Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (2): 1020-1027.DOI: 10.16085/j.issn.1000-6613.2022-0677
• Resources and environmental engineering • Previous Articles Next Articles
FAN Siqiang1(), PENG Shaozhong1, PENG Chong2(), HU Yongkang1
Received:
2022-04-18
Revised:
2022-05-30
Online:
2023-03-13
Published:
2023-02-25
Contact:
PENG Chong
通讯作者:
彭冲
作者简介:
范思强(1991—),男,硕士研究生,研究方向为加氢工艺技术。E-mail:fansiqiang.fshy@sinopec.com。
基金资助:
CLC Number:
FAN Siqiang, PENG Shaozhong, PENG Chong, HU Yongkang. Research progress in high value-added utilization technology of waste plastics[J]. Chemical Industry and Engineering Progress, 2023, 42(2): 1020-1027.
范思强, 彭绍忠, 彭冲, 胡永康. 废塑料高附加值利用技术研究进展[J]. 化工进展, 2023, 42(2): 1020-1027.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-0677
工艺条件 | 催化剂类别 | 液体产品收率/% | 液体产品碳数 |
---|---|---|---|
250℃、1.38MPa、6h | mSiO2/Pt/SiO2 Pt/SiO2 | 93.3 92.0 | 12~16 18~26 |
250℃、1.38MPa、24h | mSiO2/Pt/SiO2 Pt/SiO2 | 89.7 79.7 | 12~16 18~26 |
250℃、1.38MPa、48h | mSiO2/Pt/SiO2 Pt/SiO2 | 75.9 73.5 | 12~16 18~26 |
工艺条件 | 催化剂类别 | 液体产品收率/% | 液体产品碳数 |
---|---|---|---|
250℃、1.38MPa、6h | mSiO2/Pt/SiO2 Pt/SiO2 | 93.3 92.0 | 12~16 18~26 |
250℃、1.38MPa、24h | mSiO2/Pt/SiO2 Pt/SiO2 | 89.7 79.7 | 12~16 18~26 |
250℃、1.38MPa、48h | mSiO2/Pt/SiO2 Pt/SiO2 | 75.9 73.5 | 12~16 18~26 |
原料 | 主要工艺条件 | 处理方式 | 研究亮点 | 参考文献 |
---|---|---|---|---|
高密度聚乙烯(HDPE) | 500~800℃(最佳550℃)、N2气氛 | 热裂解 | 热解油550℃时收率达到70%(质量分数),主要是C8~C12的轻油馏分 | [ |
高密度聚乙烯(HDPE) | 430~490℃、 15~60min | 热裂解 | 430℃下处理15min,裂解油收率可达90.3%(质量分数),性质与CGO相似 460℃下处理60min,裂解油性质与LCO相似 | [ |
低密度聚乙烯(LDPE)、高密度聚乙烯(HDPE)、聚丙烯(PP)混合塑料 | 300~400℃ | 热裂解 | 液体产品收率达到82%(质量分数),具有高辛烷值(约92)、高热值和低黏度等优质燃料特性 | [ |
聚丙烯(PP) | 450~600℃ | 热裂解 | 液体产品收率为81%~93%(质量分数),常压下处理得到汽油馏分产品收率高而真空条件下得到柴油馏分产品收率高,升温速率的快慢会影响液体产物分布 | [ |
低密度聚乙烯(LDPE) | 450~650℃、加热速率1~30℃/S | 热裂解/催化热解(HZSM-5) | 在热裂解中,较高的加热速率,即20℃/s有利于提高液态油的生成,在550℃时获得最大产油量93.42%(质量分数);催化热解中HZSM-5 的引入大大提高液体产品质量 | [ |
聚丙烯(PP)、聚苯乙烯(PS) | 500~600℃、加热速率10~100℃/min | 催化裂解 (HZSM-5) | 稻草和甘蔗渣与聚丙烯和聚苯乙烯进行了共裂解,催化剂的引入提高生成油品的质量,黏度、密度和闪点与轻质燃料油相似同时氧含量大大降低 | [ |
聚丙烯(PP) | 7.0MPa、350℃ | 催化裂解 (Ni-Au/MOR) | 生成的液体产品主要由正构烷烃、异构烷烃与芳烃组成,与石化来源的柴油相似度达90% | [ |
混合塑料:低密度聚乙烯(LDPE)、高密度聚乙烯(HDPE)、聚丙烯(PP)、聚苯乙烯(PS) | 2.0MPa、 375~425℃ | 催化裂解(Al-SBA-15/Al-SBA-16) | 高温下催化剂差别不影响反应效果,低温下Al-SBA-15显示出良好的活性,液体产品收率更高 | [ |
原料 | 主要工艺条件 | 处理方式 | 研究亮点 | 参考文献 |
---|---|---|---|---|
高密度聚乙烯(HDPE) | 500~800℃(最佳550℃)、N2气氛 | 热裂解 | 热解油550℃时收率达到70%(质量分数),主要是C8~C12的轻油馏分 | [ |
高密度聚乙烯(HDPE) | 430~490℃、 15~60min | 热裂解 | 430℃下处理15min,裂解油收率可达90.3%(质量分数),性质与CGO相似 460℃下处理60min,裂解油性质与LCO相似 | [ |
低密度聚乙烯(LDPE)、高密度聚乙烯(HDPE)、聚丙烯(PP)混合塑料 | 300~400℃ | 热裂解 | 液体产品收率达到82%(质量分数),具有高辛烷值(约92)、高热值和低黏度等优质燃料特性 | [ |
聚丙烯(PP) | 450~600℃ | 热裂解 | 液体产品收率为81%~93%(质量分数),常压下处理得到汽油馏分产品收率高而真空条件下得到柴油馏分产品收率高,升温速率的快慢会影响液体产物分布 | [ |
低密度聚乙烯(LDPE) | 450~650℃、加热速率1~30℃/S | 热裂解/催化热解(HZSM-5) | 在热裂解中,较高的加热速率,即20℃/s有利于提高液态油的生成,在550℃时获得最大产油量93.42%(质量分数);催化热解中HZSM-5 的引入大大提高液体产品质量 | [ |
聚丙烯(PP)、聚苯乙烯(PS) | 500~600℃、加热速率10~100℃/min | 催化裂解 (HZSM-5) | 稻草和甘蔗渣与聚丙烯和聚苯乙烯进行了共裂解,催化剂的引入提高生成油品的质量,黏度、密度和闪点与轻质燃料油相似同时氧含量大大降低 | [ |
聚丙烯(PP) | 7.0MPa、350℃ | 催化裂解 (Ni-Au/MOR) | 生成的液体产品主要由正构烷烃、异构烷烃与芳烃组成,与石化来源的柴油相似度达90% | [ |
混合塑料:低密度聚乙烯(LDPE)、高密度聚乙烯(HDPE)、聚丙烯(PP)、聚苯乙烯(PS) | 2.0MPa、 375~425℃ | 催化裂解(Al-SBA-15/Al-SBA-16) | 高温下催化剂差别不影响反应效果,低温下Al-SBA-15显示出良好的活性,液体产品收率更高 | [ |
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