Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (11): 6042-6052.DOI: 10.16085/j.issn.1000-6613.2022-2333
• Resources and environmental engineering • Previous Articles
Received:
2022-12-19
Revised:
2023-02-19
Online:
2023-12-15
Published:
2023-11-20
Contact:
CHENG Aihua
通讯作者:
程爱华
作者简介:
常娟(1997—),女,硕士研究生,研究方向为水处理技术。E-mail:876474652@qq.com。
基金资助:
CLC Number:
CHANG Juan, CHENG Aihua. Preparation and Cr(Ⅵ) adsorption properties of FeS/chitosan-based carbon aerogel composites[J]. Chemical Industry and Engineering Progress, 2023, 42(11): 6042-6052.
常娟, 程爱华. FeS/壳聚糖基碳气凝胶复合材料的制备及对Cr(Ⅵ)的吸附[J]. 化工进展, 2023, 42(11): 6042-6052.
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2333
样品 | 比表面积/m2·g-1 | 孔体积/cm3·g-1 | 孔径/nm |
---|---|---|---|
CA | 45.89 | 0.008 | 19.15 |
FeS/CA-3 | 83.10 | 0.024 | 8.60 |
FeS/CA-2 | 87.95 | 0.044 | 9.05 |
FeS/CA-1 | 189.97 | 0.063 | 8.30 |
FeS/CA-0.5 | 210.32 | 0.100 | 7.40 |
FeS/CA-0.3 | 220.07 | 0.097 | 6.60 |
样品 | 比表面积/m2·g-1 | 孔体积/cm3·g-1 | 孔径/nm |
---|---|---|---|
CA | 45.89 | 0.008 | 19.15 |
FeS/CA-3 | 83.10 | 0.024 | 8.60 |
FeS/CA-2 | 87.95 | 0.044 | 9.05 |
FeS/CA-1 | 189.97 | 0.063 | 8.30 |
FeS/CA-0.5 | 210.32 | 0.100 | 7.40 |
FeS/CA-0.3 | 220.07 | 0.097 | 6.60 |
吸附剂 | 准一级动力学模型 | 准二级动力学模型 | ||||
---|---|---|---|---|---|---|
k1/min-1 | R2 | qe/mg·g-1 | k2/g·mg-1·min-1 | R2 | qe/mg·g-1 | |
CA | 0.022 | 0.972 | 31.222 | 0.029 | 0.889 | 46.211 |
FeS/CA-0.5 | 0.071 | 0.989 | 73.484 | 0.038 | 0.998 | 180.180 |
吸附剂 | 准一级动力学模型 | 准二级动力学模型 | ||||
---|---|---|---|---|---|---|
k1/min-1 | R2 | qe/mg·g-1 | k2/g·mg-1·min-1 | R2 | qe/mg·g-1 | |
CA | 0.022 | 0.972 | 31.222 | 0.029 | 0.889 | 46.211 |
FeS/CA-0.5 | 0.071 | 0.989 | 73.484 | 0.038 | 0.998 | 180.180 |
吸附剂 | 颗粒内扩散模型 | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
kd1 | C1 | R2 | kd2 | C2 | R2 | kd3 | C3 | R2 | |||
CA | 4.48 | -7.59 | 0.859 | 0.18 | 27.35 | 0.348 | — | — | — | ||
FeS/CA-0.5 | 10.65 | 58.13 | 0.924 | 4.47 | 100.64 | 0.986 | 2.09 | 133.35 | 0.927 |
吸附剂 | 颗粒内扩散模型 | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
kd1 | C1 | R2 | kd2 | C2 | R2 | kd3 | C3 | R2 | |||
CA | 4.48 | -7.59 | 0.859 | 0.18 | 27.35 | 0.348 | — | — | — | ||
FeS/CA-0.5 | 10.65 | 58.13 | 0.924 | 4.47 | 100.64 | 0.986 | 2.09 | 133.35 | 0.927 |
吸附剂 | Langmuir模型 | Freundlich模型 | ||||
---|---|---|---|---|---|---|
b | R2 | Q0/mg·g-1 | KF | R2 | n | |
CA | 0.018 | 0.990 | 46.253 | 3.004 | 0.990 | 2.053 |
FeS/CA-0.5 | 0.245 | 0.993 | 184.592 | 62.434 | 0.864 | 3.493 |
吸附剂 | Langmuir模型 | Freundlich模型 | ||||
---|---|---|---|---|---|---|
b | R2 | Q0/mg·g-1 | KF | R2 | n | |
CA | 0.018 | 0.990 | 46.253 | 3.004 | 0.990 | 2.053 |
FeS/CA-0.5 | 0.245 | 0.993 | 184.592 | 62.434 | 0.864 | 3.493 |
C0/mg·L-1 | ΔG/kJ·mol-1 | ΔH/kJ·mol-1 | ΔS/kJ·mol-1·K-1 | ||
---|---|---|---|---|---|
298 | 308 | 318 | |||
100 | -23.476 | -26.086 | -28.696 | 54.302 | 0.261 |
150 | -20.131 | -21.461 | -22.791 | 19.503 | 0.133 |
200 | -19.017 | -20.157 | -21.297 | 14.955 | 0.114 |
C0/mg·L-1 | ΔG/kJ·mol-1 | ΔH/kJ·mol-1 | ΔS/kJ·mol-1·K-1 | ||
---|---|---|---|---|---|
298 | 308 | 318 | |||
100 | -23.476 | -26.086 | -28.696 | 54.302 | 0.261 |
150 | -20.131 | -21.461 | -22.791 | 19.503 | 0.133 |
200 | -19.017 | -20.157 | -21.297 | 14.955 | 0.114 |
