Synthesis of polyamine-type polystyrene resin and its adsorption property for Cu2+

doi:10.16085/j.issn.1000-6613.2016.10.033

Chemical Industry and Engineering Progree ›› 2016, Vol. 35 ›› Issue (10): 3258-3262.DOI: 10.16085/j.issn.1000-6613.2016.10.033

• Material science and technology • Previous Articles Next Articles

Synthesis of polyamine-type polystyrene resin and its adsorption property for Cu²⁺

MENG Qi, LÜ Kehan, XIA Fengmin, NI Mengyi

Petrochemical Institute of Changzhou University, Changzhou 213164, Jiangsu, China

Received:2016-02-23 Revised:2016-03-12 Online:2016-10-05 Published:2016-10-05

多胺型聚苯乙烯树脂的合成及对Cu²⁺的吸附性能

孟启, 吕科翰, 夏丰敏, 倪梦燚

常州大学石油化工学院, 江苏常州 213164

通讯作者: 孟启(1965-),男,博士,教授,从事有机合成及化工清洁化研究。E-mail:mengqi@cczu.edu.cn
作者简介:孟启(1965-),男,博士,教授,从事有机合成及化工清洁化研究。E-mail:mengqi@cczu.edu.cn。
基金资助:
江苏省高校自然科学重大基础研究项目（08KJA430001）。

Abstract

Abstract: A polyamine-type polystyrene resin with tetraethylenepentamine functional group was synthesized from polystyrene resin through chloroacetylation followed by the amination of tetraethylenepentamine. Effects of reaction solvent,mole ratio of raw materials,time and temperature were discussed. The adsorption property of the polyamine-type polystyrene resin for Cu²⁺ was also studied. The results show that the synthetic reactions can take place smoothly in THF at room temperature and the complete exchange capacity of the synthesized resin is 7.45 mmol/g. The adsorption processes of Cu²⁺ can be described by pseudo-second order kinetic equation. The main control step of resin adsorption for Cu²⁺ is governed by liquid film diffusion. The adsorption of Cu²⁺ belongs to the Langmuir adsorption model and was valid for single-layer adsorption. The saturated adsorption capacity of the synthesized resin toward Cu²⁺ is 46.15mg/mL. The Cu²⁺ can be removed selectively from the mixed solution of Cu²⁺ and Ni²⁺ by the synthesized resin adsorption.

Key words: tetraethylenepentamine, resin, synthesis, adsorption, copper ion

摘要： 以聚苯乙烯树脂为起始原料，经氯乙酰化后与四乙烯五胺反应，合成了一种含四乙烯五胺功能基的多胺型聚苯乙烯树脂。考察了溶剂、物料比、时间和温度等反应条件对树脂合成的影响，研究了树脂对Cu²⁺的吸附性能。结果表明，合成反应在THF溶剂中室温即可顺利进行，所得树脂全交换容量为7.45mmol/g。树脂对Cu²⁺的吸附可以用准二级动力学方程来描述，液膜扩散为吸附主要控制步骤，吸附符合Langmuir等温方程，为单分子层吸附，饱和吸附量为46.15 mg/mL。对于Cu²⁺、Ni²⁺混合溶液，该树脂可以选择性吸附其中Cu²⁺。

关键词: 四乙烯五胺, 树脂, 合成, 吸附, 铜离子

CLC Number:

O632.6

MENG Qi, LÜ Kehan, XIA Fengmin, NI Mengyi. Synthesis of polyamine-type polystyrene resin and its adsorption property for Cu²⁺[J]. Chemical Industry and Engineering Progree, 2016, 35(10): 3258-3262.

孟启, 吕科翰, 夏丰敏, 倪梦燚. 多胺型聚苯乙烯树脂的合成及对Cu²⁺的吸附性能[J]. 化工进展, 2016, 35(10): 3258-3262.

