Please wait a minute...
Table of Content
05 December 2009, Volume 28 Issue 12
    特约评述
    Techno-economic assessment method under uncertainty in coal chemical industry
    ZHOU Wenji,ZHU Bing,FEI Weiyang
    2009, 28(12):  2087. 
    Abstract ( 2252 )  
    Related Articles | Metrics
    To develop coal chemical industry would enable taking full advantage of China’s coal resource, and has great significance for national energy security. However, huge uncertainty is faced by coal chemical industry, which is not only reflected by deepening market-oriented reform but also by constraint from policies regarding environmental and climate issues. This paper introduces the application of real options analysis (ROA) into techno-economic appraisal of energy utilization technologies, involving analysis of uncertain factors, modeling and solving techniques. Based on review of current research status, in combination with development background for China’s coal chemical industry, the necessity and feasibility of application of the ROA theory is analyzed, indicating that the ROA theory has much potential for application.
    化工过程与装备
    Progress of supported liquid membrane with ionic liquids
    SHEN Jiangnan,RUAN Huimin,WU Dongzhu,ZHANG Jie
    2009, 28(12):  2092. 
    Abstract ( 2030 )  
    Related Articles | Metrics
    Supercritical fluidsroom temperature ionic liquidsCO2 expanded liquids and wateras well as their mixtures are currently regarded as green solvents. As substitution for volatile organic solventionic liquids can be applied in separation processchemical reactionelectrochemistryand so on. This review summarizes the recent progress in preparation method of supported liquid membrane with ionic liquidsand the effect of the structure of ionic liquids and support membrane on the stability of the supported liquid with ionic liquids. In additiontheir application in organic/organic separationgas separationand coupling separation with reaction are also reviewed. The supported liquid membrane with ionic liquids will be one of the ways for clean production.
    Research progress in the separation and purification of bio-oil
    WANG Jinghua,CUI Hongyou,LI Zhihe,YI Weiming
    2009, 28(12):  2099. 
    Abstract ( 2073 )  
    Related Articles | Metrics
    The recent research progress in bio-oil refining is reviewed,including distillation,solvent extraction,chromatography,membrane separation and supercritical extraction. Distillation under ambient or reduced pressure can be used in bio-oil separation,while it suffers from a problem in the thermal sensitivity of bio-oil. On the other hand,molecular distillation is more suitable for the bio-oil refining. Some species can be extracted from bio-oil via solvent extraction,while the major disadvantage of which is the difficulty in the separation of solvent with the extract(s) as well as the low extraction selectivity. Exploring or exploiting peculiar extracting agents with specific functional groups,which can uniquely interact with the desired component in bio-oil,might be an interesting research topic in the future. Chromatography can effectively separate and purify bio-oil,but its low throughput makes it only suitable for high value-added compounds. Supercritical CO2 extraction is potentially a good way in refining bio-oil due to its nearby ambient operation temperature. In addition,supercritical CO2 extraction does not need a process of back-extraction. Fundamental research and integrated technique exploitation for bio-oil refining may be important research topics in the future.
    Research progress in flat plate heat pipes
    CHEN Jinjian,WANG Shuangfeng
    2009, 28(12):  2105. 
    Abstract ( 2997 )  
    Related Articles | Metrics

    Flat plate heat pipe is one of the available technology to deal with the high density electronic cooling problem. This paper introduces the working principle of flat plate heat pipeand the research in pipe makingcapillary structurelayout of heat source and numerical simulation is comprehensively reviewed. Future development for flat plate heat pipe is predicted.

    Film-invertion with configuration stuffing for dehumidifier
    JI Zhiguo,CUI Xiaoyu,XIN Shiyu
    2009, 28(12):  2109. 
    Abstract ( 1858 )  
    Related Articles | Metrics
    A new type of stuffing with film-invertion configuration combined with plate falling film technique for dehumidifier is proposed. With the designed experimental equipmentthe dehumidification performance of this new type of film-falling stuffing was evaluated under different volume fluxinlet concentration and temperature of the solution as well as different volume fluxinlet temperature and moisture content of air. These results provides some bases for the investigationindustrial design and application of dehumidification stuffing with film–invertion falling film techniqueand also provides some help in the development of compact dehumidifier with high efficiency.