1 | YU Shujun, TANG Hao, ZHANG Di, et al. MXenes as emerging nanomaterials in water purification and environmental remediation[J]. Science of the Total Environment, 2022, 811: 152280. |
2 | YU Shujun, PANG Hongwei, HUANG Shuyi, et al. Recent advances in metal-organic framework membranes for water treatment: A review [J]. Science of the Total Environment, 2021, 800: 149662. |
3 | WU Zhibin, YUAN Xingzhong, ZENG Guangming, et al. Highly efficient photocatalytic activity and mechanism of Yb3+/Tm3+ codoped In2S3 from ultraviolet to near infrared light towards chromium(VI) reduction and rhodamine B oxydative degradation[J]. Applied Catalysis B: Environmental, 2018, 225: 8-21. |
4 | YU Peijing, FU Fenglian, SUN Guangzhao, et al. Effects of oxalate and citrate on the behavior and redistribution of Cr(Ⅵ) during ferrihydrite-Cr( Ⅵ ) co-precipitates transformation[J]. Chemosphere, 2021, 266: 128977. |
5 | LU Wanli, DUAN Chao, ZHANG Yanling, et al. Cellulose-based electrospun nanofiber membrane with core-sheath structure and robust photocatalytic activity for simultaneous and efficient oil emulsions separation, dye degradation and Cr(Ⅵ) reduction[J]. Carbohydrate Polymers, 2021, 258: 117676-117686. |
6 | SENGUTTUVAN S, SENTHILKUMAR P, JANAKI V, et al. Significance of conducting polyaniline based composites for the removal of dyes and heavy metals from aqueous solution and wastewaters—A review [J]. Chemosphere, 2021, 267: 129201. |
7 | 周春地, 阳婷, 闵熙泽, 等. 零价铁、铜改性生物炭及其对Cr(Ⅵ)吸附性能的影响[J]. 化工进展, 2020, 39(10): 4275-4282. |
ZHOU Chundi, YANG Ting, MIN Xize, et al. Influence of zero valent iron and copper modified biochar on Cr(Ⅵ) adsorption[J]. Chemical Industry and Engineering Progress, 2020, 39(10): 4275-4282. | |
8 | LEE Jong-hoon, PARK Soo-jin. Recent advances in preparations and applications of carbon aerogels: A review[J]. Carbon, 2020, 163: 1-18. |
9 | YANG Chen, LIU Dan, HUANG Shaoming, et al. Pressure-induced monolithic carbon aerogel from metal-organic framework[J]. Energy Storage Materials, 2020, 28: 393-400. |
10 | WANG Jingyu, LIU Wenting, LI Xiaopeng, et al. Strong hydrophilicity NiS2/Fe7S8 heterojunctions encapsulated in N-doped carbon nanotubes for enhanced oxygen evolution reaction[J]. Chemical Communications, 2020, 56(10): 1489-1492. |
11 | YU Miao, HAN Yingying, LI Jian, et al. Magnetic N-doped carbon aerogel from sodium carboxymethyl cellulose/collagen composite aerogel for dye adsorption and electrochemical supercapacitor[J].International Journal of Biological Macromolecules, 2018, 115: 185-193. |
12 | JING Zefeng, DING Jichao, ZHANG Tao, et al. Flexible, versatility and superhydrophobic biomass carbon aerogels derived from corn bracts for efficient oil/water separation[J]. Food and Bioproducts Processing, 2019, 115: 134-142. |
13 | SONG Junying, MESSELE Selamawit Ashagre, MENG Lingjun, et al. Adsorption of metals from oil sands process water (OSPW) under natural pH by sludge-based Biochar/Chitosan composite[J]. Water Research, 2021, 194: 116930. |
14 | WU Qiong, HU Jinqiu, CAO Shuangshuang, et al. Heteroatom-doped hierarchical porous carbon aerogels from chitosan for high performance supercapacitors[J]. International Journal of Biological Macromolecules, 2020, 155: 131-141. |
