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Progress of photocatalysts for water splitting by solar energy

CHU Tingting,WANG Hui,FENG Caixia,MAO Liqun   

  1. School of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,Henan,China
  • Online:2012-10-05 Published:2012-10-05

可见光分解水制氢催化剂研究进展

楚婷婷,王 慧,冯彩霞,毛立群   

  1. 河南大学精细化学与工程研究所,河南 开封 475004

Abstract: In recent years,the research of photocatalysts of splitting water under visible light irradiation has attracted much attention,especially the preparation and modification of novel photocatalyst. Recent advance in photocatalytic hydrogen production was reviewed,and the preparation methods of photocatalysts were discussed,such as ion-doping,solid solution,composite semiconductor and co-catalyst. Based on the analysis above,lower utilization ratio of visible light and photochemical conversion efficiency were the most serious problems,and developing efficient and novel photocatalysts and studying the mechanism would be necessary.

Key words: water splitting, hydrogen, photocatalyst

摘要: 可见光分解水制氢研究主要集中在新型光催化剂的研制以及对传统光催化剂的改性。本文概述了近年来可见光分解水制氢技术的重要进展及最新研究成果,深入研究和分析了拓展光催化剂响应范围、提高其反应活性的几种技术路线,主要包括阴阳离子掺杂技术、固溶体技术、半导体复合技术以及加入助催化剂等;总结出了传统光催化剂存在可见光利用率低、光化学转化效率低等问题,提出了开发新型高效光催化剂并加强机理研究的必要性和可行性。

关键词: 分解水, 氢, 光催化剂

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