变形铝合金表面锆基化学转化膜的研究现状

doi:10.16085/j.issn.1000-6613.2020-0107

摘要/Abstract

摘要：

化学转化膜是金属表面主要的处理方法之一，具备良好的附着力和耐蚀性，能为铝合金提供一定的临时防护。传统的六价铬酸盐化学转化膜在日渐严苛的环保压力下已经逐渐淘汰，取而代之的是近几年发展迅猛的三价铬及无铬锆基化学转化膜。铝合金可分为铸造铝合金和变形铝合金，按照所含主要合金元素和热处理状态可分为若干个系列和型号。本文选取几种典型的变形铝合金，综述了不同铝合金微观组织对转化膜成膜过程的影响，化学转化液添加剂、预处理和后处理工艺对转化膜性能的调控及作用机理，以及几种典型商业钝化剂在变形铝合金表面的应用。总结了目前变形铝合金表面锆基化学转化膜仍面临的问题和发展趋势，未来化学转化膜需在满足新型铝合金发展要求的基础上，通过不同有机、无机添加剂以及外场作用对转化膜的成膜均一性、完整性进行调控，以提高转化膜的综合性能。

关键词: 铝合金, 表面, 化学转化, 膜, 制备, 耐蚀性

Abstract:

Chemical conversion coating is an important surface treatment method of aluminum alloy, which has good adhesion and corrosion resistance and can provide temporary protection for aluminum alloy surface. The traditional hexavalent chromate chemical conversion coatings has been gradually eliminated under the increasingly severe environmental pressure and replaced by the rapid development of zirconium-based chemical conversion coating in recent years. Aluminum alloy can be divided into cast aluminum alloy and wrought aluminum alloy. According to the main alloy elements and heat treatment status, it can be divided into several series and models. In this paper, the influence of the microstructure of several typical wrought aluminum alloys on the conversion coating forming process, the regulation of passivation solution additives, pretreatment and post-treatment process on the corrosion resistance of the conversion coating and the application of several typical commercial passivators on the surface of the aluminum alloy were reviewed. Finally, the problems and development trend of zirconium-based chemical conversion coating on aluminum alloy surface were summarized. On the basis of meeting the requirements of the development of new aluminum alloy, the uniformity and integrity of the conversion coating should be regulated by different organic and inorganic additives and field effect, so as to improve the comprehensive performance of the conversion coating.

Key words: aluminum alloy, surface, chemical conversion, coating, preparation, corrosion resistance

中图分类号:

TG174.4

潘杰, 李焰. 变形铝合金表面锆基化学转化膜的研究现状[J]. 化工进展, 2020, 39(11): 4503-4515.

Jie PAN, Yan LI. Research progress of zirconium-based chemical conversion coatings on typical wrought aluminum alloys[J]. Chemical Industry and Engineering Progress, 2020, 39(11): 4503-4515.

