化工进展 ›› 2017, Vol. 36 ›› Issue (S1): 380-387.DOI: 10.16085/j.issn.1000-6613.2017-1367

• 精细化工 • 上一篇    下一篇

环境刺激响应型乳液体系的研究现状

宋玉新, 田森林, 李英杰, 赵群, 张月超   

  1. 昆明理工大学环境科学与工程学院, 云南 昆明 650500
  • 收稿日期:2017-07-04 修回日期:2017-07-25 出版日期:2017-12-31 发布日期:2017-12-13
  • 通讯作者: 田森林,博士,教授,博士生导师,主要从事污染控制化学方面的研究。
  • 作者简介:宋玉新(1990-),男,硕士研究生,主要从事水污染控制方面的研究。E-mail:2551088398@qq.com。
  • 基金资助:
    国家自然科学基金项目(20120030)。

Research status of environmentally stimuli-responsive emulsion systems

SONG Yuxin, TIAN Senlin, LI Yingjie, ZHAO Qun, ZHANG Yuechao   

  1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, Yunnan, China
  • Received:2017-07-04 Revised:2017-07-25 Online:2017-12-31 Published:2017-12-13

摘要: 就传统的乳液体系而言,用于实现分离、生产、研究应用目的之后,乳液破除操作存在诸如不能对乳化剂、破乳药剂回收循环复用及破乳成本高等问题。环境刺激响应型乳液体系是指能够对光、磁、pH、CO2等信号刺激产生响应的新型智能乳状液体系。本文分别介绍了具有光、磁、pH、CO2环境刺激响应性能乳液体系的相关研究成果及潜在的应用研究价值,一方面,相较传统的乳液体系,环境刺激响应型乳液体系对于实现乳状液破除、循环利用乳化剂、乳状液油相以及回收目标物提供了便利;另一方面,其也拓宽了乳化液用于催化、材料合成、药物运载与可控释放等领域的空间。最后,指出了环境刺激响应型乳液体系相关研究所存在的不足之处并对研究前景进行了展望。

关键词: 乳液, 二氧化碳, 表面活性剂, 破乳, Pickering乳化剂, 环境刺激响应

Abstract: In practice, the conventional water-in-oil and oil-in-water emulsion systems are applied in the process of separation, production and research, after which demulsification is required. However, it is problematic, such as high cost, irrealizable recovery of emulsifiers and demulsifier agents, to demulsify the conventional emulsion systems. Environmental stimuli-responsive emulsion systems are a novel family of intelligent emulsion systems, which can respond to signals, such as light, magnetism, pH and CO2. The research and potential applications on environmental stimuli-responsive emulsion systems with performance responding to light, magnetism, pH and CO2 were reviewed respectively. On one hand, compared with the conventional emulsion systems, it is facile to achieve demulsification, cycling of emulsifiers and oil phase and to recovery target object. On the other hand, it also broadens the space for emulsions applied in catalysis, material synthesis, drug delivery and controlled release, and so on. In the end, the existing problems and the development prospect of environmental stimuli-responsive emulsion systems were forecasted.

Key words: emulsions, carbon dioxide, surfactants, demulsification, Pickering emulsifier, environmentally stimuli-responsive

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