References

[1] JESSE J.A,EDWARD R,ERIK J,et al.Sol-gel synthesis and characterization of silica polyamine composites:applications to metal ion capture[J].ACS Applied Materials&Interfaces,2012,4(3):1573-1584.
[2] CHEN Taipeng,LIU Fuqiang,LING Chen,et al.Insight into highly efficient coremoval of copper and p nitrophenol by a newly synthesized polyamine chelating resin from aqueous media:competition and enhancement effect upon site recognition[J].Environmental Science&Technology,2013,47(23):13652-13660.
[3] QU Rongjun,LIU Jianhui,SUN Changmei,et al.Removal and separation of Hg (Ⅱ) ions from aqueous solutions by macroporous polystyrene-co-divinylbenzene-supported polyamine chelating resins[J].Journal of Chemical&Engineering Data,2010,55(11):4650-4659.
[4] 何炳林,黄文强.离子交换与吸附树脂[M].上海:上海科技教育出版社,1995:353-354.
[5] ANDRWW J C,JOANNA V G,STEPHEN T,al et.Solid-supported copper catalysts for atom-transfer radical cyclizations:assessment of support type and ligand structure on catalyst performance in the synthesis of nitrogen heterocycles[J].Journal of Organic Chemistry,2006,71(4):1471-1479.
[6] EDWARD K,ANTON M,YULIA K,al et.Pd nanoparticles in dendrimers immobilized on silica-polyamine composites as catalysts for selective hydrogenation[J].ACS Applied Materials&Interfaces,2014,6(11):8807-8816.
[7] ANNA M,HANS-JUERGEN P A.Grafting of amino functional monomer onto initiator-modified polystyrene particles[J].Langmuir,2005,21(6):2209-2217.
[8] 张晓晓,魏荣卿,刘晓宁,等.氯乙酰化聚苯乙烯树脂的胺基化反应[J].化工进展,2008,27(5):715-719.
[9] 周赟,晏欣,周立清.多乙烯多胺胺化大孔GMA-DVB树脂的合成及其对金属离子的吸附[J].化工学报,2011,62(11):3288-3294.
[10] 魏荣卿,王强,刘晓宁,等.氯乙酰化聚苯乙烯型固相载体的制备[J].离子交换与吸附,2005,21(4):289-296.
[11] CHEN Chuhyean,CHIANG Chenli,CHEN Chuhrou.Removal of heavy menal ions by a chelating resin containing glycine as chelating groups[J].Separation and Purification Technology,2007,54(3):396-403.
[12] LAGERGERN S.About the theory of so-called adsorption of soluble substances[J].Kungllga Svenska Vetenskapsakademiens Handlingar,1898,24(4):31-39.
[13] YURY A S.Carboxyethylated polyaminostyrene for selective copper removal[J].Polymer Bulletin,2012,68(4):1065-1078.
[14] GANDHI M R,VISWANATHAN N,MEENAKSHI S.Adsorption mechanism of hexavalent chromium removal using Amberlite IRA 743 resin[J].Ion Exchange Letters,2010,3:25-35.
[15] KADOUS A,DIDI M A,VILLEMIN D,et al.A new sorbent for uranium extraction:ethylenediamino tris (methylenephosphonic) acid grafted on polystyrene resin[J].Journal of Radioanalytical and Nuclear Chemistry,2010,284(2):431-438.

Synthesis of polyamine-type polystyrene resin and its adsorption property for Cu²⁺

多胺型聚苯乙烯树脂的合成及对Cu²⁺的吸附性能

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	SHI Yongxing, LIN Gang, SUN Xiaohang, JIANG Weigeng, QIAO Dawei, YAN Binhang. Research progress on active sites in Cu-based catalysts for CO₂ hydrogenation to methanol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 287-298.
[2]	CUI Shoucheng, XU Hongbo, PENG Nan. Simulation analysis of two MOFs materials for O₂/He adsorption separation [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 382-390.
[3]	ZHAO Wei, ZHAO Deyin, LI Shihan, LIU Hongda, SUN Jin, GUO Yanqiu. Synthesis and application of triazine drag reducing agent for nature gas pipeline [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 391-399.
[4]	WANG Zhengkun, LI Sifang. Green synthesis of gemini surfactant decyne diol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 400-410.
[5]	CHEN Chongming, CHEN Qiu, GONG Yunqian, CHE Kai, YU Jinxing, SUN Nannan. Research progresses on zeolite-based CO₂ adsorbents [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 411-419.
[6]	XU Chunshu, YAO Qingda, LIANG Yongxian, ZHOU Hualong. Research progress on functionalization strategies of covalent organic frame materials and its adsorption properties for Hg(Ⅱ) and Cr(Ⅵ) [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 461-478.
[7]	GU Yongzheng, ZHANG Yongsheng. Dynamic behavior and kinetic model of Hg⁰ adsorption by HBr-modified fly ash [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 498-509.
[8]	GUO Qiang, ZHAO Wenkai, XIAO Yonghou. Numerical simulation of enhancing fluid perturbation to improve separation of dimethyl sulfide/nitrogen via pressure swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 64-72.
[9]	WANG Shengyan, DENG Shuai, ZHAO Ruikai. Research progress on carbon dioxide capture technology based on electric swing adsorption [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 233-245.
[10]	WANG Weitao, BAO Tingyu, JIANG Xulu, HE Zhenhong, WANG Kuan, YANG Yang, LIU Zhaotie. Oxidation of benzene to phenol over aldehyde-ketone resin based metal-free catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4706-4715.
[11]	GE Yafen, SUN Yu, XIAO Peng, LIU Qi, LIU Bo, SUN Chengying, GONG Yanjun. Research progress of zeolite for VOCs removal [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4716-4730.
[12]	SONG Weitao, SONG Huiping, FAN Zhenlian, FAN Biao, XUE Fangbin. Research progress of fly ash in anti-corrosion coatings [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4894-4904.
[13]	YANG Ying, HOU Haojie, HUANG Rui, CUI Yu, WANG Bing, LIU Jian, BAO Weiren, CHANG Liping, WANG Jiancheng, HAN Lina. Coal tar phenol-based carbon nanosphere prepared by Stöber method for adsorption of CO₂ [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 5011-5018.
[14]	ZHANG Zhen, LI Dan, CHEN Chen, WU Jinglan, YING Hanjie, QIAO Hao. Separation and purification of salivary acids with adsorption resin [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4153-4158.
[15]	XIANG Yang, HUANG Xun, WEI Zidong. Recent progresses in the activity and selectivity improvement of electrocatalytic organic synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4005-4014.