参考文献

1	DURSUN T, SOUTIS C. Recent developments in advanced aircraft aluminium alloys[J]. Materials and Design, 2014, 56: 862-871.
2	邓运来, 张新明. 铝及铝合金材料进展[J]. 中国有色金属学报, 2019, 29(9): 2115-2141.
2	DENG Y L, ZHANG X M. Development of aluminium and aluminium alloy[J]. The Chinese Journal of Nonferrous Metals,2019, 29(9): 2115-2141.
3	卢勇, 冯辉霞, 张晓芳. 金属表面植酸转化膜研究进展[J]. 材料导报, 2019, 33(5): 1455-1461.
3	LU Y, FENG H X, ZHANG X F. An overview on study of phytic acid conversion coatings on metal surface[J]. Materials Reports, 2019, 33(5): 1455-1461.
4	GIGANDET M P, FAUCHEU J, TACHEZ M. Formation of black chromate conversion coatings on pure and zinc alloy electrolytic deposits: role of the main constituents[J]. Surface and Coatings Technology, 1997, 89(3): 285-291.
5	BIBBER J W. Non-chrome-containing conversion coatings for zinc and zinc alloys: environmentally friendly alternatives provide equal or better adhesion and corrosion resistance as conventional methods[J]. Metal Finishing, 2008, 106(4): 41-46.
6	KENDIG M, JEANJAQUET S, ADDISON R, et al. Role of hexavalent chromium in the inhibition of corrosion of aluminum alloys[J]. Surface and Coatings Technology, 2001, 140(1): 58-66.
7	TREACY G M, WILCOX G D. Surface analytical study of the corrosion behaviour of chromate passivated Al 2014 A T-6 during salt fog exposure[J]. Applied Surface Science, 2000, 157(1): 7-13.
8	KENDIG M W, BUCHHEIT R G. Corrosion inhibition of aluminum and aluminum alloys by soluble chromates, chromate coatings, and chromate-free coatings[J]. Corrosion, 2003, 59(5): 379-400.
9	DOERRE M, HIBBITTS L, PATRICK G, et al. Advances in automotive conversion coatings during pretreatment of the body structure: a review[J]. Coatings, 2018, 8(11): 405-421.
10	CHEN X B, BIRBILIS N, ABBOTT T B. Review of corrosion-resistant conversion coatings for magnesium and its alloys[J]. Corrosion, 2011, 67(3): 035005-1-035005-16.
11	朱青. 化学转化膜在镁合金表面的研究进展[J]. 金属功能材料, 2018, 25(3): 50-54.
11	ZHU Q. Study of chemical conversion film on the surface of magnesium alloy[J]. Metallic Functional Materials, 2018, 25(3): 50-54.
12	GAO Z, ZHANG D, LI X, et al. Current status, opportunities and challenges in chemical conversion coatings for zinc[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 546: 221-236.
13	TWITE R L, BIERWAGEN G P. Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys[J]. Progress in Organic Coatings, 1998, 33(2): 91-100.
14	杨显芳, 梁天权, 韦唯, 等. 环保型铝合金表面转化处理的研究进展[J]. 材料导报, 2014, 28(S2): 439-442.
14	YANG X F, LIANG T Q, WEI W, et al. Progress of environment-friendly chemical surface treatment of aluminum alloys[J]. Materials Review, 2014, 28(S2): 439-442.
15	秦振华, 李红玲. 铝及铝合金无铬化学转化膜工艺的研究进展[J]. 腐蚀科学与防护技术, 2014, 26(3): 269-272.
15	QIN Z H, LI H L. Research progress of chromium free chemical conversion coating technology for aluminum and aluminum alloy[J]. Corrosion Science and Protection Technology, 2014, 26(3): 269-272.
16	CEREZO J, VANDENDAEL I, POSNER R, et al. The effect of surface pre-conditioning treatments on the local composition of Zr-based conversion coatings formed on aluminium alloys[J]. Applied Surface Science, 2016, 366: 339-347.
17	SHARIFI GOLRU S, ATTAR M M, RAMEZANZADEH B. Effects of surface treatment of aluminium alloy 1050 on the adhesion and anticorrosion properties of the epoxy coating[J]. Applied Surface Science, 2015, 345: 360-368.
18	SHARIFI GOLRU S, ATTAR M M, RAMEZANZADEH B. Morphological analysis and corrosion performance of zirconium based conversion coating on the aluminum alloy 1050[J]. Journal of Industrial and Engineering Chemistry, 2015, 24: 233-244.
