气液等离子体过程强化技术及其在高级氧化过程的应用

doi:10.16085/j.issn.1000-6613.2017-2215

摘要/Abstract

摘要： 气液等离子体过程强化技术是20世纪80年代发展起来的一门新兴交叉学科，在高级氧化过程、液相化学合成和纳米材料制备等领域具有巨大的研究与应用价值。从化学工程的角度理解，气液等离子体过程强化技术的本质是特殊外场作用下的多相传递与反应过程，其中涉及高能电子碰撞、化学活性组分氧化、紫外光解和冲击波等多种物理与化学作用。由于气液等离子体过程强化技术本身的复杂性及多学科交叉性，对其复杂的物理与化学耦合机理还未得到充分认识，同时缺乏对气液等离子体反应器的系统研究及设计指导，从而极大程度地限制了该技术的进一步应用和发展。为全面认识气液等离子体过程强化技术，本文综述了近年来有关气液等离子体过程强化技术的诊断及机理研究进展，并剖析了气液等离子体反应器的设计思路，同时回顾和展望了气液等离子体高级氧化过程的最新研究进展，讨论了气液等离子体过程强化技术的研究方向。

关键词: 气液等离子体, 作用机理, 反应器, 过程强化, 高级氧化过程

Abstract: Process intensification technique of gas-liquid plasma has been a newly developed interdisciplinary field since 1980s,which shows significant values in the applications of advanced oxidation processes,liquid phase chemosynthesis,nano-materials synthesis and so on. From the point of view of chemical engineering,it is a multi-phase transport and reaction process with special external field combining both physical and chemical effects of high-energy electronic collision,chemically active component oxidation,ultraviolet light and shock waves,etc. Because of the complexity and multidisciplinary feature of the gas-liquid plasma itself,the involved physical and chemical mechanism has not been fully understood. At the same time,the lack of systematic study on the gas-liquid plasma reactors has significantly restricted the further application and development of the process intensification technique of gas-liquid plasma. The aims of this paper are to review the recent advances of gas-liquid plasma,involving the diagnosis technique,process mechanism,reactor design and the applications in advanced oxidation processes. Finally,the future research direction on the gas-liquid plasma assisted processes is given.

Key words: gas-liquid plasma, mechanism, reactor, process intensification, advanced oxidation processes

中图分类号:

O646.9

冯雪兰, 程易. 气液等离子体过程强化技术及其在高级氧化过程的应用[J]. 化工进展, 2018, 37(04): 1247-1256.

FENG Xuelan, CHENG Yi. Process intensification technique of gas-liquid plasma and its application in advanced oxidation processes[J]. Chemical Industry and Engineering Progress, 2018, 37(04): 1247-1256.

