Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (7): 3550-3560.DOI: 10.16085/j.issn.1000-6613.2022-1575
• Industrial catalysis • Previous Articles Next Articles
YU Zhiqing1(), HUANG Wenbin1, WANG Xiaohan1, DENG Kaixin1, WEI Qiang1, ZHOU Yasong1(), JIANG Peng2
Received:
2022-08-25
Revised:
2022-10-24
Online:
2023-08-14
Published:
2023-07-15
Contact:
ZHOU Yasong
于志庆1(), 黄文斌1, 王晓晗1, 邓开鑫1, 魏强1, 周亚松1(), 姜鹏2
通讯作者:
周亚松
作者简介:
于志庆(1992—),男,博士研究生,研究方向为石油和天然气化工。E-mail:yuzqcup@163.com。
基金资助:
CLC Number:
YU Zhiqing, HUANG Wenbin, WANG Xiaohan, DENG Kaixin, WEI Qiang, ZHOU Yasong, JIANG Peng. B-doped Al2O3@C support for CoMo hydrodesulfurization catalyst and their hydrodesulfurization performance[J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3550-3560.
于志庆, 黄文斌, 王晓晗, 邓开鑫, 魏强, 周亚松, 姜鹏. B掺杂Al2O3@C负载CoMo型加氢脱硫催化剂性能[J]. 化工进展, 2023, 42(7): 3550-3560.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-1575
沥青粉组成质量分数/% | 软化点 /℃ | 堆积密度 /g·cm-3 | |||
---|---|---|---|---|---|
饱和分 | 胶质 | 芳香分 | 沥青质 | ||
1.87 | 9.10 | 33.74 | 55.29 | 178.74 | 0.10 |
沥青粉组成质量分数/% | 软化点 /℃ | 堆积密度 /g·cm-3 | |||
---|---|---|---|---|---|
饱和分 | 胶质 | 芳香分 | 沥青质 | ||
1.87 | 9.10 | 33.74 | 55.29 | 178.74 | 0.10 |
名称 | SBET/m2·g-1 | V/cm3·g-1 | D/nm |
---|---|---|---|
Al2O3 | 258.51 | 0.73 | 9.99 |
Al2O3@C | 234.82 | 0.68 | 9.12 |
Al2O3@BC | 231.39 | 0.68 | 8.93 |
CoMo-Al2O3 | 236.33 | 0.64 | 9.38 |
CoMo-Al2O3@C | 217.74 | 0.62 | 8.46 |
CoMo-Al2O3@BC | 215.66 | 0.62 | 8.27 |
名称 | SBET/m2·g-1 | V/cm3·g-1 | D/nm |
---|---|---|---|
Al2O3 | 258.51 | 0.73 | 9.99 |
Al2O3@C | 234.82 | 0.68 | 9.12 |
Al2O3@BC | 231.39 | 0.68 | 8.93 |
CoMo-Al2O3 | 236.33 | 0.64 | 9.38 |
CoMo-Al2O3@C | 217.74 | 0.62 | 8.46 |
CoMo-Al2O3@BC | 215.66 | 0.62 | 8.27 |
名称 | L/nm | N |
---|---|---|
CoMo-Al2O3 | 5.1 | 2.8 |
CoMo-Al2O3@C | 4.8 | 3.8 |
CoMo-Al2O3@BC | 3.8 | 3.9 |
名称 | L/nm | N |
---|---|---|
CoMo-Al2O3 | 5.1 | 2.8 |
CoMo-Al2O3@C | 4.8 | 3.8 |
CoMo-Al2O3@BC | 3.8 | 3.9 |
名称 | CoMo-Al2O3 | CoMo-Al2O3@C | CoMo-Al2O3@BC |
---|---|---|---|
Mo4+/% | 61 | 73 | 79 |
Mo5+/% | 16 | 10 | 7 |
Mo6+/% | 23 | 17 | 14 |
CoO | 34 | 30 | 24 |
CoMoS | 54 | 61 | 69 |
Co9S8 | 10 | 9 | 7 |
名称 | CoMo-Al2O3 | CoMo-Al2O3@C | CoMo-Al2O3@BC |
---|---|---|---|
Mo4+/% | 61 | 73 | 79 |
Mo5+/% | 16 | 10 | 7 |
Mo6+/% | 23 | 17 | 14 |
CoO | 34 | 30 | 24 |
CoMoS | 54 | 61 | 69 |
Co9S8 | 10 | 9 | 7 |
反应物 | 催化剂 | kHDS/10-4mol·h-1·g-1 | kDDS/10-4mol·h-1·g-1 | kHYD/10-4mol·h-1·g-1 |
---|---|---|---|---|
DBT | CoMo-Al2O3 | 2.66 | 1.95 | 0.71 |
CoMo-Al2O3@C | 3.54 | 2.39 | 1.15 | |
CoMo-Al2O3@BC | 4.01 | 2.62 | 1.39 | |
4,6-DMDBT | CoMo-Al2O3 | 0.86 | 0.10 | 0.76 |
CoMo-Al2O3@C | 1.05 | 0.11 | 0.94 | |
CoMo-Al2O3@BC | 1.17 | 0.11 | 1.05 |
反应物 | 催化剂 | kHDS/10-4mol·h-1·g-1 | kDDS/10-4mol·h-1·g-1 | kHYD/10-4mol·h-1·g-1 |
---|---|---|---|---|
DBT | CoMo-Al2O3 | 2.66 | 1.95 | 0.71 |
CoMo-Al2O3@C | 3.54 | 2.39 | 1.15 | |
CoMo-Al2O3@BC | 4.01 | 2.62 | 1.39 | |
4,6-DMDBT | CoMo-Al2O3 | 0.86 | 0.10 | 0.76 |
CoMo-Al2O3@C | 1.05 | 0.11 | 0.94 | |
CoMo-Al2O3@BC | 1.17 | 0.11 | 1.05 |
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