Chemical Industry and Engineering Progress ›› 2017, Vol. 36 ›› Issue (09): 3422-3428.DOI: 10.16085/j.issn.1000-6613.2016-2425

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Preparation of electrochemical removal lead ion imprinted composite film and its performance

LIU Xiuhong, WANG Yonghong, LIU Chengcen, HOU Mengjie, LI Long   

  1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China
  • Received:2016-12-28 Revised:2017-03-31 Online:2017-09-05 Published:2017-09-05

电化学脱除Pb2+印迹复合膜的制备及其性能

刘秀红, 王永洪, 刘成岑, 侯蒙杰, 李龙   

  1. 太原理工大学化学化工学院, 山西 太原 030024
  • 通讯作者: 王永洪,博士,副教授,硕士生导师。
  • 作者简介:刘秀红(1992-),女,硕士研究生,研究方向为电活性材料、水处理、重金属分离。E-mail:lxh547882@163.com
  • 基金资助:
    山西省青年科技研究基金(2015021061)及太原理工大学校基金(2015MS014)项目。

Abstract: Ion-surface imprinting technology has been widely used to remove heavy metal ions existed in waste water,due to its high selectivity to the target ions and good chemical stability. In this paper, electroactive surface-imprinted composite film was prepared successfully using Pb2+ as the template ion, polyaniline(PANI)as the polymer matrix and hydroxylated carbon nanotubes(MWCNTs-OH)as imprinting substrate, during which,Pb2+ ions were eluted by applying constant positive potential to form imprinted cavities. The structures of MWCNTs-OH and imprinted film were characterized by Fourier transform infrared(FTIR)and X-ray diffraction(XRD). The Pb2+ ion separation performance of the film was studied by electrochemical quartz crystal microbalance(EQCM)and atomic absorption spectrophotometer(AAS).The results showed that the maximum ion exchange capacity of composite film was 359mg/g and had excellent selectivity for Pb2+at the presence of other heavy metals ions(Cd2+,Zn2+,Co2+,Ni2+),with the separation factor of Pb2+/Zn2+ reached 418.74. Besides, the film exhibited outstanding cycle stability and rapid adsorption/desorption properties. In conclusion, this novel ion-surface imprinted composite film can be used for the efficient separation and recovery of Pb2+ in wastewater.

Key words: ion-surface imprinting, electrochemistry, separation, lead ions, waste water

摘要: 离子表面印迹技术对目标离子具有较高的选择性和良好的化学稳定性,在去除废水中的重金属离子技术中得到广泛运用。本文以Pb2+为模板离子,聚苯胺(PANI)为高分子基体,羟基化碳纳米管(MWCNTs-OH)为印迹载体,施加恒定正电位洗脱Pb2+形成印迹孔穴,成功制备出具有电活性的Pb2+表面印迹复合膜。采用傅里叶红外(FTIR)和X射线衍射(XRD)对MWCNTs-OH和印迹复合膜进行结构表征。借助电化学石英晶体微天平(EQCM)和原子吸收分光光度计(AAS)对印迹复合膜的Pb2+分离性能进行研究。结果表明,离子印迹复合膜对Pb2+的交换量可达359mg/g,且在掺杂了其他重金属离子(Cd2+、Zn2+、Co2+、Ni2+)的含Pb2+溶液中对Pb2+表现出良好的选择性,其中Pb2+/Zn2+的分离因子可达418.74。此外,复合膜具有优异的循环稳定性和快速吸脱附速率。这种新型的离子表面印迹复合膜有望用于废水中重金属Pb2+的高效分离与回收。

关键词: 离子表面印迹, 电化学, 分离, 铅离子, 废水

CLC Number: 

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