参考文献

[1] 颜彬航,卢巍,冯雪兰,等. 等离子体多相反应器基础研究和过程强化[J]. 化学反应工程与工艺,2013,29(3):214-221. YAN B H,LU W,FENG X L,et al. Fundamental study and process intensification in plasma multiphase reactors[J]. Chemical Reaction Engineering and Technology,2013,29(3):214-221.
[2] 刘万楹. 非平衡等离子体有机化学进展[J]. 有机化学,1992(12):337-344. LIU W Y. Advances in organic chemistry of nonequilibrium plasma[J]. Organic Chemistry,1992(12):337-344.
[3] 张秀玲,于淼,翟林燕. 气液等离子体技术研究进展[J]. 化工进展,2010,29(11):2034-2038. ZHANG X L,YU M,ZHAI L Y. Advances in gas-liquid plasma technology[J]. Chemical Industry and Engineering Progress,2010,29(11):2034-2038.
[4] WEN X Q,LI Q,LI J S,et al. Quantitative relationship between the maximum streamer length and discharge voltage of a pulsed positive streamer discharge in water[J]. Plasma Science and Technology,2017,19:085401.
[5] FOSTER J E,SOMMERS B S,GUCKER S N. Towards understanding plasma formation in liquid water via single bubble studies[J]. Japanese Journal of Applied Physics,2015,54:01AF05.
[6] TU Y L,XIA H L,YANG Y,et al. Time-resolved imaging of electrical discharge development in underwater bubbles[J]. Physics of Plasmas,2016,23(1):013507.
[7] LI O L,TAKEUCHI N,HE Z,et al. Active species generated by a pulsed arc electrohydraulic discharge plasma channel in contaminated water treatments[J]. Plasma Chemistry and Plasma Processing,2012,32(2):343-358.
[8] LIU Z C,LIU D X,CHEN C,et al. Physicochemical processes in the indirect interaction between surface air plasma and deionized water[J]. Journal of Physics D:Applied Physics,2015,48:495201.
[9] KANAZAWA S,KAWANO H,WATANABE S,et al. Observation of OH radicals produced by pulsed discharges on the surface of a liquid[J]. Plasma Sources Science and Technology,2011,20(3):034010.
[10] HSIEH K C,WANDELL R J,BRESCH S,et al. Analysis of hydroxyl radical formation in a gas-liquid electrical discharge plasma reactor utilizing liquid and gaseous radical scavengers[J]. Plasma Processes and Polymers,2017,14(8):1600171.
[11] NAIDIS G V. Modelling of OH production in cold atmospheric-pressure He-H₂O plasma jets[J]. Plasma Sources Science and Technology,2013,22(3):035015.
[12] QIAN M Y,YANG C Y,WANG Z D,et al. Numerical study of the effect of water content on OH production in a pulsed-DC atmospheric pressure helium-air plasma jet[J]. Chinese Physics B,2016,25:015202.
[13] LINDSAY A,ANDERSON C,SLIKBOER E,et al. Momentum,heat,and neutral mass transport in convective atmospheric pressure plasma-liquid systems and implications for aqueous targets[J]. Journal of Physics D:Applied Physics,2015,48:424007.
[14] OHYAMA R,INOUE K,CHANG J S. Schlieren optical visualization for transient EHD induced flow in a stratified dielectric liquid under gas-phase AC corona discharges[J]. Journal of Physics D:Applied Physics,2007,40(2):573-578.
[15] SHIMIZU T,IWAFUCHI Y,MORFILL G E,et al. Formation of thermal flow fields and chemical transport in air and water by atmospheric plasma[J]. New Journal of Physics,2011,13(5):053025.
[16] 王文坦,张梦雪,赵述芳,等. 激光诱导荧光技术在液体混合可视化研究中的应用[J]. 化工学报,2013,64(3):771-778. WANG W T,ZHANG M X,ZHAO S F,et al. Application of laser-induced fluorescence technique in visualization of liquid mixing process[J]. CIESC Journal,2013,64(3):771-778.
[17] FENG X L,SHAO T,WANG W T,et al. Visualization of in situ oxidation process between plasma and liquid phase in two dielectric barrier discharge plasma reactors using planar laser induced fluorescence technique[J]. Plasma Chemistry Plasma Processing,2012,32(6):1127-1137.