    Adsorption separation of CO2, CH4 and N2 on β-zeolite with different SiO2/Al2O3 ratios
    XU Xiaoliang,ZHAO Xingxiang,SUN Linbing,LIU Xiaoqin
    2009, 28(12):  2116. 
    Abstract ( 1903 )  
    Related Articles | Metrics
    The adsorption separation of CO2,CH4 and N2 was studied via volumetric measurements of β-zeolite samples with different SiO2/Al2O3 ratios at 273 and 303 K. Results showed that all the obtained adsorption isotherms are well correlated with the Langmuir-Freundlich model. For a certain sample,the adsorption capacity for CO2 is much higher than that for CH4 and N2. The adsorption capacity for CO2 increases with the decrease in SiO2/Al2O3 ratio under same temperature and pressure. The Henry law′s constant and adsorption equilibrium selectivity of CO2,CH4,and N2 on different β-zeolite samples were calculated via Virial equation,showing that the β-zeolite samples have higher equilibrium selectivity for CO2 over N2 and CH4. The selectivity of CO2 over N2 and CH4 increases with the decrease in SiO2/Al2O3 ratio. Therefore,the β-zeolite sample with a low SiO2/Al2O3 ratio is a good candidate for the separation of carbon dioxide from its mixture with methane and nitrogen. The isosteric adsorption heat for CO2,CH4 and N2 calculated by Clausius-Clapeyron equation is independent with the increase of adsorption loading,which indicates thatβ-zeolite is an energetically homogenous adsorbent.
    能源加工与技术
    Recent advances in the study of sodium borohydride hydrolysis for pure hydrogen supply to PEM fuel cell
    WANG Yuxiao
    2009, 28(12):  2122. 
    Abstract ( 2706 )  
    Related Articles | Metrics
    Sodium borohydride contains hydrogen as high as 10.6%and it is safeno fire and explosion dangerand portable. This hydrogen supply system has the features of simple structurefast startingand adjustable hydrogen production speed. Thereforesodium borohydride is a very promising hydrogen carrier and a perfect medium for pure hydrogen supply to proton exchange membrane fuel cell (PEMFC). In factthe hydrolysis of sodium borohydride for hydrogen supply to PEMFC is in the way to real application. This review summarizes the recent advances in this hydrogen generation system including catalystsreactors and purification methodsand the direction for sequent research is also discussed.
    Development and application of a simulation model for fuel ethanol production system
    ZHANG Zhiqiang,HU Shanying,CHEN Dingjiang,SHEN Jingzhu,DU Fengguang
    2009, 28(12):  2129. 
    Abstract ( 1800 )  
    Related Articles | Metrics
    Based on the analysis of a typical fuel ethanol production systemand the disadvantage of current simulation models as well as the modelling difficulties caused from system characteristicse.g. non-linear and complexitya simulation platform for fuel ethanol production system is developed using VC # programming tools and SQLSERVE. This developed simulation platform can simulate the actual fuel ethanol production processand can carry out a full-range system analysis of industrial ecology from the aspects of material flowenergy flowwater flow and value flow etc. Finallythe functionality of this developed simulation platform was verified by using two cases happened in real production.
    Preparation of biodiesel with monomer acid
    LIU Xiaofeng,CAO Xiaoyan
    2009, 28(12):  2135. 
    Abstract ( 1780 )  
    Related Articles | Metrics
    An esterification reaction of monomer acid with methanol using p-toluenesulfonic acid as catalyst for the preparation of biodiesel was studied. The process variables that influence the esterification of monomer acid, such as catalyst concentration, molar ratio of methanol to acid, reaction time and reaction temperature, were investigated and optimized. The yield of methyl esters reached to 98.25% under the conditions of reaction temperature of 60 , methanol/acid molar ratio of 31, and catalyst dosage of 6% for 3 h of reaction. The produced biodiesel was found to exhibit fuel properties within the limits prescribed by the latest American Standards for Testing Material (ASTM) and 0# diesel oil.
    工业催化
    Application of mesoporous molecular sieves SBA-15 in catalysis
    HUANG Yong,CHEN Weiqing,SHI Qiujie,SUN Wuchen
    2009, 28(12):  2140. 
