science,2012,258(22):8696-8703.

[25] 肖羽堂,李志花,徐双双. 非金属元素掺杂二氧化钛纳米管的研究进展[J]. 化工进展,2010,29(7):1235-1240.

[26] Asahi R,Monkawa T,Ohwaki T,et al. Visible-light photocatalysis in nitrogen-doped titanium oxides[J]. Science,2001,293(5528):269-271.

[27] 王泽高,郑树楠,贾春阳,等. Cu掺杂TiO₂及其纳米管的制备、表征与光催化性能[J]. 无机化学学报,2010,26(5):875-878.

[28] Macak J M,Tsuchiya H,Schmuki P,et al. TiO₂ nanotubes:Self-organized electrochemical formation properties and applications[J]. Solid State and Materials,2007,11:3-18.

[29] Shi Jian,Li Jun,Cai Yunfa. Fabrication of C,N-codoped TiO₂ nanotube photocatalysts with visible light response[J]. Acta Physico-Chimica Sinica,2008,24(7):1283-1286.

[30] Su Yaling,Zhang Xingwang,Zhou Minghua,et al. Preparation of high efficient photoelectrode of N-F-codoped TiO₂ nanotubes[J]. Journal of Photochemistry and Photobiology A:Chemistry,2008,194:152-160.

[31] Li X,Chen Z M,Shi Y C,et al. Preparation of N,Fe co-doped TiO₂ with visible light response[J]. Powder Technology,2011,207:165-169.

[32] 吴奇,苏钰丰,孙岚,等. Fe、N共掺杂TiO₂纳米管阵列的制备及可见光光催化活性[J]. 物理化学学报,2012,28(3):635-640.

[33] 赵芳. Ag、N共掺杂改性负载型纳米二氧化钛的制备、表征及光催化性能的研究[D]. 银川:宁夏大学,2013.

[34] 孙岚,李静,庄慧芳,等. TiO₂纳米管阵列的制备、改性及其应用研究进展[J]. 无机化学学报,2007,23(11):1841-1850.

[35] 李海龙,罗武林,陈涛,等. 载Ag二氧化钛纳米管的制备及其光催化性能[J]. 物理化学学报,2008,24(8):1383-1386.

[36] 包华辉,徐铸德,殷好勇,等. TiO₂纳米管负载Ag、Au、Pt纳米粒子的微波合成与表征[J]. 无机化学学报,2005,21(3):374-378.

[37] 李印华. 光敏气敏性半导体纳米材料的制备及性能研究[D]. 大连:大连理工大学,2011.

[38] Kim J C,Choi J,Lee Y B,et al. Enhanced photocatalytic activity in composites of TiO₂ nanotubes and CdS nanoparticles[J]. Chemical Communications,2006,48:5024-5026.

[39] Chen S,Paulose M,Grimes C A,et al. Electrochemically synthesized CdS nanoparticles-modified TiO₂ nanotube-array photoelectrodes:Preparation,characterization,and application to photoelectrochemical cells[J]. Journal of Photochemistry and Photobiology A:Chemistry,2006,177:177-184.

[40] Xie Yibing. Photoelectrochemical application of nanotubular titania photoanode[J]. Electrochimica Acta,2006,51:3399-3406.

[41] Macak J M,Zlamal M,Schmuki P,et al. Self-organized TiO₂ nanotube layers as highly efficient photocatalysts[J]. Small,2007,3(2):300-304.

[42] Varghese O K,Gong D,Grimes C A,et al. Hydrogen sensing using tiatnia nanotubes[J]. Sensors and Actuators B,2003,93:338-344.

[43] Grimes C A,Ong K G,Varghese O K,et al. A sentinel sensor network for hydrogen sensing[J]. Sensors,2003,3:69-82.

[44] 袁宝. TiO₂纳米管阵列可控制备及其改性研究[D]. 合肥:合肥工业大学,2013.

[45] Fujishima A,Honda K. Photolysis-decomposition of water at the surface of an irradiated semiconductor[J]. Nature,1972,238:37-38.

[46] Bae S,Shim E,Yoon J,et al. Photoanodic and cathodic role of anodized tubular titania in light-sensitized enzymatic hydrogen production[J]. Journal of Power Sources,2008,185:439-444.

[47] Mor Gopal K,Shankar Karthik,Paulose Maggie,et al. Enhanced photocleavage of water using titania nanotube arrays[J]. Nano Letters,2005,5(1):191-195.

[48] Regan B O,Gratzel M. A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO₂[J]. Nature,1991,353:737-739.

[49] Zhang Jing,Peng Wenqin,Chen Zhenhua,et al. Effect of cerium doping in the TiO₂ photonode on the electron transport of dye-sensitized solar cells[J]. The Journal of Physical Chemistry C,2012,116:19182-19190.

[50] Paulose Maggie,Shankar Karthik,Varghese Oomman K,et al. Backside illuminated dye-sensitized solar cells based on tiatnia nanotube array electrodes[J]. Institute of Physics Publishing,2006,17:1446-1448.