[18] FENG X L,YAN B H,LU W,et al. Visualization of coupled mass transfer and reaction in a gas-liquid dielectric barrier discharge reactor[J]. Chemical Engineering Journal,2014,245:47-55.
[19] BRUGGEMAN P,LEYS C. Non-thermal plasmas in and in contact with liquids[J]. Journal of Physics D:Applied Physics,2009,42(5):53001.
[20] BRISSET J,MOUSSA D,DOUBLA A,et al. Chemical reactivity of discharges and temporal post-discharges in plasma treatment of aqueous media:examples of gliding discharge treated solutions[J]. Industrial & Engineering Chemistry Research,2008,47(16):5761-5781.
[21] MOUELE E,TIJANI J O,FATOBA O O,et al. Degradation of organic pollutants and microorganisms from wastewater using different dielectric barrier discharge configurations-a critical review[J]. Environmental Science and Pollution Research,2015,22(23):18345-18362.
[22] BANASCHIK R,LUKES P,JABLONOWSKI H,et al. Potential of pulsed corona discharges generated in water for the degradation of persistent pharmaceutical residues[J]. Water Research,2015,84:127-135.
[23] ZHU L,HE Z H,GAO Z W,et al. Research on the influence of conductivity to pulsed arc electrohydraulic discharge in water[J]. Journal of Electrostatics,2014,72(1):53-58.
[24] SAITO R,SUGIURA H,ISHIJIMA T,et al. Influence of temperature and pressure on solute decomposition efficiency by microwave-excited plasma[J]. Current Applied Physics,2011,11(5):S195-S198.
[25] MALIK M A. Water purification by plasmas:which reactors are most energy efficient?[J]. Plasma Chemistry Plasma Processing,2010,30(1):21-31.
[26] MINAMITANI Y,SHOJI S,OHBA Y,et al. Decomposition of dye in water solution by pulsed power discharge in a water droplet spray[J]. IEEE Transactions on Plasma Science,2008,36(5):2586-2591.
[27] HANDA T,MINAMITANI Y. The effect of a water-droplet spray and gas discharge in water treatment by pulsed power[J]. IEEE Transactions on Plasma Science,2009,37(1):179-183.
[28] KOBAYASHI T,SUGAI T,HANDA T,et al. The effect of spraying of water droplets and location of water droplets on the water treatment by pulsed discharge in air[J]. IEEE Transactions on Plasma Science,2010,38(10):2675-2680.
[29] SUGAI T,NGUYEN P T,TOKUCHI A,et al. The effect of flow rate and size of water droplets on the water treatment by pulsed discharge in air[J]. IEEE Transactions on Plasma Science,2015,43(101):3493-3499.
[30] STRATTON G R,BELLONA C L,DAI F,et al. Plasma-based water treatment:conception and application of a new general principle for reactor design[J]. Chemical Engineering Journal,2015,273:543-550.
[31] FOSTER J E. Plasma-based water purification:challenges and prospects for the future[J]. Physics of Plasmas,2017,24(5):055501.
[32] LESAGE O,THIBAULT R C,COMMENGE J M,et al. Degradation of 4-chlorobenzoic acid in a thin falling film dielectric barrier discharge reactor[J]. Industrial & Engineering Chemistry Research,2014,53:10387-10396.
[33] YU Z Q,SUN Y B,ZHANG G Y,et al. Degradation of DEET in aqueous solution by water falling film dielectric barrier discharge:effect of three operating modes and analysis of the mechanism and degradation pathway[J]. Chemical Engineering Journal,2017,317:90-102.
[34] FENG X L,YAN B H,YANG Q L,et al. Gas-liquid dielectric barrier discharge falling film reactor for the decoloration of dyeing water[J]. Journal of Chemical Technology and Biotechnology,2016,91(2):431-438.