19	MILO?EV I, FRANKEL G S. Review-conversion coatings based on zirconium and/or titanium[J]. Journal of the Electrochemical Society, 2018, 165(3): C127-C144.
20	NORDLIEN J H, WALMSLEY J C, ?STERBERG H, et al. Formation of a zirconium-titanium based conversion layer on AA 6060 aluminium[J]. Surface & Coatings Technology, 2002, 153(1): 72-78.
21	SMIT M A, HUNTER J A, SHARMAN J D B, et al. Effects of thermal and mechanical treatments on a titanium-based conversion coating for aluminium alloys[J]. Corrosion Science, 2004, 46(7): 1713-1727.
22	LI L, SWAIN G P, HOWELL A, et al. The formation, structure, electrochemical properties and stability of trivalent chrome process (TCP) coatings on AA2024[J]. Journal of the Electrochemical Society, 2011, 158(9): C274-C283.
23	LI L, WHITMAN B W, SWAIN G M. Characterization and performance of a Zr/Ti pretreatment conversion coating on AA2024-T3[J]. Journal of The Electrochemical Society, 2015, 162(6): C279-C284.
24	KHUN N W, FRANKEL G S, ZIMMERMAN J. Investigation of surface morphology, wear resistance, and adhesiveness of AA6061-T6 treated in a hexafluorozirconic acid-based solution[J]. Corrosion, 2013, 69(3): 259-267.
25	CEREZO J, VANDENDAEL I, POSNER R, et al. Initiation and growth of modified Zr-based conversion coatings on multi-metal surfaces[J]. Surface and Coatings Technology, 2013, 236: 284-289.
26	CEREZO J, TAHERI P, VANDENDAEL I, et al. Influence of surface hydroxyls on the formation of Zr-based conversion coatings on AA6014 aluminum alloy[J]. Surface and Coatings Technology, 2014, 254: 277-283.
27	CEREZO J, POSNER R, VANDENDAEL I, et al. The effect of conversion bath convection on the formation of Zr-based thin-film coatings on multi-metal surfaces[J]. Materials and Corrosion, 2016, 67(4): 361-367.
28	SARFRAZ A, POSNER R, LANGE M M, et al. Role of intermetallics and copper in the deposition of ZrO₂ conversion coatings on AA6014[J]. Journal of the Electrochemical Society, 2014, 161(12): C509-C516.
29	LI L, DESOUZAC A L, SWAIN G M. In situ pH measurement during the formation of conversion coatings on an aluminum alloy (AA2024)[J]. Analyst, 2013, 138: 4398-4402.
30	PENG D, WU J, YAN X, et al. The formation and corrosion behavior of a zirconium-based conversion coating on the aluminum alloy AA6061[J]. Journal of Coatings Technology and Research, 2016, 13(5): 837-850.
31	LUNDER O, SIMENSEN C, YU Y, et al. Formation and characterisation of Ti-Zr based conversion layers on AA6060 aluminium[J]. Surface and Coatings Technology, 2004, 184(2/3): 278-290.
32	SUIB S L, SCALA J LA, NICKERSON W, et al. Determination of hexavalent chromium in NAVAIR trivalent chromium process (TCP) coatings and process solutions[J]. Metal Finishing, 2009, 107(2): 28-31.
33	LI L, WHITMAN B W, MUNSON C A, et al. Structure and corrosion performance of a non-chromium process (NCP) Zr/Zn pretreatment conversion coating on aluminum alloys[J]. Journal of the Electrochemical Society, 2016, 163(13): C718-C728.
34	CARREIRA A F, PEREIRA A M, VAZ E P, et al. Alternative corrosion protection pretreatments for aluminum alloys[J]. Journal of Coatings Technology and Research, 2017, 14(4): 879-892.
35	QI J, HASHIMOTO T, WALTON J, et al. Formation of a trivalent chromium conversion coating on AA2024-T351 alloy[J]. Journal of the Electrochemical Society, 2016, 163(2): C25-C35.
36	QI J, GAO L, LIU Y, et al. Chromate formed in a trivalent chromium conversion coating on aluminum[J]. Journal of the Electrochemical Society, 2017, 164(7): C442-C449.