    Abstract ( 2204 )  
    Related Articles | Metrics
    This paper summarizes the recent application progress of mesoporous molecular sieves SBA-15 in catalysis mainly in loading solid acid catalystsmetals and metal oxidesas well as chiral catalysts. The future developments of SBA-15 in catalysis are proposed.
    Progress in the nitrogen chemistry during the regeneration of fluid catalytic cracking catalyst
    YU Daoyong,XU Hai,QUE Guohe
    2009, 28(12):  2146. 
    Abstract ( 2122 )  
    Related Articles | Metrics
    The nitrogen chemistry during the regeneration of coked fluid catalytic cracking (FCC) catalyst is reviewedincluding the main types and formation pathways of the nitrogen compounds on the coked FCC catalystthe transformation pathways of these nitrogen compounds and nitrogen intermediates during the regeneration process. Strategies to control the NOx emission from FCC regenerator are also discussed.
    Catalysts for the preparation of hexafluoroacetone through hexafluoropropylene oxidation in gas phase
    ZHANG Guoli,YANG Hui’e,ZHANG Wenqing,LI Feng,LI Huili
    2009, 28(12):  2152. 
    Abstract ( 2051 )  
    Related Articles | Metrics
    Progress in the catalysts for the synthesis of hexafluoroacetone through hexafluoropropylene oxidation in gas phase is summarized. Influences of catalyst preparation methods, varieties, structure and properties are reviewed, and the formation of active component and reaction mechanism are also introduced. It is indicated that the problems for hexafluoropropylene oxidation in gas phase are the much lower conversion of hexafluoropropylene and the much lower selectivity for hexafluoroacetone as well as the poor catalyst stability. It is presented that to develop new catalyst system in lowering the reaction activation energy and new promoter in maintaining the stability of active component are the main aims in future research works.
    Preparation of polyethylene with bimodal distribution catalyzed by complex catalyst of Ziegler-Natta with metallocene
    WANG Gang,HE Shuyan,CHANG Yuhong
    2009, 28(12):  2156. 
    Abstract ( 2259 )  
    Related Articles | Metrics
    ZM complex catalyst was prepared by impregnating metallocene catalyst on supported Ziegler-Natta catalyst, its catalytic performance in ethylene polymerization toward bimodal polyethylene in a single reactor was investigated. The influence of the amount of metallocene, polymerization temperature, the amount of co-catalyst and 1-hexene on the catalytic activity was studied. The complex catalyst exhibits high catalytic activity for ethylene polymerization, and the MI values of the polymers are obviously relevant to the polymerization temperature, the mol ratio of Al/M and 1-hexene content in feed. The structure and properties of the obtained polymers were characterized by GPC and FT-IR, which revealed that the polymers featured bimodal distribution with MWD at the range of 18 to 155, and the incorporation of 1-hexene within the polymer chain increased with the increase of the co-monomer content in feed.
    Effect of solvent on the structure and performance of CuZnAl catalyst prepared by complete liquid phase technology
    GAO ZhihuaLI JunfangHUANG WeiYIN LihuaXIE Kechang
    2009, 28(12):  2160. 
    Abstract ( 1936 )  
    Related Articles | Metrics
    Al-based slurry catalysts using pseudo-boehmite as aluminum source were prepared by complete liquid phase technology, and the catalyst precursors Cu(NO3)2 and Zn(NO3)2 were dissolved in different solvents. The as-prepared catalysts were characterized by means of X-ray diffraction, N2 adsorption, Xray photoelectron spectroscopy and H2 temperature-programmed reduction. Performance of the catalysts was evaluated in a slurry reactor for the synthesis of dimethyl ether (DME) from syngas. Results indicated that different solvent has significant influence on the catalyst structure and performance. Using glycol as solvent, the catalyst shows a stable phase structure and largest pore diameter and pore volume, meanwhile, the catalyst has more reducible copper and can be easily reduced. Therefore, the catalyst shows enhanced CO conversation while keeping the DME selectivity unchanged.
    Acid treatment of support on the performance of catalysts combined with heat storage function
    WANG Jing,XU Li,FU Mingli,HUANG Bichun,YE Daiqi
    2009, 28(12):  2164. 
