Chemical Industry and Engineering Progress ›› 2020, Vol. 39 ›› Issue (1): 257-266.DOI: 10.16085/j.issn.1000-6613.2019-0747
• Materials science and technology • Previous Articles Next Articles
Yu XIAO(),Yu GUO(),Hongmei WU,Xiaoqing JIANG
Received:
2019-05-08
Online:
2020-01-14
Published:
2020-01-05
Contact:
Yu GUO
通讯作者:
郭宇
作者简介:
肖昱(1994—),男,硕士研究生,研究方向为化工新材料。E-mail:基金资助:
CLC Number:
Yu XIAO,Yu GUO,Hongmei WU,Xiaoqing JIANG. Adsorption of chromium (Ⅲ) ions with amino functionalized mesoporous silica adsorbent[J]. Chemical Industry and Engineering Progress, 2020, 39(1): 257-266.
肖昱,郭宇,吴红梅,姜晓庆. 氨基功能化介孔硅吸附剂的制备及其对铬(Ⅲ)的吸附行为[J]. 化工进展, 2020, 39(1): 257-266.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2019-0747
样品 | 比表面积/m2·g-1 | 孔径/nm |
---|---|---|
SBA-15 | 757 | 9.69 |
NH2-SBA-15 | 565 | 6.54 |
样品 | 比表面积/m2·g-1 | 孔径/nm |
---|---|---|
SBA-15 | 757 | 9.69 |
NH2-SBA-15 | 565 | 6.54 |
温度/℃ | Langmuir | Freundlich | |||||
---|---|---|---|---|---|---|---|
q m/mg·g-1 | K L | R 2 | K F | 1/n | R 2 | ||
30 | 21.982 | 0.417 | 0.996 | 7.785 | 0.317 | 0.816 | |
40 | 23.911 | 0.434 | 0.996 | 8.459 | 0.324 | 0.814 | |
50 | 25.550 | 0.672 | 0.993 | 11.207 | 0.266 | 0.555 |
温度/℃ | Langmuir | Freundlich | |||||
---|---|---|---|---|---|---|---|
q m/mg·g-1 | K L | R 2 | K F | 1/n | R 2 | ||
30 | 21.982 | 0.417 | 0.996 | 7.785 | 0.317 | 0.816 | |
40 | 23.911 | 0.434 | 0.996 | 8.459 | 0.324 | 0.814 | |
50 | 25.550 | 0.672 | 0.993 | 11.207 | 0.266 | 0.555 |
样品 | 温度 /K | K c | ΔG /kJ?mol-1 | ΔS/kJ?mol?K-1 | ΔH/kJ?mol-1 |
---|---|---|---|---|---|
SBA-15 | 293 | 0.329 | 2.686 | 0.038 | 13.82 |
303 | 0.432 | 2.306 | |||
313 | 0.484 | 1.926 | |||
323 | 0.643 | 1.546 | |||
333 | 0.621 | 1.166 | |||
NH2-SBA-15 | 293 | 3.124 | -3.242 | 0.084 | 21.37 |
303 | 5.734 | -4.082 | |||
313 | 8.217 | -4.922 | |||
323 | 9.204 | -5.762 | |||
333 | 9.000 | -6.602 |
样品 | 温度 /K | K c | ΔG /kJ?mol-1 | ΔS/kJ?mol?K-1 | ΔH/kJ?mol-1 |
---|---|---|---|---|---|
SBA-15 | 293 | 0.329 | 2.686 | 0.038 | 13.82 |
303 | 0.432 | 2.306 | |||
313 | 0.484 | 1.926 | |||
323 | 0.643 | 1.546 | |||
333 | 0.621 | 1.166 | |||
NH2-SBA-15 | 293 | 3.124 | -3.242 | 0.084 | 21.37 |
303 | 5.734 | -4.082 | |||
313 | 8.217 | -4.922 | |||
323 | 9.204 | -5.762 | |||
333 | 9.000 | -6.602 |
吸附剂 | q e(实验)/mg·g-1 | 拟一级动力学模型 | 拟二级动力学模型 | |||||
---|---|---|---|---|---|---|---|---|
K 1/min-1 | q e(计算)/mg·g-1 | R 2 | K 2/g·mg-1·min-1 | q e(计算)/mg·g-1 | R 2 | |||
NH2-SBA-15 | 18.10 | 0.0228 | 252.924 | 0.852 | 2.36×10-4 | 21.724 | 0.942 |
吸附剂 | q e(实验)/mg·g-1 | 拟一级动力学模型 | 拟二级动力学模型 | |||||
---|---|---|---|---|---|---|---|---|
K 1/min-1 | q e(计算)/mg·g-1 | R 2 | K 2/g·mg-1·min-1 | q e(计算)/mg·g-1 | R 2 | |||
NH2-SBA-15 | 18.10 | 0.0228 | 252.924 | 0.852 | 2.36×10-4 | 21.724 | 0.942 |
吸附剂 | pH | q m/mg·g-1 | 参考文献 |
---|---|---|---|
多壁碳纳米管 | 3 | 13.2 | [ |
活性炭 | 6 | 12.23 | [ |
改性氧化石墨烯 | 5 | 13.3 | [ |
硫醇功能化MCM-41 | 5 | 15.34 | [ |
臭氧化活性炭 | 6 | 13.31 | [ |
NH2-SBA-15 | 6 | 24.88 | 本工作 |
吸附剂 | pH | q m/mg·g-1 | 参考文献 |
---|---|---|---|
多壁碳纳米管 | 3 | 13.2 | [ |
活性炭 | 6 | 12.23 | [ |
改性氧化石墨烯 | 5 | 13.3 | [ |
硫醇功能化MCM-41 | 5 | 15.34 | [ |
臭氧化活性炭 | 6 | 13.31 | [ |
NH2-SBA-15 | 6 | 24.88 | 本工作 |
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