37	SHRUTHI T K, SWAIN G M. Detection of H₂O₂ from the reduction of dissolved oxygen on TCP-coated AA2024-T3: impact on the transient formation of Cr(Ⅵ)[J]. Journal of the Electrochemical Society, 2019, 166(11): C3284-C3289.
38	KHARITONOV D S, SOMMERTUNE J, ?RNEK C, et al. Corrosion inhibition of aluminium alloy AA6063-T5 by vanadates: oclal surface chemical events elucidated by confocal Raman micro-spectroscopy[J]. Corrosion Science, 2019, 148: 237-250.
39	CAMPESTRINI P, WESTING E P M VAN, DE WIT J H W. Influence of surface preparation on performance of chromate conversion coatings on alclad 2024 aluminium alloy part Ⅱ: EIS investigation[J]. Electrochimica Acta, 2002, 46(17): 2631-2647.
40	HASHIMOTO T, ZHANG X, ZHOU X, et al. Investigation of dealloying of S phase (Al₂CuMg) in AA 2024-T3 aluminium alloy using high resolution 2D and 3D electron imaging[J]. Corrosion Science, 2016, 103: 157-164.
41	CAMPESTRINI P, TERRYN H, VEREECHEN J, et al. Chromate conversion coating on aluminum alloys Ⅱ: effect of the microstructure[J]. Journal of the Electrochemical Society, 2004, 151(6): B359-B369.
42	SAILLARD R, VIGUIER B, ODEMER G, et al. Influence of the microstructure on the corrosion behaviour of 2024 aluminium alloy coated with a trivalent chromium conversion layer[J]. Corrosion Science, 2018, 142: 119-132.
43	GEORGE F O, SKELDON P, THOMPSON G E. Formation of zirconium-based conversion coatings on aluminium and Al-alloys[J]. Corrosion Science, 2012, 65: 231-237.
44	DONG X, WANG P, ARGEKAR S, et al. Structure and composition of trivalent chromium process (TCP) films on Al alloy[J]. Langmuir, 2010, 26(13): 10833-10841.
45	DONG X, ARGEKAR S, WANG P, et al. In situ evolution of trivalent chromium process passive film on Al in a corrosive aqueous environment[J]. ACS Applied Materials Interfaces, 2011, 3(11): 4206-4214.
46	QI J, GAO L, LI Y, et al. An optimized trivalent chromium conversion coating process for AA2024-T351 alloy[J]. Journal of the Electrochemical Society, 2017, 164(7): C390-C395.
47	张博, 赵焕, 董宇, 等. 2024铝合金表面有色钛锆转化膜的制备与性能研究[J]. 材料保护, 2018, 51(7): 1-5.
47	ZHANG B, ZHAO H, DONG Y. Preparation and performance of colored Ti-Zr conversion coating on 2024 aluminum alloy[J]. Materials Protection, 2018, 51(7): 1-5.
48	YOGANANDAN G, PRADEEP PREMKUMAR K, BALARAJU J N. Evaluation of corrosion resistance and self-healing behavior of zirconium-cerium conversion coating developed on AA2024 alloy[J]. Surface and Coatings Technology, 2015, 270: 249-258.
49	LI L, DESOUZA A L, SWAIN G M. Effect of deoxidation pretreatment on the corrosion inhibition provided by a trivalent chromium process (TCP) conversion coating on AA2024-T3[J]. Journal of the Electrochemical Society, 2014, 161(5): C246-C253.
50	VERDALET-GUARDIOLA X, BONINO J, DULUARD S, et al. Influence of the alloy microstructure and surface state on the protective properties of trivalent chromium coatings grown on a 2024 aluminium alloy[J]. Surface and Coatings Technology, 2018, 344: 276-287.
51	QI J, NEMCOVA A, WALTON J R, et al. Influence of pre- and post-treatments on formation of a trivalent chromium conversion coating on AA2024 alloy[J]. Thin Solid Films, 2016, 616: 270-278.
52	VIROULAUD R, ?WIATOWSKA J, SEYEUX A, et al. Influence of surface pretreatments on the quality of trivalent chromium process coatings on aluminum alloy[J]. Applied Surface Science, 2017, 423: 927-938.