    Abstract ( 1838 )  
    Related Articles | Metrics
    The effect of support treatment with HNO3 on the performance of the self-made catalysts combined with heat storage function was studied. The catalysts were characterized by DSC and XRD techniquesand the specific surface area were calculated using BET theoretical models according to their nitrogen adsorption isotherms. Besidesthe application characteristics of the catalysts combined with heat storage function in reverse flow reactor was investigated. It was found that the heat storage function of the catalysts was almost unaffected with no change in crystalline phase after acid treatment. While the catalytic activity of the catalysts was obviously enhanced after acid treatmenttoluene conversion reached to 97.42% at 400 at steady-statewhich was increased by about 5% as compared to the catalyst without acid treatment. The catalysts with acid treatment also showed good heat storage function in reverse flow reactor applications.
    材料科学与技术

    WANG Pin,CUI Yingde,YIN Guoqiang,HE Ming,ZHANG Buning
    2009, 28(12):  2169. 
    Abstract ( 2153 )  
    Related Articles | Metrics
    Protein-based hydrogels have got more and more attention for their abundant resourcesbiodegradability and good biocompatibility. The crosslinking mechanisms of protein-based hydrogels are firstly introduced in this reviewand then the characterization methods for the structure measurement of protein-based hydrogels are presentedsuch as spectroscopic measurementthermal analysis and microscope. The applications of protein-based hydrogels in absorbent hydrogelsintelligent hydrogels and tissue engineering are reviewedand finally the existing problems and the trends of research are discussed.
    Research progress of the synthetic methods for conducting polymer nanomaterials
    FENG Xiaomiao,HOU Wenhua,ZHU Junjie
    2009, 28(12):  2173. 
    Abstract ( 2598 )  
    Related Articles | Metrics
    Conducting polymer nanomaterials not only have high conductivity, but also have special properties of nanomaterials. Therefore, these materials have application prospect in many fields. In this paper, the synthetic methods of conducting polymer nanomaterials including template method and templateless method are discussed. The template method could be divided into hard and soft template methods. The advantages and disadvantages of each method are analyzed through taking the preparation of polyaniline as examples mainly. The development prospect of such conductive polymer nanomaterials is also presented.
    Chemical degradation and recycling of coloured polyethylene terephthalate waste
    LI Yan,ZHENG Nan,ZHENG Yubin
    2009, 28(12):  2180. 
    Abstract ( 1562 )  
    Related Articles | Metrics
    In order to reduce the pollution produced by polyethylene terephthalate (PET) wastes and promote resource recyclingthe degradation of PET in supercritical methanol yielding dimethyl terephthalate (DMT) was studiedand the decolorization methods for the product were investigated. It was found that fiber-grade PET can be depolymerized though supercritical methanol in about 30min at 265 and 11MPa with DMT yield of nearly 85%and the monomer has the purity to fiber-grade PET. Whileit needs longer time for bottle-grade PET to reach the same depolymerization.
    Adsorption properties of graft copolymers of xanthan gum and acrylamide for Cr3+
    CHENG Lei,LI Zhongjin,WANG Lei,ZHU Xiaofeng,ZHANG Chaowu
    2009, 28(12):  2185. 
    Abstract ( 2122 )  
    Related Articles | Metrics
    The graft copolymers of xanthan gum and acrylamide XG-g-AM were synthesized from xanthan gum by microwave irradiation with acrylamide as graft monomerand the product was characterized by Fourier thransform infrared spectroscopy FTIR and X-ray diffraction XRD. The adsorption behavior of XG-g-AM for Cr3+ was investigatedand the adsorption thermodynamics was studied according to adsorption isotherm. The adsorption behavior of XG-g-AM for Cr3+ can be expressed by Freundlich adsorption isotherm equation in the temperature range of 298318 K. The adsorption is a spontaneous and endothermic process with increased entropyand the increase in temperature would benefit the adsorption.
    Effect of conjugative polyalcohol on the mechanical properties of rigid polyurethane foam
    LI Hongbo,DING Xuejia,XUE Haijiao,WU Henglan,YUAN Yuan,CHU Wenjuan,ZHANG Deqiang
    2009, 28(12):  2189. 