[35] 冯雪兰,杨千里,王玉珏,等. 气液介质阻挡放电降膜反应器降解甲硝唑实验研究[J]. 环境科学学报,2016,36(11):3965-3970. FENG X L,YANG Q L,WANG Y J,et al. Degradation of metronidazole using a gas-liquid dielectric barrier discharge falling film reactor[J]. Acta Scientiae Circumstantiae,2016,36(11):3965-3970.
[36] FOSTER J E,SOMMERS B S,GUCKER S N,et al. Perspectives on the interaction of plasmas with liquid water for water purification[J]. IEEE Transactions on Plasma Science,2012,40(5):1311-1323.
[37] JIANG B,ZHENG J T,QIU S,et al. Review on electrical discharge plasma technology for wastewater remediation[J]. Chemical Engineering Journal,2014,236:348-368.
[38] HYOUNG S K,WRIGHT K,JOSHUA P A,et al. Inactivation of bacteria by the application of spark plasma in produced water[J]. Separation and Purification Technology,2015,156(2):544-552.
[39] CLEMENTS J S,SATO M,DAVIS R H. Preliminary investigation of prebreakdown phenomena and chemical reactions using a pulsed high voltage discharge in water[J]. IEEE Transactions on Industry Applications,1987,23(2):224-235.
[40] SUN B,SATO M,CLEMENTS J S. Optical study of active species produced by a pulsed streamer corona discharge in water[J]. Journal of Electrostatics,1997,39(3):189-202.
[41] SUN B,SATO M,CLEMENTS J S. Use of a pulsed high-voltage discharge for removal of organic compounds in aqueous solution[J]. Journal of Physics D:Applied Physics,1999,32(15):1908-1915.
[42] SUN B,SATO M,CLEMENTS J S. Oxidative processes occurring when pulsed high voltage discharges degrade phenol in aqueous solution[J]. Environmental Science & Technology,2000,34(3):509-513.
[43] 张路路,黄娅妮,王刚,等. 滑动弧等离子体处理三种染料废水的研究[J]. 环境工程,2016,34(12):48-52. ZHANG L L,HUANG Y Y,WANG G,et al. Treatment of three kinds of dye wastewater by gliding arc discharge plasma[J]. Environmental Engineering,2016,34(12):48-52.
[44] 陶旭梅,王国伟,刘得璐,等. 新型两级DBD等离子体反应器处理印染废水的研究[J]. 现代化工,2016,36(10):142-145. TAO X M,WANG G W,LIU D L,et al. A novel two-stage DBD plasma reactor for dyeing wastewater degradation[J]. Modern Chemical Industry,2016,36(10):142-145.
[45] ZHOU Z Y,LIANG Z R,LIU Y,et al. Intensification of degradation of Sunset Yellow using packed bed in a pulsed high-voltage hybrid gas-liquid discharge system:optimization of operating parameters,degradation mechanism and pathways[J]. Chemical Engineering and Processing,2017,115:23-33.
[46] NI G,ZHAO G,JIANG Y,et al. Steam plasma jet treatment of phenol in aqueous solution at atmospheric pressure[J]. Plasma Processes and Polymers,2013,10:353-363.
[47] 董冰岩,张鹏,聂亚林,等. 针-板式高压脉冲气液两相放电降解废水中的苯酚[J]. 化工进展,2016,35(1):314-319. DONG B Y,ZHANG P,NIE Y L,et al. Phenol wastewater treatment by needle-plate pulsed high voltage discharge in gas-liquid two phase[J]. Chemical Industry and Engineering Progress,2016,35(1):314-319.
[48] DOBRIN D,BRADU C,MAGUREANU M,et al. Degradation of diclofenac in water using a pulsed corona discharge[J]. Chemical Engineering Journal,2013,234:389-396.
[49] RONG S P,SUN Y B. Wetted-wall corona discharge induced degradation of sulfadiazine antibiotics in aqueous solution[J]. Journal of Chemical Technology and Biotechnology,2014,89(9):1351-1359.
[50] MAGUREANU M,MANDACHE N B,PARVULESCU V I. Degradation of pharmaceutical compounds in water by non-thermal plasma treatment[J]. Water Research,2015,81:124-136.
[51] THAGARD S M,STRATTON G R,DAI F,et al. Plasma-based water treatment:development of a general mechanistic model to estimate the treatability of different types of contaminants[J]. Journal of Physics D:Applied Physics,2017,50:014003.
