化工进展 ›› 2020, Vol. 39 ›› Issue (7): 2662-2669.DOI: 10.16085/j.issn.1000-6613.2019-1584

• 工业催化 • 上一篇    下一篇

CeO2含量对柴油机商用稀土SCR催化剂脱硝性能的影响

王艳1,2(), 李兆强1,2(), 张丞1,2, 王雨1,2, 樊蓉蓉1,2, 丁智勇1,2, 郭欣1,2, 王荣1,2   

  1. 1.包头稀土研究院白云鄂博稀土资源研究与综合利用国家重点实验室,内蒙古 包头 014030
    2.瑞科稀土冶金及功能材料国家工程研究中心,内蒙古 包头 014030
  • 出版日期:2020-07-05 发布日期:2020-07-10
  • 通讯作者: 李兆强
  • 作者简介:王艳(1987—),女,硕士,工程师,研究方向为稀土催化材料。E-mail:wy_brire@163.com
  • 基金资助:
    内蒙古自然科学基金面上项目(2017MS0209);北方稀土科技计划(BFXT-2018-D-1)

Influence of CeO2 contents on the SCR performance of commercial rare earth catalysts

Yan WANG1,2(), Zhaoqiang LI1,2(), Cheng ZHANG1,2, Yu WANG1,2, Rongrong FAN1,2, Zhiyong DING1,2, Xin GUO1,2, Rong WANG1,2   

  1. 1.State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou 014030, Inner Mongolia, China
    2.National Engineering Research of Rare Earth Metallurgy and Functional Materials, Baotou 014030, Inner Mongolia, China
  • Online:2020-07-05 Published:2020-07-10
  • Contact: Zhaoqiang LI

摘要:

考察了不同CeO2含量对柴油机商用稀土选择性催化还原(SCR)催化剂NH3-SCR性能的影响。通过X射线衍射、N2吸附-脱附、X射线光电子能谱、H2-程序升温还原和NH3-程序升温脱附等表征手段对催化剂的结构及性能进行了研究。研究发现,CeO2含量对催化剂的晶体结构没有影响,添加后促进了稀土催化剂表面SiO2的分散,从而对催化剂的脱硝性能及水热老化性能产生影响;CeO2含量影响催化剂的织构性质,较大的孔体积和适当的比表面有利于催化剂水热老化后催化剂的脱硝性能的提高;随着CeO2含量从14%增加到20%,其表面Ce含量呈先降低后升高的趋势,其中Ce4+含量与催化剂的水热老化后催化剂的脱硝性能成正相关;CeO2含量的增加会阻碍稀土催化剂中其他组分的还原或增加其热稳定性,从而影响催化剂的还原能力和酸性位数量;通过脱硝性能测试,稀土催化剂中CeO2的最佳含量为16%。

关键词: 氧化铈, 催化剂, 氨选择性催化还原, 水热老化, 催化作用

Abstract:

The effect of CeO2 contents on the NH3-SCR performance of commercial rare earth catalysts in diesel was investigated. By using XRD, N2 adsorption-desorption, XPS, H2-TPR and NH3-TPD analysis, we found that the addition of CeO2 had no effect on the crystal structure of the catalysts, but it promoted the dispersion of SiO2 on the surface of the rare earth catalysts, which affected the SCR performance and hydrothermal stability of the catalysts. The content of CeO2 affected the texture properties of the catalysts, and larger pore volume and appropriate specific surface were beneficial for the improvement of the hydrothermal aging performance of the catalysts. The content of Ce on the surface firstly decreased and then increased when the CeO2 content increased from 14% to 20%, and the amount of Ce4+ was positively correlated with the hydrothermal aging performance of the catalysts. Moreover, the redox ability and the number of acid sites decreased with the increase of CeO2 content because it could hinder the reduction of other components or increase the thermal stability of the rare earth catalysts. According to the results of catalytic activity tests for NH3-SCR, the optimum content of CeO2 in the rare earth catalysts was 16%.

Key words: cerium oxide, catalyst, NH3-SCR, hydrothermal aging, catalysis

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