    Abstract ( 2034 )  
    Related Articles | Metrics
    Four series of polyurethane foams were prepared from main polyether mixed with low hydroxyl value polyether alcoholmiddle hydroxyl value polyether alcoholphthalic anhydride polyester polyalcohol and polymer polyalcohol respectively. The addition of low and middle hydroxyl value polyether alcohol resulted in the decrease of bubble diameterTMN3050 with low hydroxyl value resulted in the decrease of foam mechanical propertiesTMN700 resulted in the improvement of compression and impact strength of the foambut the decrease in bending strength. Low addition dosage of TPOP36/28 resulted in the decrease of bubble diameter and the improvement of compression and impact strength of the foambut the bending strength also decreased; addition of PS400A decreased the bubble diameterbut the density and mechanical properties of the foam decreased sharply.

    Thermal conductivity of PP/Al(OH)3/Mg(OH)2 composites

    QIU Yulin,LIANG Jizhao
    2009, 28(12):  2195. 
    Abstract ( 2748 )  
    Related Articles | Metrics
    Polypropylene (PP) thermal composites filled with Al(OH)3 and Mg(OH)2 were prepared. The thermal conductivity coefficient of the composites was measured by stable flat measuring instrument for thermal conductivity in different testing temperature. The addition of Al(OH)3 and Mg(OH)2 resulted in the thermal conductivity increase of PP. The thermal conductivity coefficient of PP/Al(OH)3/Mg(OH)2 composites presents a nonlinear increase with the increase in filler contentwith the increase in testing temperatureas well as with the increase in filler diameter.
    精细化工
    Advances in agrochemical surfactants
    DENG Kunxue,HUANG Qigu
    2009, 28(12):  2199. 
    Abstract ( 1629 )  
    Related Articles | Metrics
    Agrochemical surfactants are introduced from their mechanism in agrochemical manufacture and function at plants surface. The selection principle,the category of agrochemical surfactants and the existing problems are also discussed. Advances in the development of several new kinds of agrochemical surfactants are summarized and the prospect for there for future development is also proposed.

    White carbon black production from drained slurry generated by cutting silicon crystal using a wire-saw

    TIAN Weiliang,XU Dongmei,TONG Yu,GAO Jun,HU Yangdong
    2009, 28(12):  2205. 
    Abstract ( 1788 )  
    Related Articles | Metrics

    Based on the analysis of research progress in drained slurry and white carbon black,the preparation of white carbon black using silicon as starting material is proposed. The reaction of ammonium fluoride with silicon contained in the drained slurry generated by cutting silicon crystal using a wire-saw,the amination reaction of ammonium fluorosilicate,as well as the recycling of ammonium fluoride in the closed cycle system are investigated. Results showed that the recovering of ammonium fluoride is higher than 95% and the optimum conditions are: mass concentration of ammonium fluoride is 40%—55% and temperature is 50—60℃ for the reaction ammonium fluoride with the drained slurry. While for the amination reaction,the pH value is no higher than 6.9 in the nucleation stage and 7.1 in the growth stage,the mass concentration of ammonium fluorosilicate is 12% with two stages of precipitation and filtration,the dropping rate of ammonia water is 2 drop/s at the initial precipitation stage and 0.5—1 drop/s at the second precipitation stage and temperature is 40—50 ℃. This process has the advantages of diversity in starting material,low temperature,low-loss of ammonium fluoride and low-cost for reclaiming silicon from drained slurry.

    Preparation and application of the main monomer for high fatty alcohol defoamer
    YU Zhenglang,GUO Rui,JI Zhenqing,JIA Jianmin
    2009, 28(12):  2210. 
    Abstract ( 1869 )  
    Related Articles | Metrics
    Glyceryl monostearate was synthesized by a method of group protection. The optimum conditions for the synthesis were found through orthogonal experiments as:petroleum ether is 120 (mL/molGT),the molar ratio of glycerol∶ acetone ∶stearic acid is 1∶1.5∶0.7,the mass of catalyst is 5% of glycerol. The elemental analysis and IR spectrogram of the product were identical with the target product. Then the product was mixed with high-level fatty alcohol so as to develop a water-based emulsion non-silicon defoamer. A comparative study on the technical specifications showed that this defoamer is suitable for papermaking and coating process.
    Preparation and properties of polymerized silicate containing magnesium sulfate and zinc sulfate(PSMZS)
    ZHAO Binxia,BAI Weili,LIANG Wan,ZHANG Xiaoli
    2009, 28(12):  2214. 
