Research progress on advanced oxidation degradation of organic pollutants in water based on spinel type CoFe2O4

doi:10.16085/j.issn.1000-6613.2023-1773

Abstract

Abstract:

Advanced oxidation technologies (AOPs), which based on free radical reactions, have been widely investigated as a simple, efficient and clean technology for the removal of organic pollutants. Spinel-type cobalt ferrite (CoFe₂O₄) is widely used as a catalyst for driving radical generation in advanced oxidation processes due to its good catalytic performance, low metal leaching rate and high recycling rate. This review takes spinel-type CoFe₂O₄ as the research object. Herein, the structure and properties of CoFe₂O₄ are outlined. The modification methods of CoFe₂O₄, including morphology modification, elemental doping and coupling composite materials, are summarized. The basic principles and research progress of photocatalytic oxidation of CoFe₂O₄ and its composites, non-homogeneous Fenton-like oxidation, peroxydisulfate oxidation and ozone-catalyzed oxidation for the degradation of organic pollutants in water are highlighted. Finally, the problems of the current study are pointed out and the direction of its subsequent research is envisioned.

Key words: cobalt ferrite, advanced oxidation, catalytic degradation, organic pollutants, mechanism, water body

摘要：

基于自由基反应的高级氧化技术（AOPs）作为一种简单、高效、清洁的有机污染物去除技术得到了广泛研究。尖晶石型钴铁氧体（CoFe₂O₄）具有催化性能好、金属浸出率低和回收再利用率高等特点，被广泛用作高级氧化过程中驱动自由基生成的催化剂。本文以尖晶石型CoFe₂O₄为研究对象，概述了CoFe₂O₄的结构与性质；归纳总结了包括形貌调控、元素掺杂、耦合复合材料在内的CoFe₂O₄改性方法；重点综述了CoFe₂O₄及其复合材料光催化氧化、非均相类芬顿氧化、过一硫酸盐氧化与臭氧催化氧化降解水中有机污染物的基本原理及研究进展；最后指出当前研究存在的问题，并对其后续研究方向进行展望。

关键词: 钴铁氧体, 高级氧化, 催化降解, 有机污染物, 机理, 水体

CLC Number:

O643

ZHOU Tianhong, WANG Jinyi, SU Xu, ZENG Honglin, ZHAI Tianjiao. Research progress on advanced oxidation degradation of organic pollutants in water based on spinel type CoFe₂O₄[J]. Chemical Industry and Engineering Progress, 2024, 43(11): 6412-6427.

周添红, 王金怡, 苏旭, 曾虹霖, 翟天骄. 基于尖晶石型CoFe₂O₄高级氧化降解水中有机污染物研究进展[J]. 化工进展, 2024, 43(11): 6412-6427.

Figures/Tables 11

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催化剂	制备方法	异质结类型	光源	污染物	降解效率	稳定性	参考文献
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	罗丹明B （20mg/L）	93.8% （90min）	7次循环（>82.1%）	[70]
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	刚果红（30mg/L）	94.43% （50min）	7次循环（>83.5%）	[70]
CoFe₂O₄@CoWO₄	共沉淀法	Ⅱ型	可见光（10W LED灯）	亚甲基蓝（20mg/L）	96.3% （120min）	6次循环（87.6%）	[71]
CoFe₂O₄-Bi₂O₃	共沉淀法	Ⅰ型	卤素灯（9500lm）	亚甲基蓝（10mg/L）	80.0% （200min）	6次循环（约80.0%）	[72]
BiOI/CoFe₂O₄	共沉淀法	Z型	模拟太阳光光源	罗丹明B （5mg/L）	91.3% （90min）	3次循环（80.2%）	[73]
CoFe₂O₄/MIL-101(Fe)	溶剂热法	S型	氙灯光源（300W，λ>420nm）	四环素（10mg/L）	90.0% （120min）	4次循环（约75.0%）	[74]
CoFe₂O₄/NiFe₂O₄	水热法	S型	模拟太阳光光源	盐酸四环素（10mg/L）	76.1% （60min）	—	[75]
CoFe₂O₄/g-C₃N₄	水热法	Z型	可见光（10W LED灯）	亚甲基蓝（10mg/L）	98.86% （140min）	5次循环（约82.5%）	[76]
ZnIn₂S₄/CoFe₂O₄/BC	溶剂热法	p-n型	氙灯光源（150W）	环丙沙星（20mg/L）	96.9% （120min）	6次循环（约96.9%）	[77]
CoFe₂O₄/g-C₃N₄/Bi₄Ti₃O₁₂	超声辅助热处理法	双Z型	可见光（45W节能灯）	孔雀石绿（10mg/L）	98.05% （120min）	3次循环（约98.05%）	[78]