[52] STRATTON G R,DAI F,BELLONA C L,et al. Plasma-based water treatment:efficient transformation of perfluoroalkyl substances in prepared solutions and contaminated groundwater[J]. Environmental Science & Technology,2017,51:1643-1648.
[53] BLANKSON I M,FOSTER J E,ADAMOVSKY G. Non-equilibrium plasma applications for water purification supporting human spaceflight and terrestrial point-of-use[EB/OL].[2016-05-24]. https://ntrs.nasa.gov/search.jsp?R=20160006639.
[54] ZOLEZZI A. How water purification technology is saving lives[EB/OL].
[2013] . https://www.youtube.com/watch?v=eEh4SsM_nKQ.
[55] BAI M D,ZHANG Z T,ZHANG N H,et al. Treatment of 250t/h ballast water in oceanic ships using·OH radicals based on strong electric-field discharge[J]. Plasma Chemistry Plasma Processing,2012,32(4):693-702.
[56] BRESCH S,WANDELL R,WANG H H,et al. Oxidized derivatives of n-hexane from a water/argon continuous flow electrical discharge plasma reactor[J]. Plasma Chemistry Plasma Processing,2016,36(2):553-584.
[57] AGUNG M,NOMURA S,MUKASA S,et al. One-step phenol production from a water-toluene mixture using radio frequency in-liquid plasma[J]. Plasma Science and Technology,2017,19(5):60-67.
[58] MARIOTTI D,PATEL J,SVRCEK V,et al. Plasma-liquid interactions at atmospheric pressure for nanomaterials synthesis and surface engineering[J]. Plasma Processes and Polymers,2012,9(11/12):1074-1085.
[59] SAMUKAWA S,HORI M,RAUF S,et al. The 2012 plasma roadmap[J]. Journal of Physics D:Applied Physics,2012,45(25):253001.
[60] ADAMOVICH I,BAALRUD S D,BOGAERTS A,et al. The 2017 plasma roadmap:low temperature plasma science and technology[J]. Journal of Physics D:Applied Physics,2017,50:323001.
[61] 闫克平,李树然,冯卫强,等. 高电压环境工程应用研究关键技术问题分析及展望[J]. 高电压技术,2015,41(8):2528-2544. YAN K P,LI S R,FENG W Q,et al. Analysis and prospect on key technology of high-voltage discharge for environmental engineering study and application[J]. High Voltage Engineering,2015,41(8):2528-2544.
[62] VANRAES P,GHODBANE H,DAVISTER D,et al. Removal of several pesticides in a falling water film DBD reactor with activated carbon textile:energy efficiency[J]. Water Research,2017,116:1-12.
[63] 孙基惠,孙玉,程茜,等. 介质阻挡放电联合生物法处理染料废水的研究[J]. 水处理技术,2017,43(5):38-42. SUN J H,SUN Y,CHENG Q,et al. Study on dye wastewater treatment by dielectric barrier discharge combined with biological method technology of water treatment[J]. Technology of Water Treatment,2017,43(5):38-42.
[64] LIU H,DU C M,WANG J,et al. Comparison of acid orange 7 degradation in solution by gliding arc discharge with different forms of TiO₂[J]. Plasma Processes and Polymers,2012,9(3):285-297.
[65] GHEZZAR M R,OGNIER S,CAVADIAS S,et al. DBD plate TiO₂ treatment of yellow tartrazine azo dye solution in falling film[J]. Separation and Purification Technology,2013,104:250-255.
[66] 荣俊锋. 等离子体协同紫外光催化净化聚丙烯酰胺废水[J]. 应用化工,2016,45(8):1535-1538. RONG J F. PAM wastewater treatment by non-thermal plasma-UV photocatalytic combination process[J]. Applied Chemical Industry,2016,45(8):1535-1538.
[67] 余芳,陈元涛,张炜,等. TiO₂-HNTs催化剂协同介质阻挡放电等离子体降解亚甲基蓝废水[J]. 化工进展,2016,35(12):4076-4081. YU F,CHEN Y T,ZHANG W,et al. Treatment of methylene blue wastewater with a compound photo-catalyst TiO₂-HNTs combined with dielectric barrier discharge[J]. Chemical Industry and Engineering Progress,2016,35(12):4076-4081.

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