    Abstract ( 1937 )  
    Related Articles | Metrics
    Inorganic polymer flocculantspoly(magnesium silicate zinc sulfate) (PSMZS) were prepared by the copolymerization of sodium silicate with zinc sulfate and magnesium sulfate. The influences of SiO2 concentrationactivation timeMg/Si and Zn/Si molar ratio and flocculant dosage on the flocculation efficiency were investigated. The structure and morphology of the prepared PSMZ flocculant were studies using XRD and SEM. The optimal preparation conditions for PSMZ are 0.4 mol/L of SiO2 concentration1.5 hours of ageing time with 150.5 of SiMgZn molar ratio. The optimal flocculant dosage was found to be 25 mL/L wastewaterwhere PSMZS has a banded structure featuring excellent flocculation efficiency.
    Synthesis and characterization of sodium 2-hydroxy-3-chloro propanesulfate
    SHEN Yunxia,BI Caifeng,ZHAO Yu,WANG Yufang,WANG Yilong
    2009, 28(12):  2218. 
    Abstract ( 2268 )  
    Related Articles | Metrics
    Sodium 2-hydroxy-3-chloro propanesulfate was synthesized from epichlorohydrin and sodium bisulfite. The effect of molar ratio of sodium bisulfite to epichlorohydrinreaction temperature and reaction time on product yield was investigated. The optimized reaction conditions were found to be the molar ratio of sodium bisulfite to epichlorohydrin is 1.151 and that of sodium sulfite to sodium bisulfite is 0.200.62where the highest product yield is 70.8%. Melting point of the product is 253254 . The structure of the product was verified by IR spectrumnuclear magnetic resonance and mass spectrometry.
    Dyeing method and performances of reactive dye containing bis(monofluoro-s-triazine) groups
    HUANG Haofei,ZHANG Shufen
    2009, 28(12):  2221. 
    Abstract ( 1715 )  
    Related Articles | Metrics
    A dimononfluorotriazineDMFT reactive dye containing bismonofluoro-s-triazine groups was used to dyeing cotton fabric. The parameters influencing on the efficiency of dyeing on cotton have been discussed in detailincluding dyeing temperatureconcentration of salt and alkali and fixation temperature. When the dyeing temperature reached 90 the salt concentration was 70 g/Lfixation temperature set to 4060 and alklai concentration reached 13g/Lthe total fixation rate of DMFT dye was 87%. Compared with the analogous reactive dye containing bismonochloro-s-triazine) groupsDMCT)the total fixation rate of DMFT dye increased 13.5%. Cotton dyed with the reactive dyes containing different reactive systems has relatively the same fastness properties.
    资源与环境工程
    Progress in silver-loaded activated carbon for the deep purification of potable water
    WANG Ziqiang,LIU Shouxin,LIU Shang
    2009, 28(12):  2226. 
    Abstract ( 1703 )  
    Related Articles | Metrics
    This review summarizes the progress of silver-loaded activated carbon AC/Ag for the deep purification of potable water. The propagation of microorganisms on AC and the antibacterial mechanisms of silver are firstly discussed. Then, the preparation methods for AC/Ag are elaborated, in which the nano-silver loaded AC/Ag has been proved to have stronger antibacterial characteristic. The influence of valence state and particle size of silver, the pore distribution and surface chemical properties of AC on the antibacterial and inhibitory properties are discussed. Furthermore, the developmental trend of AC/Ag is proposed.
    Advances in catalysis non-thermal plasma reactor for air pollution control
    LIU Yuexu,WANG Shaobo,YUAN Peisheng,ZHAO Ying
    2009, 28(12):  2232. 
    Abstract ( 2008 )  
    Related Articles | Metrics
    Catalysis non-thermal plasma reactor has been demonstrated to be effective in improving the energy efficiency and purification for air pollution control. According to the available experimental datafor a given specific energy densitythe energy efficiency for gaseous pollutant abatement obtained with catalysis non-thermal plasma reactor could be improved with 1.112 times as compared to that of conventional reactors depending on the type of pollutantsreactor geometry and catalyst used. The influences of reaction mechanismreactor geometry and catalyst parameters on the performance for gaseous pollutant removal are comprehensively discussedand the further development trend of this technology is proposed.
