化工进展 ›› 2017, Vol. 36 ›› Issue (12): 4641-4650.DOI: 10.16085/j.issn.1000-6613.2017-0653

• 资源与环境化工 • 上一篇    下一篇

氨法碳捕集中氨逃逸抑制机制研究进展

王甫1, 赵军2, 邓帅2, 赵加佩1, 袁金良1, 杨国华1, 严晋跃3   

  1. 1 宁波大学海运学院, 浙江 宁波 315211;
    2 天津大学中低温热能高效利用教育部重点实验室, 天津 300350;
    3 瑞典皇家理工学院化学工程系, 斯德哥尔摩 10044
  • 收稿日期:2017-04-13 修回日期:2017-05-09 出版日期:2017-12-05 发布日期:2017-12-05
  • 通讯作者: 袁金良,教授,研究方向为新能源利用及储能关键技术。
  • 作者简介:王甫(1987-),男,博士,讲师。E-mail:wangfu@nbu.edu.cn。
  • 基金资助:
    国家自然科学基金青年科学基金(517061122,51506149)。

Review on development and mechanism of reducing ammonia escape from carbon dioxide capture process using ammonia method

WANG Fu1, ZHAO Jun2, DENG Shuai2, ZHAO Jiapei1, YUAN Jinliang1, YANG Guohua1, YAN Jinyue3   

  1. 1 Faculty of Maritime and Transportation, Ningbo University, Ningbo 315211, Zhejiang, China;
    2 Key Laboratory of Efficient Utilization of Low and Medium Grade Energy, Tianjin University, Tianjin 300350, China;
    3 Department of Chemical Engineering, Royal Institute of Technology, SE 10044, Stockholm, Sweden
  • Received:2017-04-13 Revised:2017-05-09 Online:2017-12-05 Published:2017-12-05

摘要: 氨法碳捕集技术具有低成本、高脱除效率等特点,在电厂烟气CO2脱除领域具有很大的应用前景,但氨逃逸是制约该技术推广应用的主要障碍。基于此,本文综述了近年来氨逃逸抑制技术及其应用方面的进展。首先阐述了吸收-解吸过程氨逃逸传递过程理论,分析了氨逃逸影响因素;其后,重点回顾了代表性氨逃逸抑制技术,包括水(酸)洗、添加剂、参数优化以及流程改进等,并且分析了各技术之间的优缺点。最后,就氨逃逸抑制技术的发展趋势进行了展望,指出氨逃逸抑制技术的系统集成是发展趋势,同时,低成本、低能耗、高效率抑制剂是未来应用研究的重点之一。

关键词: 二氧化碳捕集, 氨逃逸抑制技术, 反应器, 吸收剂, 添加剂, 优化

Abstract: Ammonia carbon capture technology has the advantages of low cost and high efficiency in removing CO2,which has great potentials in several applications,particularly in stationary power generation systems. However,ammonia escape is one of the main obstacles. This paper presented a review on the development of mechanism and applications of reducing ammonia escaping technology in the recent years. Firstly,the mass transfer phenomenon of ammonia escaping in absorption and desorption process was described,and the factors influencing the ammonia escaping were analyzed and discussed. Then,the typical technologies of ammonia escaping control were outlined and highlighted,including water(acid)washing,additive,parameter optimization,in terms of their advantages and disadvantages. Finally,the outlook of ammonia escape suppression technology was presented. The combination of different options is believed as a significant development trend. At the same time,low cost and energy consumption,as well as high efficiency will be focused in the future research.

Key words: CO2 capture, ammonia escape reduction, reactor, absorption solvent, additive, optimization

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