Chemical Industry and Engineering Progress ›› 2017, Vol. 36 ›› Issue (07): 2464-2472.DOI: 10.16085/j.issn.1000-6613.2016-2127

Previous Articles     Next Articles

Side-chain alkylation of toluene with methanol to produce styrene:mechanism and catalysts

LI Jiangchuan1, CHAI Yongming1,2, LIU Bin1,2, WU Yilan1, LI Yichuan2, LIU Chenguang1,2   

  1. 1 State Key Laboratory of Heavy Oil Processing, School of Chemical Engineering, China University of Petroleum(East China), Qingdao 266580, Shandong, China;
    2 Key Laboratory of Catalysis, China National Petroleum Corp., Qingdao 266580, Shandong, China
  • Received:2016-11-17 Revised:2016-12-22 Online:2017-07-05 Published:2017-07-05

甲苯-甲醇侧链烷基化制备苯乙烯反应机理与催化剂

李江川1, 柴永明1,2, 刘宾1,2, 吴仪岚1, 李奕川2, 刘晨光1,2   

  1. 1 中国石油大学(华东)化学工程学院, 重质油国家重点实验室, 山东 青岛 266580;
    2 中国石油天然气集团公司催化重点实验室, 山东 青岛 266580
  • 通讯作者: 刘晨光,博士,教授,主要从事油品加氢精制和工业催化研究。
  • 作者简介:李江川(1993-),男,硕士研究生,主要从事石油天然气加工研究。E-mail:jcli1993@126.com。
  • 基金资助:
    国家重点基础研究发展计划(2010CB226905)及中央高校基本科研专项资金(14CX06112A,15CX07002A,15CX02023A)项目。

Abstract: Side-chain alkylation of toluene with methanol is a promising method to prepare styrene which shows great industrial prospect and therefore is of both economic and scientific importance.The research background is briefly introduced and then the research progress on the side-chain alkylation mechanism is systemically reviewed.Subsequently,we summarize the influence of various reaction conditions and the features of different catalysts.The development concepts and technology routes of acid-base dual-functional catalysts are summarized comprehensively.Results based on reaction mechanistic path and thermodynamic property analysis show that methanol decomposition and activation of methyl in toluene are the main limiting factors.Ultimately,this review provides applications of new catalytic materials in side-chain alkylation and a novel catalyst design idea that combines suitable acid and basic catalyst to construct synergistic catalysts.

Key words: toluene, methanol, side-chain alkylation, styrene, acid-base catalysis

摘要: 甲苯-甲醇侧链烷基化制备苯乙烯是具有重要研究意义和工业化前景的苯乙烯生产途径。本文回顾了甲苯-甲醇侧链烷基化的研究背景,综述了近年来甲苯-甲醇侧链烷基化反应机理的研究进展,简述了反应条件的影响,分析了催化剂特点和需求,全面总结了酸碱双功能催化剂开发理念和技术路线。对甲苯-甲醇侧链烷基化反应历程的研究结果和热力学特性进行了分析,结果表明甲醇深度分解和活化甲苯侧链甲基为反应主要限制因素。最后论述了新催化材料在侧链烷基化反应中的应用,提出酸催化剂和碱催化剂的高效耦合构建活性中心的催化剂设计新思路。

关键词: 甲苯, 甲醇, 侧链烷基化, 苯乙烯, 酸碱催化

CLC Number: 

京ICP备12046843号-2;京公网安备 11010102001994号
Copyright © Chemical Industry and Engineering Progress, All Rights Reserved.
E-mail: hgjz@cip.com.cn
Powered by Beijing Magtech Co. Ltd