Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (11): 5648-5660.DOI: 10.16085/j.issn.1000-6613.2022-2293
• Energy processes and technology • Previous Articles Next Articles
XU Li1(), WU Yufeng1(), ZHANG Yuanjia2, HU Shuangqing2
Received:
2022-12-11
Revised:
2023-04-21
Online:
2023-12-15
Published:
2023-11-20
Contact:
WU Yufeng
通讯作者:
吴玉锋
作者简介:
徐漓(1985—),男,博士研究生,研究方向为生物质高值化转化利用。E-mail:94471442@qq.com。
基金资助:
CLC Number:
XU Li, WU Yufeng, ZHANG Yuanjia, HU Shuangqing. Progress of comprehensive utilization technology of agricultural and forestry wastes in Guangdong under the background of “carbon peaking and carbon neutrality”[J]. Chemical Industry and Engineering Progress, 2023, 42(11): 5648-5660.
徐漓, 吴玉锋, 张元甲, 胡双清. “双碳”目标背景下广东农林废弃物综合利用技术进展[J]. 化工进展, 2023, 42(11): 5648-5660.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2293
农作物 | 收获面积/万亩 | 亩产公斤/亩 | 总产量/万吨 |
---|---|---|---|
经济作物 | 3427.98 | ||
甘蔗/糖蔗 | 225.16 | 5803 | 1306.60 |
油料作物/花生 | 536.16 | 219 | 117.30 |
麻类 | 0.09 | 212 | 0.02 |
烟叶 | 23.77 | 163 | 3.88 |
中草药材 | 84.57 | 491 | 41.53 |
蔬菜及食用菌 | 2088.37 | 1846 | 3855.73 |
瓜果类(果用瓜) | 64.70 | 2026 | 131.06 |
其他农作物/木薯 | 405.16 | — | — |
粮食作物 | 3471.80 | ||
稻谷 | 3319.50 | 386 | 1279.90 |
玉米 | 120.08 | 303 | 54.54 |
大豆 | 31.79 | 183 | 8.71 |
小麦 | 0.42 | 233 | 0.15 |
农作物 | 收获面积/万亩 | 亩产公斤/亩 | 总产量/万吨 |
---|---|---|---|
经济作物 | 3427.98 | ||
甘蔗/糖蔗 | 225.16 | 5803 | 1306.60 |
油料作物/花生 | 536.16 | 219 | 117.30 |
麻类 | 0.09 | 212 | 0.02 |
烟叶 | 23.77 | 163 | 3.88 |
中草药材 | 84.57 | 491 | 41.53 |
蔬菜及食用菌 | 2088.37 | 1846 | 3855.73 |
瓜果类(果用瓜) | 64.70 | 2026 | 131.06 |
其他农作物/木薯 | 405.16 | — | — |
粮食作物 | 3471.80 | ||
稻谷 | 3319.50 | 386 | 1279.90 |
玉米 | 120.08 | 303 | 54.54 |
大豆 | 31.79 | 183 | 8.71 |
小麦 | 0.42 | 233 | 0.15 |
单位项目 | 地点 | 装机容量/MW | 原料 |
---|---|---|---|