    Progress in production of levulinic acid from biomass
    PENG Hong,LIU Yuhuan,ZHANG Jinsheng,RUAN Rongsheng
    2009, 28(12):  2237. 
    Abstract ( 2147 )  
    Related Articles | Metrics
    As the exhaustion of unrenewable resourcesit has become the global attention focus in producing fuel and chemicals from renewable biomass resource. Levulinic acidwhich can be produced from biomassis an important platform compound having high reactivity and extensive uses. In this paperthe production of levulinic acid from biomass is reviewedincluding the issues with catalysis and purification.
    Progress in waste rubber cryogenic comminution technology
    ZHENG Huiping,XU Wendong,BIAN Haijun,FAN Shuanshi,LUO Dongxiao,HOU Jianguo
    2009, 28(12):  2242. 
    Abstract ( 2089 )  
    Related Articles | Metrics
    Waste rubber recycle is a preferential development direction to promote the development of rubber industry and to improve environment management level. Producing fine powder by cryogenic comminution is the most promising method for rubber recycle. The present paper summarizes the progress in rubber cryogenic comminution,including refrigeration techniques with liquid nitrogen,air expansion,ammonia-ethane,natural gas under high pressure expansion and liquefied natural gas cryogenic energy. Most of these techniques are encountered with many difficulties such as high energy consumption,product quality control as well as dust pollution etc. Hence,the present paper proposes a waste rubber cryogenic comminution technique using liquid refrigerant and liquefied natural gas as the cold source,which may have some merits such as lower energy consumption,better product quality control and dramatically reduced dust pollution and so on.
    Ultra-deep desulfurization of pentane with K2FeO4 by catalytic oxidation process
    SONG Hua,LI Zhengguang,WANG Huafeng,LIU Yanxiu
    2009, 28(12):  2248. 
    Abstract ( 1962 )  
    Related Articles | Metrics
    Potassium ferrate is prepared by an improved hypochlorite oxidation method and then characterized. A neweffective and green approach for ultralow-sulfur pentane production is proposed using potassium ferrate as oxidant. Effects of oxidation conditions on the desulphurization and the oxidation mechanism are discussed. With 0.1786 g of K2FeO40.5 mL of ZSW-1 catalyst20 mL of pentane under 30 for 60 minthe reaction mixture was extracted with 5%NaOH aqueous solutionthe sulphur content was reduced from 50 mg/L to 0.632 mg/Land the desulfurization ratio reached to 98.7.
    应用技术
    A novel chemical process for coal-gasification wastewater treatment
    School of Chemical Engineering,South China University of Technology; China Coal Longhua Harbin Coal Chemical Industry Co. Ltd.
    2009, 28(12):  2253. 
    Abstract ( 2859 )  
    Related Articles | Metrics
    A novel chemical process is introduced for the treatment of coal-gasification wastewater produced from Lurqi gasification,and the process has been industrially realized. Ammonia and acidic gas in coal-gasification wastewater are removed through a sour water stripping tower in the new process,through which the pH value of the treated wastewater is decreased from 9—11 to 7,and hence it is beneficial to the subsequent solvent extraction for phenols. The distribution coefficients of MIBK to phenol and polyhydric phenols are greater than those of DIPE. The application of MIBK as extraction solvent would recover more phenolic substances from wastewater than DIPE. The COD value would be further reduced before the coal-gasification wastewater flowed into the biochemical treatment.
    Method and apparatus for real-time gas concentration detection in gas mixture
    FEI Guangping,LI Ruijun,XIE Donglai,QIAO Weiyan
    2009, 28(12):  2257. 
    Abstract ( 1452 )  
    Related Articles | Metrics
    A real-time dynamic detection method and apparatus for measuring the concentration of a certain component in gas mixture has been developed to meet the demand in chemical production process. The principlesstructure and calibration method of the equipment are described in details. The apparatus has been successfully examined in the dynamic monitoring of the tracer gas concentration in a fluidized bed cold modeland the experimental results proved that the apparatus has features like easy operationgeneralized application and high accuracy.
京ICP备12046843号-2;京公网安备 11010102001994号
Copyright © Chemical Industry and Engineering Progress, All Rights Reserved.
E-mail: hgjz@cip.com.cn
Powered by Beijing Magtech Co. Ltd