钛系锂离子筛用于盐湖提锂的研究进展

doi:10.16085/j.issn.1000-6613.2021-0465

化工进展 ›› 2021, Vol. 40 ›› Issue (S1): 1-12.DOI: 10.16085/j.issn.1000-6613.2021-0465

钛系锂离子筛用于盐湖提锂的研究进展

路青强¹(), 陈琳琳²(), 巢艳红³, 李小为², 蒋磊⁴, 朱文帅²()

^1.江苏大学材料科学与工程学院，江苏镇江 212013
^2.江苏大学化学化工学院，江苏镇江 212013
^3.江苏大学药学院，江苏镇江 212013
^4.江苏特丰新材料科技有限公司，江苏镇江 212001

收稿日期:2021-03-08 修回日期:2021-03-22 出版日期:2021-10-25 发布日期:2021-11-09
通讯作者: 朱文帅
作者简介:路青强（1996—），男，硕士研究生，研究方向为锂资源的提取。E-mail：18852869385@163.com|陈琳琳（1989—），女，博士后，讲师，研究方向为吸附与分离。E-mail：chenllujs@ujs.edu.cn。
基金资助:
国家自然科学基金(21908082);江苏省自然科学基金(BK20190854);中国博士后科学基金(2020M671364);镇江市科技基金(GY2020027)

Research progress of titanium-based lithium ion sieve for extracting lithium from salt lake brine

LU Qingqiang¹(), CHEN Linlin²(), CHAO Yanhong³, LI Xiaowei², JIANG Lei⁴, ZHU Wenshuai²()

^1.School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China
^2.School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China
^3.School of Pharmacy, Jiangsu University, Zhenjiang 212013, Jiangsu, China
^4.Jiangsu Topfine New Materials Science & Technology Co. , Ltd. , Zhenjiang 212013, Jiangsu, China

Received:2021-03-08 Revised:2021-03-22 Online:2021-10-25 Published:2021-11-09
Contact: ZHU Wenshuai

摘要/Abstract

摘要：

随着新能源行业在世界范围内的快速发展，金属锂因其能量密度高等优势被广泛应用，从蕴含大量锂资源的盐湖卤水中提锂是获取锂资源的重要方向。盐湖提锂的方法主要有碳化法、沉淀法、离子筛吸附法、电化学辅助法等。离子筛吸附法适合从浓度低的液相中选择性回收锂，其中钛系锂离子筛因其稳定性强、吸附容量大而成为吸附法的研究热点。本文以钛系锂离子筛技术为立足点，对全球锂资源分布现状、钛系锂离子筛提锂机理进行了分析，综述了目前钛氧化物锂离子筛的合成方法、成型方法、现存的问题等，为后续开发新型钛系锂离子筛，提高饱和吸附容量等方面提供参考。

关键词: 液态锂资源, 离子交换, 吸附剂, 钛系锂离子筛, 选择性

Abstract:

With the rapid development of the new energy industry, lithium is widely used because of its high energy density, extracting lithium from salt lake brine is an important way to obtain lithium resources. The main methods of extracting lithium from salt lake brine are carbonization, precipitation, ion-sieve adsorption, and electrochemical method. Ion sieve adsorption method is suitable for selective recovery of lithium from low concentration liquid phase. Titanium-based lithium ion sieve has become a research hotspot because of its strong stability and large adsorption capacity. Based on the titanium-based lithium ion sieve technology, this paper analyzes the global lithium resource distribution and the lithium extraction mechanism of titanium-based lithium ion sieve, and summarizes the synthesis methods, molding methods and existing problems of titanium-based lithium ion sieve, so as to provide reference for the subsequent development of new titanium lithium ion sieve and the improvement of saturated adsorption capacity.

Key words: liquid lithium resource, ion exchange, adsorbents, titanium-based lithium ion sieve, selectivity

中图分类号:

O614.111

路青强, 陈琳琳, 巢艳红, 李小为, 蒋磊, 朱文帅. 钛系锂离子筛用于盐湖提锂的研究进展[J]. 化工进展, 2021, 40(S1): 1-12.

LU Qingqiang, CHEN Linlin, CHAO Yanhong, LI Xiaowei, JIANG Lei, ZHU Wenshuai. Research progress of titanium-based lithium ion sieve for extracting lithium from salt lake brine[J]. Chemical Industry and Engineering Progress, 2021, 40(S1): 1-12.

图/表 10

图1 全球锂资源分布现状[22]

图2 从锂矿中提取锂的流程示意图[24]

图3 锂离子筛吸附锂离子示意图

图4 TiO2纳米带（TO）、Li2TiO3前体（LTO）和TiO2离子筛（STO）的TEM图像[44]

图5 Fe掺杂的H2TiO3的表面形貌、EDX元素分析以及透射电镜（TEM）图[47]

图6 层状结构Li2TiO3、H2TiO3和Li交换后的H2TiO3[51]

图7 多孔Li4Ti5O12脱锂/提取过程[55]

图8 改进固相法合成的锂离子筛颗粒尺寸分布[59]

图9 TiO2纳米管在150℃下反应不同时间的表面形貌图[56]

图10 PMMA为模板的Li4Ti5-xZrxO12表面形貌图[67]

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钛系锂离子筛用于盐湖提锂的研究进展

Research progress of titanium-based lithium ion sieve for extracting lithium from salt lake brine

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