53	LI L, SWAIN G M. Effects of aging temperature and time on the corrosion protection provided by trivalent chromium process coatings on AA2024-T3[J]. ACS Applied Materials Interfaces, 2013, 5(16): 7923-30.
54	STOICA A, ?WIATOWSKA J, ROMAINE A, et al. Influence of post-treatment time of trivalent chromium protection coating on aluminium alloy 2024-T3 on improved corrosion resistance[J]. Surface and Coatings Technology, 2019, 369: 186-197.
55	ELY M, ?WIATOWSKA J, SEYEUX A, et al. Role of post-treatment in improved corrosion behavior of trivalent chromium protection (TCP) coating deposited on aluminum alloy 2024-T3[J]. Journal of the Electrochemical Society, 2017, 164(6): C276-C284.
56	QI J, ZHANG B, WANG Z, et al. Effect of an Fe(Ⅱ)-modified trivalent chromium conversion process on Cr(Ⅵ) formation during coating of AA 2024 alloy[J]. Electrochemistry Communications, 2018, 92: 1-4.
57	LI L, KIM D Y, SWAIN G M. Transient formation of chromate in trivalent chromium process (TCP) coatings on AA2024 as probed by Raman spectroscopy[J]. Journal of the Electrochemical Society, 2012, 159(8): C326-C333.
58	SONG L L, LI J F, CAI C. Corrosion resistance and self-repairing behaviour of Cr(Ⅲ) contained conversion coating on AA2024-T3[J]. Corrosion Engineering, Science and Technology, 2016, 51(4): 263-271.
59	AHMADI P, SARABI A A, EIVAZ MOHAMMADLOO H, et al. Effect of practical parameters on the structure and corrosion behavior of vanadium/zirconium conversion coating on AA2024 aluminum alloy[J]. Journal of Coatings Technology and Research, 2019, 16(5): 1503-1513.
60	CHEN W K, BAI C Y, LIU C M, et al. The effect of chromic sulfate concentration and immersion time on the structures and anticorrosive performance of the Cr(Ⅲ) conversion coatings on aluminum alloys[J]. Applied Surface Science, 2010, 256(16): 4924-4929.
61	CHEN W K, LEE J L, BAI C Y, et al. Growth and characteristics of Cr(Ⅲ)-based conversion coating on aluminum alloy[J]. Journal of the Taiwan Institute of Chemical Engineers, 2012, 43(6): 989-995.
62	ZHANG H, ZHANG X, ZHAO X, et al. Preparation of Ti-Zr-based conversion coating on 5052 aluminum alloy, and its corrosion resistance and antifouling performance[J]. Coatings, 2018, 8(11): 397-408.
63	LIU B, ZHAO Y, LI L, et al. Formation and properties of Zr/Ti based nano-sized non-chromium chemical conversion coating on AA 5083[J]. Journal of Nanoscience and Nanotechnology, 2019, 19(6): 3487-3494.
64	李欣琳. 铝合金表面新型锆钛转化膜的制备与性能研究[D]. 哈尔滨: 哈尔滨工程大学, 2018.
64	LI X L. Research on preparation and performance of a novel type of Ti-Zr conversion coating based on the aluminum alloy[D]. Harbin: Harbin Engineering University, 2018.
65	ANDREATTA F, TURCO A, DE GRAEVE I, et al. SKPFM and SEM study of the deposition mechanism of Zr/Ti based pre-treatment on AA6016 aluminum alloy[J]. Surface and Coatings Technology, 2007, 201(18): 7668-7685.
66	陈龙, 李文芳, 祝闻. 6063铝合金表面钛/锆/钼转化膜的制备及自愈性[J]. 材料导报, 2019, 33(5): 1691-1696.
66	CHEN L, LI W F, ZHU W. The Preparation and self-healing of titanium /zirconium /molybdenum conversion coating on 6063 aluminum alloy[J]. Materials Reports, 2019, 33(5): 1691-1696.
67	ZHAN W, LIU X, OUYANG G. Film-forming mechanism and properties of Ti/Zr/Mo colored conversion coating prepared on aluminum alloy[J]. International Journal of Precision Engineering and Manufacturing: Green Technology, 2016, 3(3): 297-302.
68	YI A, LI W, DU J, et al. Effects of Mn²⁺on the chrome-free colored Ti/Zr-based conversion coating on 6063 aluminum alloy[J]. Surface and Interface Analysis, 2015, 47(9): 863-870.