15 | WANG Yifan, VAN ZWIETEN Lukas, WANG Hailong, et al. Sorption of Pb(Ⅱ) onto biochar is enhanced through co-sorption of dissolved organic matter[J]. Science of The Total Environment, 2022, 825: 153686. |
16 | WANG Zhiwei, WANG Yahuan, CAO Shuai, et al. Fabrication of core@shell structural Fe-Fe2O3@PHCP nanochains with high saturation magnetization and abundant amino groups for hexavalent chromium adsorption and reduction[J]. Journal of Hazardous Materials, 2020, 384: 121483. |
17 | JIANG Xiancai, XIANG Xiaotong, PENG Shuijiao, et al. Facile preparation of nitrogen-doped activated mesoporous carbon aerogel from chitosan for methyl orange adsorption from aqueous solution[J]. Cellulose, 2019, 26(7): 4515-4527. |
18 | LI Jiahao, CHENG Rong, CHEN Jiaao, et al. Microscopic mechanism about the selective adsorption of Cr(Ⅵ) from salt solution on nitrogen-doped carbon aerogel microsphere pyrolysis products[J]. Science of the Total Environment, 2021, 798: 149331. |
19 | YUAN Yanmei, TAO Hong, FAN Jinhong, et al. Degradation of p-chloroaniline by persulfate activated with ferrous sulfide ore particles[J]. Chemical Engineering Journal, 2015, 268: 38-46. |
20 | HE Xingyu, MIN Xiaobo, PENG Tianyu, et al. Mechanochemically activated microsized zero-valent iron/pyrite composite for effective hexavalent chromium sequestration in aqueous solution[J]. Journal of Chemical & Engineering Data, 2020, 65(4): 1936-1945. |
21 | 张浩. 壳聚糖稳定的硫化亚铁磁性复合材料的制备及其对铬的去除研究[D]. 长沙: 湖南农业大学, 2019. |
ZHANG Hao. The preparation of chitosan-stabilized FeS magnetic composites and its application for chromium removal[D]. Changsha: Hunan Agricultural University, 2019. | |
22 | 郭秦铭, 崔金萍, 陈明星, 等. CA/MoS2复合物的制备及其去除六价铬的性能[J]. 浙江理工大学学报(自然科学版), 2021, 45(2): 212-220. |
GUO Qinming, CUI Jinping, CHEN Mingxing, et al. Preparation of CA/MoS2 composite and its removal of hexavalent chromium[J]. Journal of Zhejiang Sci-Tech University (Natural Sciences Edition), 2021, 45(2): 212-220. | |
23 | 孙悦. 硫化亚铁复合材料的制备及其对水中汞离子的去除性能研究[D]. 杭州: 浙江大学, 2018. |
SUN Yue. Preparation of iron sulfide composites for the removal of mercury from aqueous system[D]. Hangzhou: Zhejiang University, 2018. | |
24 | ZHANG Hao, PENG Liang, CHEN Anwei, et al. Chitosan-stabilized FeS magnetic composites for chromium removal: characterization, performance, mechanism, and stability[J]. Carbohydrate Polymers, 2019, 214: 276-285. |
25 | 郭成, 郝军杰, 李明阳, 等. 海藻酸钠/聚乙烯亚胺凝胶球的合成及对Cr(Ⅵ)的吸附性能和机制[J]. 复合材料学报, 2021, 38(7): 2140-2151. |
GUO Cheng, HAO Junjie, LI Mingyang, et al. Adsorption of Cr(Ⅵ) on porous sodium alginate/polyethyleneimine hydrogel beads and its mechanistic study[J]. Acta Materiae Compositae Sinica, 2021, 38(7): 2140-2151. | |
26 | CHEN Yongjun, MA Rui, PU Xunchi, et al. The characterization of a novel magnetic biochar derived from sulfate-reducing sludge and its application for aqueous Cr(Ⅵ) removal through synergistic effects of adsorption and chemical reduction[J]. Chemosphere, 2022, 308: 136258. |
27 | SUN Zhichao, LIU Yunguo, HUANG Yuanqing, et al. Fast adsorption of Cd2+ and Pb2+ by EGTA dianhydride (EGTAD) modified ramie fiber [J]. Journal of Colloid and Interface Science, 2014, 434: 152-158. |
[1] | WANG Shengyan, DENG Shuai, ZHAO Ruikai. Research progress on carbon dioxide capture technology based on electric swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 233-245. |