广东粤电湛江生物质发电有限公司 | 湛江 | 2×50,直燃发电机组 | 树皮、枝叶、树根、秸秆、甘蔗叶、皮壳等农林废弃物 |
韶能集团新丰旭能生物质能发电工程 | 韶关 | 120,直燃发电机组 | 树皮、枝叶、树根、秸秆、甘蔗叶、皮壳等农林废弃物 |
潮州市环保发电厂项目 | 潮州 | 35 | 生活垃圾 |
珠海市环保生物质热电工程项目 | 珠海 | 60 | 生活垃圾 |
茂名电白绿能环保发电项目 | 茂名 | 50 | 生活垃圾 |
信宜市绿能环保发电项目 | 茂名 | 24 | 生活垃圾 |
汕头市澄海洁源垃圾发电厂扩建项目 | 汕头市 | 25 | 生活垃圾 |
汕头市潮阳区生活垃圾焚烧发电厂BOT二期扩建项目 | 汕头市 | 25 | 生活垃圾 |
单位项目 | 地点 | 装机容量/MW | 原料 |
---|---|---|---|
广东粤电湛江生物质发电有限公司 | 湛江 | 2×50,直燃发电机组 | 树皮、枝叶、树根、秸秆、甘蔗叶、皮壳等农林废弃物 |
韶能集团新丰旭能生物质能发电工程 | 韶关 | 120,直燃发电机组 | 树皮、枝叶、树根、秸秆、甘蔗叶、皮壳等农林废弃物 |
潮州市环保发电厂项目 | 潮州 | 35 | 生活垃圾 |
珠海市环保生物质热电工程项目 | 珠海 | 60 | 生活垃圾 |
茂名电白绿能环保发电项目 | 茂名 | 50 | 生活垃圾 |
信宜市绿能环保发电项目 | 茂名 | 24 | 生活垃圾 |
汕头市澄海洁源垃圾发电厂扩建项目 | 汕头市 | 25 | 生活垃圾 |
汕头市潮阳区生活垃圾焚烧发电厂BOT二期扩建项目 | 汕头市 | 25 | 生活垃圾 |
研究者 | 研究内容 | 研究成果 |
---|---|---|
Vispute等[ | 生物质快速热解制备生物油及化学品 | 采用加氢和沸石催化相结合的综合催化方法,将生物质热解油转化为化学品原料 |
Cheng等[ | 生物质催化热解制备化学品 | 采用双功能Ga/ZSM-5催化剂快速催化热解木质纤维素生物质制备芳香族化合物 |
Zhang等[ | 生物质微波转化制备化学品 | 研究了微波辅助下木质素模型化合物在离子液体中转化为芳香族化合物 |
Yang等[ | 生物质热解特性 | 解析了纤维素、半纤维素和木质素热解特征及演化规律 |
Wang等[ | 生物质热解机理 | 解析了生物质热解机理模型及反应路线 |
Li等[ | 生物质气化制氢 | 钙基和镍基吸附强化玉米秸秆水蒸气气化制氢 |
Lu等[ | 生物质热解机理 | 纤维素快速热解特征链端和脱水单元的作用机理 |
Dou等[ | 生物质热解制液体燃料 | Co-Zn-β沸石催化剂催化转化硫酸盐木质素制备液体燃料 |
Shan等[ Xing等[ | 生物质催化热解制备液体燃料 | 铜、钾催化农林废弃物制备生物油及生物柴油 |
Lang等[ | 生物质气化兆瓦级应用 | 1MW固定床生物质气化飞灰及焦油脱除 |
Zhuang等[ | 生物质气化制合成气及氢焦 | 生物废物衍生氢焦结构-反应关系对后续热解气化性能影响 |
Wang等[ | 生物质气化合成二甲醚及液体燃料 | 生物质气化制备二甲醚、汽油为一体的生物质制液体燃料的实验装置 |
Zhang等[ | 生物质合成气催化合成气汽油 | 采用Ni/ASA催化剂将生物质合成气低聚反应制备富烯烃汽油系列碳氢化合物 |
Wei等[ | 生物质化学链气化 | 基于负碳排放的生物质化学链气化制备合成气,裂解CO2 |
Zhang等[ | 生物质制低碳烯烃 | Fe改性ZSM-5催化剂催化生物质向制备低碳烯烃 |
研究者 | 研究内容 | 研究成果 |
---|---|---|
Vispute等[ | 生物质快速热解制备生物油及化学品 | 采用加氢和沸石催化相结合的综合催化方法,将生物质热解油转化为化学品原料 |
Cheng等[ | 生物质催化热解制备化学品 | 采用双功能Ga/ZSM-5催化剂快速催化热解木质纤维素生物质制备芳香族化合物 |
Zhang等[ | 生物质微波转化制备化学品 | 研究了微波辅助下木质素模型化合物在离子液体中转化为芳香族化合物 |