69	ZHONG X, WU X, JIA Y, et al. Self-repairing vanadium-zirconium composite conversion coating for aluminum alloys[J]. Applied Surface Science, 2013, 280: 489-493.
70	ZHU W, LI W, MU S, et al. The adhesion performance of epoxy coating on AA6063 treated in Ti/Zr/V based solution[J]. Applied Surface Science, 2016, 384: 333-340.
71	YI A, LI W, DU J, et al. Preparation and properties of chrome-free colored Ti/Zr based conversion coating on aluminum alloy[J]. Applied Surface Science, 2012, 258(16): 5960-5964.
72	陈廷益, 付业琦, 路文, 等. 6063铝合金Zr-Ni黑色化学转化膜的制备及表征[J]. 材料导报, 2014, 28(7): 100-103.
72	CHEN T Y, FU Y Q, LU W, et al. Synthesis and characterization of chrome-free Zr-Ni dark coating on AA6063 aluminium alloy[J]. Materials Review, 2014, 28(7): 100-103.
73	于强, 赵金柱, 崔艳丽, 等. 铝合金红色Zr-Se化学转化膜的制备及性能研究[J]. 材料保护, 2019, 52(7): 1-6.
73	YU Q, ZHAO J Z, CUI Y L, et al. Preparation and characterization of Zr-Se based conversion coatings on aluminum alloy[J]. Materials Protection, 2019, 52(7):1-6.
74	WANG S, LIU C, SHAN F. Corrosion behavior of a zirconium-titanium based phosphonic acid conversion coating on AA6061 aluminium alloy[J]. Acta Metallurgica Sinica (English Letters), 2008, 21(4): 269-274.
75	WU Y, LIN J, WANG P, et al. Effect of long-term neutral salt spray exposure on durability of adhesive-bonded Zr-Ti coated aluminum joint[J]. International Journal of Adhesion and Adhesives, 2016, 64: 97-108.
76	MENG Q, FRANKEL G S. Effect of copper content on chromate conversion coating protection of 7×××-T6 aluminum alloys[J]. Corrosion, 2004, 60: 897-905.
77	TIRINGER U, KOVA? J, MILO?EV I. Effects of mechanical and chemical pre-treatments on the morphology and composition of surfaces of aluminium alloys 7075-T6 and 2024-T3[J]. Corrosion Science, 2017, 119: 46-59.
78	KLOMJIT P, BUCHHEIT R G. Localized corrosion inhibition of 7075-T6 by calcium sulfate[J]. Corrosion, 2016, 72(4): 486-499.
79	HUANG I, HURLEY B L, YANG F, et al. Dependence on temperature, pH, and Cl^-in the uniform corrosion of aluminum alloys 2024-T3, 6061-T6, and 7075-T6[J]. Electrochimica Acta, 2016, 199: 242-253.
80	MUNSON C A, MCFALL-BOEGEMAN S A, SWAIN G M. Cross comparison of TCP conversion coating performance on aluminum alloys during neutral salt-spray and thin-layer mist accelerated degradation testing[J]. Electrochimica Acta, 2018, 282: 171-184.
81	MUNSON C A, SWAIN G M. Structure and chemical composition of different variants of a commercial trivalent chromium process (TCP) coating on aluminum alloy 7075-T6[J]. Surface and Coatings Technology, 2017, 315: 150-162.
82	MUNSON C A, ZUTIM P, SWAIN G M. Electrochemical characterization of different variants of a commercial trivalent chromium process (TCP) coating on aluminum alloy 7075-T6[J]. Corrosion, 2018, 74(1): 50-65.
83	LI L, DORAN K P, SWAIN G M. Electrochemical characterization of trivalent chromium process (TCP) coatings on aluminum alloys 6061 and 7075[J]. Journal of the Electrochemical Society, 2013, 160(8): C396-C401.
84	LI L, SWAIN G M. Formation and structure of trivalent chromium process coatings on aluminum alloys 6061 and 7075[J]. Corrosion, 2013, 69(12): 1205-1216.
85	LIU Q, CAO X, DU A, et al. Investigation on adhesion strength and corrosion resistance of Ti-Zr aminotrimethylene phosphonic acid composite conversion coating on 7A52 aluminum alloy[J]. Applied Surface Science, 2018, 458: 350-359.
86	COLOMA S P, IZAGIRRE U, BELAUSTEGI Y, et al. Chromium-free conversion coatings based on inorganic salts (Zr/Ti/Mn/Mo) for aluminum alloys used in aircraft applications[J]. Applied Surface Science, 2015, 345: 24-35.

