CO2水合物浆在水平圆管中的传热特性

doi:10.16085/j.issn.1000-6613.2015.01.012

化工进展 ›› 2015, Vol. 34 ›› Issue (1): 69-74.DOI: 10.16085/j.issn.1000-6613.2015.01.012

CO₂水合物浆在水平圆管中的传热特性

刘妮, 由龙涛, 张亚楠, 柳秀婷

上海理工大学能源与动力工程学院, 上海 200093

收稿日期:2014-04-14 修回日期:2014-05-05 出版日期:2015-01-05 发布日期:2015-01-05
通讯作者: 刘妮(1974-),女,博士,副教授。E-mail ni-liu@hotmail.com。
作者简介:刘妮(1974-),女,博士,副教授。E-mail ni-liu@hotmail.com。
基金资助:
国家自然科学基金(50706028)及上海市教委科研创新项目(12YZ106)。

Heat transfer characteristics of CO₂ hydrate slurry in horizontal circular tube

LIU Ni, YOU Longtao, ZHANG Yanan, LIU Xiuting

School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China

Received:2014-04-14 Revised:2014-05-05 Online:2015-01-05 Published:2015-01-05

摘要/Abstract

摘要： 在CO₂水合物浆流动传热特性测试实验系统上,采用套管式电加热的方法对CO₂水合物浆进行了分解实验,并对CO₂水合物浆的流动传热特性进行了分析。对CO₂水合物浆的相变特性进行了研究,得到CO₂水合物浆的相变温度在8～12℃。研究了在固相体积分数为13.2%以及流速为0.45m/s的条件下CO₂水合物浆在内径为8mm的水平不锈钢管中的传热特性,计算得到CO₂水合物浆在不锈钢水平圆管中的对流传热系数为1500～1800 W/(m²·K),并且其在流动传热过程中呈现先增大随后趋向平稳的趋势,在水合物的相变区相应的对流传热系数表现最大。研究了分解加热功率对管壁温和对流传热系数的影响,发现加热功率对管壁温度的影响较强。在实际应用中可利用CO₂水合物浆的相变作用来增强传热,提高传热效率。

关键词: 二氧化碳, 水合物浆, 传热, 相变

Abstract: The flow and heat transfer characteristics of CO₂ hydrate slurry in horizontal circular tube was studied experimentally. The dissociation properties of CO₂ hydrate slurry was investigated using the electric heating water around the tube method. The analysis of phase transition and heat transfer characteristics of CO₂ hydrate slurry indicated that the phase transition temperature of CO₂ hydrate slurry was at 8—12℃. The heat transfer characteristics of CO₂ hydrate slurry with 13.2%(vol) solid fraction in a 8 mm straight stainless steel horizontal circular tube were studied at the flow rate of 0.45 m/s in a dynamic loop. The corresponding local convective heat transfer coefficient in horizontal circular tube increased and then stayed constant and the range was calculated to be 1500—1800 W/(m²·K). The results showed that the largest corresponding convective heat transfer coefficient appeared in the phase transition field of CO₂ hydrate slurry. The influences of heating power on tube wall temperature and the convective heat transfer coefficient were discussed respectively. It was discovered that the heating power had a strong effect on wall temperature. The phase transition effect of CO₂ hydrate slurry can be used to enhance the heat transfer and increase the heat transfer efficiency in related applications.

Key words: carbon dioxide, hydrate slurry, heat transfer, phase transition

中图分类号:

TQ031

刘妮, 由龙涛, 张亚楠, 柳秀婷. CO₂水合物浆在水平圆管中的传热特性[J]. 化工进展, 2015, 34(1): 69-74.

LIU Ni, YOU Longtao, ZHANG Yanan, LIU Xiuting. Heat transfer characteristics of CO₂ hydrate slurry in horizontal circular tube[J]. Chemical Industry and Engineering Progree, 2015, 34(1): 69-74.

参考文献

[1] Melinder A,Granryd E. Using property values of aqueous solutions and ice to estimated ice concentrations and enthalpies of ice slurries[J]. International Journal of Refrigeration,2005,28(1):13-19.

[2] Bel O,Lallemand A. Study of a two-phase secondary refrigerant 2:Experimental analysis of thermal and rheological behavior[J]. International Journal of Refrigeration,1999,22(3):175-187.

[3] Knodel B D,France D M,Choi U S,et al. Heat transfer and pressure drop in ice-water slurries[J]. Applied Thermal Engineering,2000,20(7):671-685.

[4] 谢应明,谢振兴,范兴龙. CO₂ 水合物浆作为空调载冷剂的流动和传热特性研究进展[J]. 化工进展,2014,33(1):10-15.

[5] 刘妮,张国昌,罗杰斯 R E. 二氧化碳气体水合物生成特性的实验研究[J]. 上海理工大学学报,2007,29(4):405-408.

[6] Anthony Delahaye,Laurence Fournaison,Salem Jerbi,et al. Rheological properties of CO₂ hydrate slurry flow in the presence of additives[J]. Industrial & Engineering Chemistry Research ,2011,50:8344-8353.

[7] 陈伟军,刘妮,肖晨,等. CO₂水合物浆在蓄冷空调中的应用前景[J]. 制冷学报,2012,33(3):1-8.

[8] Anthony Delahaye,Laurence Fournaison,Sandrine Marinhas,et al. Rheological study of CO₂ hydrate slurry in a dynamic loop applied to secondary refrigeration[J]. Chemical Engineering Science,2008,63:3551-3559.

[9] Jin Hu,Osmann Sari. Experimental study on flow behavior of CO₂ hydrate slurry[J]. IIR Proceedings Series Refrigeration Science and Technology,2010,5:69-79.

[10] Inaba H,Miyahara S,Takeda K. Fundamental study on continuous ice making in a circular tube by flowing water solution[J]. Trans. of JSME:Series B,1995,61(589):3296-3303.

[11] 刘妮,戴海凤,余宏毅,等. CO₂水合物浆在水平圆管中的流动特性[J]. 化工学报,2014,65(2):550-554.

[12] 宋文吉,肖睿,董凯军,等. TBAB包络化合物浆水平管内的传热特性研究[J]. 工程热物理学报,2009,30(9):1502-1504.

[13] 肖睿,何世辉,黄冲,等. 四丁基溴化铵包络化合物浆在铜管内的对流传热特性[J]. 化工学报,2007,58(9):2205-2210.

[14] 马志伟,张鹏,王如竹. 水合物浆体在水平直管中的流动传热特性研究[J]. 化工学报,2010,31(8):1398-1402.

[15] Ma Z W,Zhang P,Wang R Z. Forced flow and convective melting heat transfer of clathrate hydrate slurry in tubes[J]. International Journal of Heat and Mass transfer,2010,53:3745-3757.

[16] Osmann Sari,Jin Hu,Frederic Brun,et al. In-situ study of the thermal properties of hydrate slurry by high pressure DSC[C]//International Congress of Refrigeration:Beijing,2007.

[17] 王武昌,樊栓狮,梁德青,等. 水合物浆在管道中的流动安全[J]. 化工学报,2008,59(6):1545-1550.

CO₂水合物浆在水平圆管中的传热特性

Heat transfer characteristics of CO₂ hydrate slurry in horizontal circular tube

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