Yang等[ | 生物质热解特性 | 解析了纤维素、半纤维素和木质素热解特征及演化规律 |
Wang等[ | 生物质热解机理 | 解析了生物质热解机理模型及反应路线 |
Li等[ | 生物质气化制氢 | 钙基和镍基吸附强化玉米秸秆水蒸气气化制氢 |
Lu等[ | 生物质热解机理 | 纤维素快速热解特征链端和脱水单元的作用机理 |
Dou等[ | 生物质热解制液体燃料 | Co-Zn-β沸石催化剂催化转化硫酸盐木质素制备液体燃料 |
Shan等[ Xing等[ | 生物质催化热解制备液体燃料 | 铜、钾催化农林废弃物制备生物油及生物柴油 |
Lang等[ | 生物质气化兆瓦级应用 | 1MW固定床生物质气化飞灰及焦油脱除 |
Zhuang等[ | 生物质气化制合成气及氢焦 | 生物废物衍生氢焦结构-反应关系对后续热解气化性能影响 |
Wang等[ | 生物质气化合成二甲醚及液体燃料 | 生物质气化制备二甲醚、汽油为一体的生物质制液体燃料的实验装置 |
Zhang等[ | 生物质合成气催化合成气汽油 | 采用Ni/ASA催化剂将生物质合成气低聚反应制备富烯烃汽油系列碳氢化合物 |
Wei等[ | 生物质化学链气化 | 基于负碳排放的生物质化学链气化制备合成气,裂解CO2 |
Zhang等[ | 生物质制低碳烯烃 | Fe改性ZSM-5催化剂催化生物质向制备低碳烯烃 |
制氢过程 | 制氢成本/CNY·kg-1 | 制氢纯度 | 制氢排放/kg CO2·kg H2-1 | 特点 | 参考文献 |
---|---|---|---|---|---|
煤气化制氢 | 11~20(无/有CCS) | 35%~40% | 20 | 工艺成熟,成本较低,产物纯度需后续提高 | [ |
甲烷重整制氢 | 18~24(无/有CCS) | 75%~90% | 10 | 工艺成熟,反应速率快,蒸汽重整需外供热 | [ |
电解水制氢 | 35~46 | 超过99.99% | 30 | 产物纯度好,但能耗相对较高,能量利用率低 | [ |
可再生能源发电-电解水制氢 | 28~85 | 超过99.99% | 低于4.9 | 过程清洁,发电及电解水效率受限制 | [ |
生物质气化制氢 | 30~33 | 35%~40% | 近零 | 反应速率快,能耗低,环境友好 | [ |
生物质化学链制氢 | 12~15 | 超过99.9 % | 近零 | 反应速率快,能耗低,产物纯度高 | [ |
生物质发酵制氢 | — | 超过40 % | 近零 | 适用于液相重整制氢,存在生物质解聚及反应速率等瓶颈 | [ |
生物质光催化制氢 | — | 66.7%左右 | 近零 | 无污染,有工业化潜力,但光能转化效率及氢产率不高 | [ |
制氢过程 | 制氢成本/CNY·kg-1 | 制氢纯度 | 制氢排放/kg CO2·kg H2-1 | 特点 | 参考文献 |
---|---|---|---|---|---|
煤气化制氢 | 11~20(无/有CCS) | 35%~40% | 20 | 工艺成熟,成本较低,产物纯度需后续提高 | [ |
甲烷重整制氢 | 18~24(无/有CCS) | 75%~90% | 10 | 工艺成熟,反应速率快,蒸汽重整需外供热 | [ |
电解水制氢 | 35~46 | 超过99.99% | 30 | 产物纯度好,但能耗相对较高,能量利用率低 | [ |
可再生能源发电-电解水制氢 | 28~85 | 超过99.99% | 低于4.9 | 过程清洁,发电及电解水效率受限制 | [ |
生物质气化制氢 | 30~33 | 35%~40% | 近零 | 反应速率快,能耗低,环境友好 | [ |
生物质化学链制氢 | 12~15 | 超过99.9 % | 近零 | 反应速率快,能耗低,产物纯度高 | [ |
生物质发酵制氢 | — | 超过40 % | 近零 | 适用于液相重整制氢,存在生物质解聚及反应速率等瓶颈 | [ |
生物质光催化制氢 | — | 66.7%左右 | 近零 | 无污染,有工业化潜力,但光能转化效率及氢产率不高 | [ |
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