催化剂	制备方法	异质结类型	光源	污染物	降解效率	稳定性	参考文献
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	罗丹明B （20mg/L）	93.8% （90min）	7次循环（>82.1%）	[70]
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	刚果红（30mg/L）	94.43% （50min）	7次循环（>83.5%）	[70]
CoFe₂O₄@CoWO₄	共沉淀法	Ⅱ型	可见光（10W LED灯）	亚甲基蓝（20mg/L）	96.3% （120min）	6次循环（87.6%）	[71]
CoFe₂O₄-Bi₂O₃	共沉淀法	Ⅰ型	卤素灯（9500lm）	亚甲基蓝（10mg/L）	80.0% （200min）	6次循环（约80.0%）	[72]
BiOI/CoFe₂O₄	共沉淀法	Z型	模拟太阳光光源	罗丹明B （5mg/L）	91.3% （90min）	3次循环（80.2%）	[73]
CoFe₂O₄/MIL-101(Fe)	溶剂热法	S型	氙灯光源（300W，λ>420nm）	四环素（10mg/L）	90.0% （120min）	4次循环（约75.0%）	[74]
CoFe₂O₄/NiFe₂O₄	水热法	S型	模拟太阳光光源	盐酸四环素（10mg/L）	76.1% （60min）	—	[75]
CoFe₂O₄/g-C₃N₄	水热法	Z型	可见光（10W LED灯）	亚甲基蓝（10mg/L）	98.86% （140min）	5次循环（约82.5%）	[76]
ZnIn₂S₄/CoFe₂O₄/BC	溶剂热法	p-n型	氙灯光源（150W）	环丙沙星（20mg/L）	96.9% （120min）	6次循环（约96.9%）	[77]
CoFe₂O₄/g-C₃N₄/Bi₄Ti₃O₁₂	超声辅助热处理法	双Z型	可见光（45W节能灯）	孔雀石绿（10mg/L）	98.05% （120min）	3次循环（约98.05%）	[78]

催化剂	制备方法	污染物	催化剂用量	PMS用量	降解效率	稳定性	参考文献
CoFe₂O₄@NPC	水热碳化法	罗丹明B （100mg/L）	0.06g/L	0.3g/L	99.05% （20min）	5次循环（约83.2%）	[100]
CoFe₂O₄/OMt	改性水热法	卡马西平（5mg/L）	0.4g/L	0.5mmol/L	93% （60min）	3次循环（73.0%）	[101]
CoFe₂O₄@BC	溶胶-凝胶法	对硝基氯苯（10mg/L）	0.1g/L	1mmol/L	89% （240min）	5次循环（87.8%）	[102]
CoFe₂O₄/Al₂O₃	溶胶-凝胶法	磺胺氯吡啶（5mg/L）	1.0mmol/L	0.5mmol/L	97.8% （15min）	4次循环（97.6%）	[103]
CoFe₂O₄-SAC	水热法	诺氟沙星（10mg/L）	0.1g/L	0.15g/L	>92% （60min）	5次循环（>90.0%）	[104]
CoFe₂O₄@MoS₂	一锅水热法	四环素（10mg/L）	0.2g/L	0.5mmol/L	94.45% （30min）	5次循环（约90.0%）	[105]
CoFe₂O₄/ZIF-8	溶剂热法	亚甲基蓝（20mg/L）	0.04g/L	0.3g/L	97.9% （60min）	4次循环（80.4%）	[106]
CoFe₂O₄@3DG	水热法	苯并三唑（100mg/L）	0.2g/L	16mmol/L	100% （150min）	7次循环（90.4%）	[107]

催化剂	制备方法	污染物	催化剂用量	PMS用量	降解效率	稳定性	参考文献
CoFe₂O₄@NPC	水热碳化法	罗丹明B （100mg/L）	0.06g/L	0.3g/L	99.05% （20min）	5次循环（约83.2%）	[100]
CoFe₂O₄/OMt	改性水热法	卡马西平（5mg/L）	0.4g/L	0.5mmol/L	93% （60min）	3次循环（73.0%）	[101]
CoFe₂O₄@BC	溶胶-凝胶法	对硝基氯苯（10mg/L）	0.1g/L	1mmol/L	89% （240min）	5次循环（87.8%）	[102]
CoFe₂O₄/Al₂O₃	溶胶-凝胶法	磺胺氯吡啶（5mg/L）	1.0mmol/L	0.5mmol/L	97.8% （15min）	4次循环（97.6%）	[103]
CoFe₂O₄-SAC	水热法	诺氟沙星（10mg/L）	0.1g/L	0.15g/L	>92% （60min）	5次循环（>90.0%）	[104]
CoFe₂O₄@MoS₂	一锅水热法	四环素（10mg/L）	0.2g/L	0.5mmol/L	94.45% （30min）	5次循环（约90.0%）	[105]
CoFe₂O₄/ZIF-8	溶剂热法	亚甲基蓝（20mg/L）	0.04g/L	0.3g/L	97.9% （60min）	4次循环（80.4%）	[106]
CoFe₂O₄@3DG	水热法	苯并三唑（100mg/L）	0.2g/L	16mmol/L	100% （150min）	7次循环（90.4%）	[107]

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Research progress on advanced oxidation degradation of organic pollutants in water based on spinel type CoFe₂O₄

基于尖晶石型CoFe₂O₄高级氧化降解水中有机污染物研究进展

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