[1]	张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透（RO）膜[J]. 化工进展, 2023, 42(S1): 364-373.
[2]	张杰, 白忠波, 冯宝鑫, 彭肖林, 任伟伟, 张菁丽, 刘二勇. PEG及其复合添加剂对电解铜箔后处理的影响[J]. 化工进展, 2023, 42(S1): 374-381.
[3]	赵景超, 谭明. 表面活性剂对电渗析减量化工业含盐废水的影响[J]. 化工进展, 2023, 42(S1): 529-535.
[4]	王谨航, 何勇, 史伶俐, 龙臻, 梁德青. 气体水合物阻聚剂研究进展[J]. 化工进展, 2023, 42(9): 4587-4602.
[5]	高彦静. 单原子催化技术国际研究态势分析[J]. 化工进展, 2023, 42(9): 4667-4676.
[6]	李雪佳, 李鹏, 李志霞, 晋墩尚, 郭强, 宋旭锋, 宋芃, 彭跃莲. 亲水和疏水改性膜的抗结垢和润湿能力的对比[J]. 化工进展, 2023, 42(8): 4458-4464.
[7]	徐杰, 夏隆博, 罗平, 邹栋, 仲兆祥. 面向膜蒸馏过程的全疏膜制备及其应用进展[J]. 化工进展, 2023, 42(8): 3943-3955.
[8]	潘宜昌, 周荣飞, 邢卫红. 高效分离同碳数烃的先进微孔膜：现状与挑战[J]. 化工进展, 2023, 42(8): 3926-3942.
[9]	王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004.
[10]	张超, 杨鹏, 刘广林, 赵伟, 杨绪飞, 张伟, 宇波. 表面微结构对阵列微射流沸腾换热的影响[J]. 化工进展, 2023, 42(8): 4193-4203.
[11]	李润蕾, 王子彦, 王志苗, 李芳, 薛伟, 赵新强, 王延吉. CuO-CeO₂/TiO ₂ 高效催化CO低温氧化反应性能[J]. 化工进展, 2023, 42(8): 4264-4274.
[12]	张振, 李丹, 陈辰, 吴菁岚, 应汉杰, 乔浩. 吸附树脂对唾液酸的分离纯化[J]. 化工进展, 2023, 42(8): 4153-4158.
[13]	吴海波, 王希仑, 方岩雄, 纪红兵. 3D打印催化材料开发与应用进展[J]. 化工进展, 2023, 42(8): 3956-3964.
[14]	俞俊楠, 俞建峰, 程洋, 齐一搏, 化春键, 蒋毅. 基于深度学习的变宽度浓度梯度芯片性能预测[J]. 化工进展, 2023, 42(7): 3383-3393.
[15]	陆诗建, 刘苗苗, 杨菲, 张俊杰, 陈思铭, 刘玲, 康国俊, 李清方. 改良型CO₂湿壁塔内气液两相流动规律及传质特性[J]. 化工进展, 2023, 42(7): 3457-3467.