[2] | ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286. |
[3] | HU Xi, WANG Mingshan, LI Enzhi, HUANG Siming, CHEN Junchen, GUO Bingshu, YU Bo, MA Zhiyuan, LI Xing. Research progress on preparation and sodium storage properties of tungsten disulfide composites [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 344-355. |
[4] | CUI Shoucheng, XU Hongbo, PENG Nan. Simulation analysis of two MOFs materials for O2/He adsorption separation [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 382-390. |
[5] | CHEN Chongming, CHEN Qiu, GONG Yunqian, CHE Kai, YU Jinxing, SUN Nannan. Research progresses on zeolite-based CO2 adsorbents [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 411-419. |
[6] | XU Chunshu, YAO Qingda, LIANG Yongxian, ZHOU Hualong. Research progress on functionalization strategies of covalent organic frame materials and its adsorption properties for Hg(Ⅱ) and Cr(Ⅵ) [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 461-478. |
[7] | GU Yongzheng, ZHANG Yongsheng. Dynamic behavior and kinetic model of Hg0 adsorption by HBr-modified fly ash [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 498-509. |
[8] | GUO Qiang, ZHAO Wenkai, XIAO Yonghou. Numerical simulation of enhancing fluid perturbation to improve separation of dimethyl sulfide/nitrogen via pressure swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 64-72. |
[9] | GE Yafen, SUN Yu, XIAO Peng, LIU Qi, LIU Bo, SUN Chengying, GONG Yanjun. Research progress of zeolite for VOCs removal [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4716-4730. |
[10] | YANG Ying, HOU Haojie, HUANG Rui, CUI Yu, WANG Bing, LIU Jian, BAO Weiren, CHANG Liping, WANG Jiancheng, HAN Lina. Coal tar phenol-based carbon nanosphere prepared by Stöber method for adsorption of CO2 [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 5011-5018. |
[11] | ZHANG Zhen, LI Dan, CHEN Chen, WU Jinglan, YING Hanjie, QIAO Hao. Separation and purification of salivary acids with adsorption resin [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4153-4158. |
[12] | TANG Lei, ZENG Desen, LING Ziye, ZHANG Zhengguo, FANG Xiaoming. Research progress of phase change materials and their application systems for cool storage [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4322-4339. |
[13] | JIANG Jing, CHEN Xiaoyu, ZHANG Ruiyan, SHENG Guangyao. Research progress of manganese-loaded biochar preparation and its application in environmental remediation [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4385-4397. |
[14] | YU Jingwen, SONG Luna, LIU Yanchao, LYU Ruidong, WU Mengmeng, FENG Yu, LI Zhong, MI Jie. An indole-bearing hypercrosslinked polymer In-HCP for iodine adsorption from water [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3674-3683. |
[15] | LI Yanling, ZHUO Zhen, CHI Liang, CHEN Xi, SUN Tanglei, LIU Peng, LEI Tingzhou. Research progress on preparation and application of nitrogen-doped biochar [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3720-3735. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 Copyright © Chemical Industry and Engineering Progress, All Rights Reserved. E-mail: hgjz@cip.com.cn Powered by Beijing Magtech Co. Ltd |